聚丙烯腈/醋酸纤维素共混纤维亲水性研究Research on the Hydrophilic Fiber of Polyacrylonitrile/cellulose Acetate
杨炳超,肖长发,安树林,贾广霞
YANG Bing-chao, XIAO Chang-fa, AN Shu-lin, JIA Guang-xia (Department of Material Science
摘要(Abstract):
将丙烯腈/醋酸乙烯酯/潜交联剂三元共聚物与醋酸纤维素共混纺丝,经交联水解处理后得到含交联结构的亲水性聚丙烯腈/醋酸纤维素共混纤维。分析了纤维的吸水性能,并利用傅里叶红外光谱仪、扫描电镜、单纤强力仪等测试仪器测试了其它性能。
The blended polymer of acrylonitrile(AN)/ vinyl acetate(VAc)/ potential crosslinker and cellulose acetate(CA)were spun to fibers by wet spinning. The hydrophilic fiber of polyacrylonitrile/cellulose acetate which contain three-dimensional framework was prepared by crosslinking and hydrolyzing. The properties of the hydrophilic fiber were tested with FTIR, SEM and the single fiber strength tester.
关键词(KeyWords):
聚丙烯腈;醋酸纤维素;共混;亲水性
polyacrylonitrile, cellulose acetate, blends, hydrophilic
基金项目(Foundation):
作者(Author):
杨炳超,肖长发,安树林,贾广霞
YANG Bing-chao, XIAO Chang-fa, AN Shu-lin, JIA Guang-xia (Department of Material Science
参考文献(References):
- [1]顾利霞.亲水性纤维[M].北京:中国石化出版社,1997.235.
- [2]Young Se Oh.Modified polyacrylonitrile blends with cellulose acetate:fibers'properties[J].Journal of Applied Polymer Science,1997,64:1937-1946.
- [3]Byung Kyu Kim.Modified polyacrylonitrile blends with cellulose acetate:blend properties[J].Polymer,2000,41:385-390.
- [4]Xiao Chang fa.Microvoid formation of acrylic copolymer(PAC)/cellulose acetate(CA)blend fibers[J].Journal of Applied Polymer Science,1990,41:439-444.
- [5]李留忠.废腈纶水解物的制备与表征[J].高分子材料科学与工程,2003,19(4):169-172.
- [6]杨大川,曹建平.聚丙烯腈碱性条件下的水解研究[J].北京化工学院学报(自然科学版),1990,17(1):13-18.
- [7]Xiaoyu Hu,Changfa Xiao.Study on superabsorbent polyacrylonitrile-based fibre[J].Indian Journal of Fibre&Textile Research,2005,30:207-210.
- [8]S Zhu,Y Tian,A E Hamielec.Radical concentrations in free radical copolymerization of MMA/EGDMA[J].Polymer,1990,31(1):154~159
- [9]G T Sivy,M M Coleman.Fourier Transform IR studies of the degradution of polyacrylonitrile copolymer-Ⅱ[J].Carbon,1981,19(1):127-131.
- [10]吴培熙,张留城.聚合物共混改性[M].北京:中国轻工业出版社,2001.23.