涤纶织物表面改性及其对水中Cu~(2+)的吸附研究Surface Modification of Polyester Fabric and its Absorption Properties of Cu~(2+)
董朝红,翟海群,朱平,李娜娜,王磊
DONG Chao-hong1,2,ZHAI Hai-qun1,ZHU Ping1,3
摘要(Abstract):
以柠檬酸作为交联剂,次亚磷酸钠作为催化剂,将β-环糊精整理到涤纶织物上。通过单因素分析发现,织物增重率与β-环糊精浓度、柠檬酸浓度、催化剂浓度、焙烘时间及焙烘温度有关。确定最佳整理工艺为:β-环糊精90 g/L,柠檬酸100 g/L,催化剂30 g/L,焙烘温度180℃,焙烘时间20 min。经过整理后的织物对Cu2+有较好的吸附能力。
With citric acid(CA) as cross-linking agent,sodium hypophosphite as a catalyst,β-CD was fixed on the surface of polyester fabric.The effects of factors such as concentration of β-CD,CA and sodium hypophosphite,cured time and temperature on the finished fabric were discussed as well.The optimum conditions were β-CD 90 g/L,CA100 g/L,sodium hypophosphite 30 g/L,cured at 180 ℃ for 20 min.The results indicated that the fabric had good absorption of Cu2+.
关键词(KeyWords):
β-环糊精;柠檬酸;涤纶织物;Cu2+;吸附
β-cyclodextrin,citric acid,polyester fabric,Cu2+,absorption
基金项目(Foundation):
作者(Author):
董朝红,翟海群,朱平,李娜娜,王磊
DONG Chao-hong1,2,ZHAI Hai-qun1,ZHU Ping1,3
DOI: 10.16090/j.cnki.hcxw.2011.03.014
参考文献(References):
- [1]邱红娟.β-环糊精的匀染作用研究[J].印染,2008,34(4):13-16.
- [2]王春梅.环糊精在染整加工中的应用[J].丝绸,2005,49(12):35-37.
- [3]朱平.功能纤维及功能纺织品[M].北京:中国纺织出版社,2006.
- [4]李晶.β-环糊精与织物接枝方法的研究[D].上海:东华大学,2007:1-59.
- [5]B Martel,M Morcellet,D Ruffin,L Ducoroy and M Weltrowski.Finishing of polyester fabrics with cyclodextrins and polycarboxylic acidsas crosslinking agents[J].Journal of Inclusion Phenomena andMacrocyclic Chemistry,2002,44:443-446.
- [6]魏俊富,胡容霞,张政朴.聚四氟乙烯基离子交换纤维及其对Pb2+、Cu2+吸附性能研究[J].天津工业大学学报,2005,24(1):4-8.