合成纤维

2005, (12) 12-14

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聚砜酰胺的半连续化聚合研究
Investigation on Semi-continuous Polymerization of Polysulfonamide

汪海峰,沙玉明,刘岳新,钱明娟,王秀峰
WANG Hai-feng, SHA Yu-ming, LIU Yue-xin, QIAN Ming-juan, WANG Xiu-feng (Shanghai Synethetic Fiber Research Institute

摘要(Abstract):

聚砜酰胺纤维是耐热性能优异的耐高温纤维。在间歇式聚合的基础上,选用双螺杆挤出机作为反应器,对聚砜酰胺进行了半连续化聚合的研究。研究表明:与间歇式聚合相比,采用双螺杆挤出机进行半连续化聚合可以大大加快反应完成的速度,同时还容易制得相对分子质量较高的聚合物。
Polysulfonamide fiber has good heat resistance. In this paper, on the basis of intermittent polymerization, twin screw extruder chosen as the reactor, the semi-continuous polymerization of polysulfonamide is investigated. The results show that compared with the intermittent polymerization, the semi-continuous polymerization can greatly improve the reaction rate, and polymer with high relative molecular weight can be easily obtained.

关键词(KeyWords): 聚砜酰胺;双螺杆挤出机;半连续化聚合;反应速度;相对分子质量
polysulfonamide, twin screw extruder, semi-continuous polymerization, reaction rate, relative molecular weight

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作者(Author): 汪海峰,沙玉明,刘岳新,钱明娟,王秀峰
WANG Hai-feng, SHA Yu-ming, LIU Yue-xin, QIAN Ming-juan, WANG Xiu-feng (Shanghai Synethetic Fiber Research Institute

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