炭黑/聚氨酯熔纺导电纤维结构与性能的研究Research on Structure and Property of Carbon Black/polyurethane Melt Spun Electrical Conductive Fibers
刘小波,安树林,卢佳楠
LIU Xiao-bo, AN Shu-lin, LU Jia-nan (Tianjin Municipal Key laboratory of Fiber Modification and Functional Fiber
摘要(Abstract):
将导电炭黑混入到热塑性聚氨酯中,经熔融纺丝制得导电纤维。随着炭黑含量增加,炭黑/聚氨酯共混体系的黏度增大,玻璃化转变温度提高。炭黑含量在13% ̄16%时,炭黑在体系中的分布较为均匀,纤维的导电性能较好,力学性能可以满足应用要求。
Carbon black was blended into thermoplastic polyurethane, the electrical conductive fiber was obtained by melting spinning. The results showed that the viscosity and temperature of glass transition of carbon black/polyurethane were improved with the content of carbon black increase in the blend system. When the content of carbon black in the system was between 13 % to 16 %, the distribution of carbon black in system was uniformity, the electrical conductive and the mechanical properties were satisfied for applications.
关键词(KeyWords):
炭黑;热塑性聚氨酯;导电性;熔融纺丝
carbon black, thermoplastic polyurethane, electrical conductive, melt spinning
基金项目(Foundation):
作者(Author):
刘小波,安树林,卢佳楠
LIU Xiao-bo, AN Shu-lin, LU Jia-nan (Tianjin Municipal Key laboratory of Fiber Modification and Functional Fiber
参考文献(References):
- [1]阳贝双,王桦.导电纤维及其应用领域[J].四川纺织科技,2001,2:13-15.
- [2]陈彬.氨纶工业状况与生产技术发展趋势[J].浙江化工,2005,36(1):37-38.
- [3]董炎明.高分子分析手册[M].中国化工出版社,2004.3.465.
- [4]李莹,王仕峰等.炭黑填充复合型导电聚合物的研究进展[J].塑料,2005,34(2):7-8.
- [5]Rosner R B.Conductive materials for ESD applications:an overview[C].Electrical Overstress/Electrostatic Discharge Symposium Proceedings,2000,Sep(26-28):121-131.
- [6]高广艳,安树林等.炭黑/聚酯复合纤维中导电组分的研究[J].天津工业大学学报,2005,24(2):12-15.