唐雯,俞昊,朱美芳,张雯
TANG Wen1,YU Hao1,ZHU Mei-fang1,2

• 1:东华大学材料科学与工程学院
• 2:纤维改性国家重点实验室

摘要(Abstract)：

利用静电纺丝设备,在仅改变滚筒收集装置的转速的条件下,制得不同有序度的聚丙烯腈超细纤维毡,利用扫描电子显微镜来观察纤维的直径及形态,得出纤维排列的有序度随滚筒转速的增加而提高。再将制得的聚丙烯腈纳米纤维毡在不同温度下预氧化,最后经过碳化,得到超细碳纤维毡,分析在不同滚筒转速下收集的不同有序度的超细碳纤维毡的力学性质。通过拉伸试验,得出随着转速的增加,纤维毡的拉伸强度有所增加。
In this thesis the PAN fiber web in uniaxially aligned arrays were produced by electrospinning equipment under the condition of only different rolling speeds.The diameter and morphology of the ultrafine fibers in the PAN electrospinning fiber mats were observed by scanning electron microscopy(SEM).SEM images showed that the degree of ordering increased with the increasing rolling speed.And then the PAN fiber webs were pre-oxidated to different temperatures in order to find the optimal temperature.After the last step of carbonation,the carbon fiber webs were obtained,which were measured to test the mechanical performance.The result revealed the strength performance was increased by the increasing rolling speed.

关键词(KeyWords)： 聚丙烯腈;静电纺丝;预氧化;碳化;力学性能
PAN,electrospinning,pre-oxidation,carbonation,mechanical performance

Abstract:

Keywords:

基金项目(Foundation): 中央高校基本科研业务费专项资金项目(项目编号A01-1)

作者(Author): 唐雯,俞昊,朱美芳,张雯
TANG Wen1,YU Hao1,ZHU Mei-fang1,2

DOI: 10.16090/j.cnki.hcxw.2010.12.003

参考文献(References)：

• [1]Max L.Lecture presented at conference.Global Outlook for CarbonFiber.2002,Raleigh,NC.USA.
• [2]陈红燕,王继辉.纳米碳纤维及其在聚合物中的应用[J].玻璃钢/复合材料,2005,(3):41-44.
• [3]王强华.纳米碳纤维用于低成本工程聚合物[J].玻璃钢,2009,(1):28-31.
• [4]Lidholobov A,et al.New carbon-carbonaccous composites forcatalysis and adsorption[J].React Kinet Cata Lett,1995,54(2):381-411.
• [5]Fan Y Y,Liao B,Liu M,et al.Hydrogen uptake in vaporgrown carbonnanofibers[J].Carbon,1999,37:1 649-1 652.
• [6]Chambers A,Park C,Baker R,et al.Hydrogen storage in graphitenanofibers[J].Phys Chem B,1998,102(22):253-256.
• [7]舒卫国.碳纤维复合材料在民品中的应用[J].纤维复合材料,2004,(3):54-59.
• [8]Eun J R,Kay H A,et al.Anisotropic electrical conductivity ofMWCNT/PAN nanofiber paper[J].Chemical Physics Letters,2005,8(413):188-193.
• [9]Smith R C,Carey J D,et al.Electron field emission from roomtemperature grown carbon nanofibers[J].Appl Phys Lett,2004,95(6):153-157.
• [10]Hammel E,Tang X,Tramipe R Me,t al.Carbon nanofibers forComposite applieations[J].Carbon,20044,2:1 153-1 158.
• [11]Chun L,Reneker D H,et al.Carbon nanotubes on carbon nanofibers:a novel structure ased on electrospun polymer nanofibers[J].Adv Mater,1999,46:31-36.
• [12]Wang Y,Santiago-aviles J J.Large negative magnetoresistance andtwo-dimensional weak lcalization in carbon nanofibers fabrieated usingelectrospinning[J].Appl Phys Lett,2003,94(3):1 721-1 727.
• [13]Yu W,et al.Raman characterization of carbon nanofibers preparedusing electrospinning[J].Synthetic Metals,2003,(138):423-427.
• [14]Shuying G,et al.Preparation and surface structures of carbonnanofibers produced from electrospun PAN precursors[J].New CarbonMaterials,2008,23(2):171-176.
• [15]杨茂伟,王成国,王延相等.聚丙烯睛原丝的预氧化过程研究[J].合成纤维工业,2005,28(6):5-6.