细菌纤维素纳米复合材料的研究进展Progress on Study of Bacterial Cellulose Nanocomposite
张秀菊,林志丹,陈文彬,容建华
ZHANG Xiu-ju,LIN Zhi-dan,CHEN Wen-bin,RONG Jian-hua(College of Science and Engineering
摘要(Abstract):
细菌纤维素是一种新型微生物合成材料,与植物纤维素相比,无木质素和半纤维素等伴生产物,同时具有高结晶度和高聚合度、超精细的网络结构、极高的抗张强度和优异的生物相容性,在食品、医药、纺织、化工等方面有着巨大的应用潜力。利用细菌纤维素的纳米网络结构和超强弹性模量等特点可以用于增强聚合物基体,制备无机纳米粒子的模板、分散载体以及用于制备透明增强复合材料。重点介绍了细菌纤维素与高分子材料、无机纳米材料等的纳米复合材料的研究进展,阐述了现阶段存在的问题并对该种复合材料的发展趋势进行了展望。
Bacterial cellulose is a novel material synthesized by microbe.Compared with plant cellulose,it is free of lignin and semicellulose and other impurities.It presents unique properties such as high mechanical strength and an extremely fine and pure fiber network structure and good biocompatibility,which have potential applications in food,medicine,texitile and chemical industry.Due to its nanometer network structure and hign elastic modulus bacterial cellulose could be used as reinforcements in polymer composites and template and dispersing carrier for preparing inorganic nanoparticle.Progress on study of nanocomposites of bacterial cellulose with polymer and inorganic nanoparticle is introduced mainly.Problems existing in each work are discussed while the research emphsese are prospected in future in the correlative area.
关键词(KeyWords):
细菌纤维素;复合材料;增强;纳米
bacterial cellulose,composite,reinforcement,nanometer
基金项目(Foundation): 国家自然科学基金(20604010);; 广东省自然科学基金项目(8451063201000041)
作者(Author):
张秀菊,林志丹,陈文彬,容建华
ZHANG Xiu-ju,LIN Zhi-dan,CHEN Wen-bin,RONG Jian-hua(College of Science and Engineering
DOI: 10.16090/j.cnki.hcxw.2010.01.010
参考文献(References):
- [1]Yamanaka S,Watanabe K,Kitamura N,et al.Production of bacterial cellulose by acetobacter xylinum from watermelon peel juice[J].J Mater Sci,1989,24:3141-3145.
- [2]Rebello C,Almeida D A,et al.Biofill um novo substituto de pele.[J].ReV Bras Cir,1987,77(6):407-414.
- [3]Novaes A B J,Novaes A B.Bone formation over a TiAl6V4implant placed into an extraction-socket in association with membrane therapy.[J].Clin Oral Implant Res,1993,4:106-110.
- [4]Klemm D,Schumann D,Udhardt U,Marsch S.Bacterial synthesized cellulose-artificial blood vessels for microsurgery[J].Prog Polym Sci,2001,26:1561-1603.
- [5]Fontana J D,Desouza A M,Fontama C K,et al.Acetobacter cellulosepellicle as a temporary skin substitute.[J].Appl Biochem Biotechnol,1990,24:253-264.
- [6]胡晓燕,曲音波.细菌纤维素的研究进展[J].纤维素科学与技术,1998,6(4):56-64.
- [7]张震元.美国研究开发生物聚合物的动向[J].中国生物工程杂志,1987,(1):66.
- [8]赵梓年,王红.聚乳酸/细菌纤维素复合材料制备研究[J].塑料工业,2008,36(12):11-13.
- [9]Kim Y,Jung R,Kim H S,et al.Transparent nanocomposites prepared by incorporating microbial nanofibrils into poly(L-lactic acid).[J].Current Applied Physics,2009,9:69-71.
- [10]Gray D G.Transcrystallization of polypropylene at cellulose nanocrystal surfaces.[J].Cellulose,2008,15:297-301.
- [11]Lauad M,Contos V S,et al.Characterization of nanocellulose-rein-forced shape memory polyurethanes.[J].Poly Int,2008,57:651-659.
- [12]Park W P,Kang M S,Kim H S,et al.Electrospinning of poly(ethy-lene oxide)with bacterial cellulose whiskers[J].Macromol Symp,2007:249-250,289-294.
- [13]Brown E E,Laborie M P G,et al.Bioengineering bacterial cellulose/poly(ethylene oxide)nanocomposites[J].Biomacromolecules,2007,8(10):3074-3081.
- [14]Millon L E,Guhados G,Wan W K,et al.Polyvinyl alcohol-bacterial cellulose nanocomposite for biomedical applications[J].Journal of Biomedical Materials Research Part B:Applied Biematerials,2008:444-452.
- [15]Wiegand C,Elsner P,Christina U,et al.Protease and ROS activities influenced by a composite of bacterial cellulose and collagen type I in vitro[J].Cellulose,2006,13:689-696.
- [16]Luo H L,Xiong G Y,Huang Y,et al.Preparation and characteriza-tion of a novel COL/BC composite for potential tissue engineering scaf-folds[J].Materials Chemistry and Physics,2008,110:193-196.
- [17]Phisalaphong M,Suwanmajo T,et al.Synthesis and characterization of bacterial cellulose/alginate blend membranes.[J].Journal of Applied Polymer Science,2008,107:3419-3424.
- [18]Nakayama A,Kakugo A,et al.High mechanical strength double-network hydrogel with bacterial cellulose[J].Advanced Functional Materi-als,2004,14(11):1124-1128.
- [19]Pommet M,Juntaro J,Heng J Y,et al.Surface modification of natu-ral fibers using bacteria:depositing bacterial cellulose onto natural fibers to create hierarchical fiber reinforced nanocomposites[J].Biomacro-molecules,2008,9(6),1643-1651.
- [20]Gindl W,Keckes J,et al.Tensile properties of cellulose acetate bu-tyrate composites reinforced with bacterial cellulose[J].Composite Science and Technology,2004,64:2407-2413.
- [21]Yano H,Sugiyama J,et al.Optically transparent composites rein-forced with networks of bacterial nanofibers[J].Advanced Materials,2005,17(2):153-155.
- [22]Nogi M,Handa K,Nakagaito A N,et al.Optically transparent bionanofiber composites with low sensitivity to refractive index of the polymer matrix[J].Applied Physics Letters,2005,87:243110.
- [23]黄远,万怡灶,扈立等.仿生矿化法制备可降解羟基磷灰石/氧化细菌纤维素[J].复合材料学报,2008,25(6):140-145.
- [24]Nakagaito A N,Iwamoto S,et al.Bacterial cellulose:the ultimate nano-scalar cellulose morphology for the production of high-strength composites[J].Applied Physics Materials Science and Processing,2005,80:93-97.
- [25]Wan Y Z,Hong L,et al.Synthesis and characterization of hydroxyapatite-bacterial cellulose nanocomposites[J].Composites Science and Technology,2006,66(11-12):1825-1832.
- [26]Wan Y Z,Huang Y,Yuan C D,et al.Biomimetic synthesis of hydroxyapatite/bacterial cellulose nanocomposites for biomedical applications[J].Materials Science and Engineering,2007,27(4):855-864.
- [27]Pinto R J B,Marques P A A P,et al.Electrostatic assembly and growth of gold nanoparticles in cellulosic fibers[J].Journal of Colloid and Interface Science,2007,312:506-512.
- [28]Yoon S H,Jin H J,Kook M C,et a1.Electrically conductive bacterial cellulose by incorporation of carbon nanotubes[J].Biomacromolecules,2006,7(4):1280-1284.