俞昊,张瑜,朱美芳,陈彦模
Yu Hao Zhang Yu Zhu Meifang Cheng YanmoState key Lab. for Modification of Chemical Fibers and Polymer materids, China Textile University

• 1:中国纺织大学纤维材料改性国家重点验室
• 2:中国纺织大学纤维材料改性国家重点验室
• 3:中国纺织大学纤维材料改性国家重点验室
• 4:中国纺织大学纤维材料改性国家重点验室 上海 200051

摘要(Abstract)：

随着人们对废弃高分子材料造成环境污染的日益认识,对生物可降解材料的研究得到了重视和发展。本文对高分子材料的降解机理和目前在聚酯纤维方面已取得的进展进行了讨论。着重介绍了目前研究有所发展的聚乳酸(PLA)、聚(β-羟基丁酸酯)(PHB)和聚丁二酸酯类等近几年的工作。
Waste macromolecular materials have polluted the environment. Lots of researches on biodegradable material have been done to solve the problem. In this paper, the mechanism of biodegradation is discussed. And the development of biodegradable polyester fibers, such as PLA fiber,PHB fiber, etc. is introduced. (60 Ref.)

关键词(KeyWords)： 生物可降解;聚酯;纤维;降解机理;微生物;纤维性能

Abstract:

Keywords:

基金项目(Foundation):

作者(Author): 俞昊,张瑜,朱美芳,陈彦模
Yu Hao Zhang Yu Zhu Meifang Cheng YanmoState key Lab. for Modification of Chemical Fibers and Polymer materids, China Textile University

DOI: 10.16090/j.cnki.hcxw.1999.02.009

参考文献(References)：

• [1] Schut J H. Plastics World .1996,54(12) :29
• [2] Narayan R. ASTM stand News .1992, (7) :23-26
• [3] Ottenbright R M. Biodegradable Poly-mers and Plastics.1992: 73-92
• [4] Vert M. Biodegradable Polymers and Plastics.1992:292
• [5] Potts J E. Environmentally Degradable Plastics in Encyclopedia of Chemical Technology . 3rd Edn . New York: John Wiley and Sons, 1984． 626-663
• [6] Huang J C. Adv Polym Technol .1990, 10(1 ):23
• [7] Nir M M. Plastics Eng . 1993,49(3) :75-93
• [8] Holmes P A. Biologically Produces (R)-3-Hydroxy Al-kanoate Polymers and Copolymers in Developments in Crystal-lins Polymers , London : Applied Science , 1988: 1
• [9] Wamock Mary M. Effect of soil PH on the biodegradability of nowoven fabrics 见: Textile Inst. Manchester: Engl. 394
• [10] Wilson C A. Enzyme and Microbial Technology .1992, 14(4) :258-264
• [11] Scott G. Biodegradable Polym and Plas ; 1992:292
• [12] Li M. Degradable Polymers 1995:43-76
• [13] 何光波,黄世强,高分子通报.1996,(6) :116-119
• [14] Pramanik D,T T Ray. Polym Bull. 1987． 18:311
• [15] Walland E L. Polym Comm. 1989,30:302
• [16] Homes P A. Physics in Technology .1985, 16:32
• [17] Billingham N C. Degradation & Stabilization of polyesters of Biological & Synthestic Origin in Developments in Polymer Degradation 7, London : Elsevier Applied Science, 1987: 81-121
• [18] Lenz R W.Chinese J Polym Sci . 1989,7(4) : 289
• [19] Gatenbolm P. Joumal of Appl Polym Sci. 1994,51 (7) :1231-1237
• [20] Avella, M. Journal of Appl Polym Sci. 1993,49(12) :2091-2103
• [21] Avella M. Ceramic Matrix Composites and Other Systems .1993, 2(7) : 864-869
• [22] Bourban Ch. Journal of Environmental Polym Degradation .1997,5(3) : 159-166
• [23] Gatenholm P. Int' l Symposium on Advances in New Materials .见: Contemporary Topics in Polymer Science .1990: 75-82
• [24] Catenbolm P. Journal of Applied Polym Sci .1992,45(9) :1667-1677
• [25] Kanesawa Y. Makromol Chem Rapid Commun ,1990, 11:679-682
• [26] Foster L J R. Journal of Environmental Polymer Degradation . 1994,2(3) : 185-194
• [27] EP 52459, 1981
• [28] EP 52459, 1982
• [29] EP 69497, 1983
• [30] Holy N L. Chem Tech .1991,21:26-30
• [31] Thayer A M. Chem Eng News .1990． 68:7-14
• [32] Matsui. Chem Fibers Int'l. 1996,46(5) :318
• [33] Pegoretti A. J Appl Polym Sci .1997,64(2) :213
• [34] Fambri L. Polymer . 1997,38(1) :79-85
• [35] Horacek I.J Appl Polym Sci. 1994,54(11) : 1751
• [36] Horacek I .J Appl Polym Sci .1994,54(11) : 1759
• [37] Horacek I. J Appl Polym Sci .1994,54(11) : 1767
• [38] 三菱人造丝.J8-226016,1996,9． 3
• [39] Lee C W. J Kobunshi Ronbunshul Jpn Journal of Polym Sci and Tech .1995 .52(11) :692-697
• [40] Lee C W. Bull Chem Soc Jpn 1996,69(6) : 1787
• [41] 王远亮,赵建华.功能材料,1995,26(6) :567-571
• [42] 尤尼吉卡.JP.J7-278965,1995． 10． 24
• [42] 尤尼吉卡.JP.J8-144127, 1996． 6． 4
• [44] 尤尼吉卡.JP.J8-209453, 1996． 8． 13
• [45] 尤尼吉卡.JP.J8-81830,1996． 3． 26
• [46] 尤尼吉卡.JP.J8-134719,1996． 5． 28
• [47] 尤尼吉卡.JP.J8-134723,1996． 5． 28
• [48] 尤尼吉卡.JP.J8-158154,1996． 6． 18
• [49] 昭和电工.JP.J7-2905664,1995． 11． 7
• [50] 三菱煤气化学.JP.J8-158158,1996． 6． 18
• [51] Rutherfor D R. WO (Appl. ) 95-33874,
• [52] High Perform Text .1996,(7) : 10-11
• [53] 可乐丽.JP.J7-316378,1995． 12． 5
• [54] Du Pont Magazine .1997,91(1) : 14-16
• [55] 窒素.WO(Appl. )96-25538, 1996． 8． 22
• [56] 尤尼吉卡.JP.J8-134718,1996． 5． 28
• [57] 郡是产业.JP. J8-100345, 1996 .4． 16
• [58] 近江健桥等. JP. J8-92820, 1996． 4． 9
• [59] Agboh O C. Polym adv Techn . 1997 .8(6) :355
• [60] Fagles Dana . Text Res J. 1996,66(4) :277