田孟琪,杨建忠,高宾
TIAN Meng-qi,YANG Jian-zhong,GAO Bin

• 1:西安工程大学理学院
• 2:西安工程大学纺织与材料学院

摘要(Abstract)：

采用空气低温等离子体改善超高相对分子质量聚乙烯(UHMWPE)短纤维的黏着性,设计正交试验对改性后纤维的黏着性进行测试与分析,确定出较优试验方案;然后对未处理和经较优方案改性后的UHMWPE短纤维的表面形貌、表面化学成分、表面润湿性和强伸性进行测试分析。结果表明:空气低温等离子体改性UHMWPE短纤维黏着性的较优处理条件为功率50 W、压强15 Pa、反应时间120 s,此时,纤维的剥离功是未处理的4.14倍,黏着性得到了大幅度的提升,且单纤维强力损失率仅为3.29%;经较优方案处理后,纤维表面的粗糙程度有所增加,表面润湿性有明显改善,纤维表面的C元素含量明显减少,O、N元素含量有所增加,且出现了相对含量为22.2%的C=O官能团,有利于UHMWPE短纤维黏着性的改善。
The air low temperature plasma was used to improve the adhesion of ultra-high molecular weightpolyethylene(UHMWPE) short fiber. The fiber adhesion was tested and analyzed by orthogonal test, andthe optimum testing condition was picked up. Then, some properties of short fibers untreated and modifiedby the optimum testing condition were tested such as surface morphology, surface chemical composition,surface wettability and tensile strength. The results showed that the optimum testing conditions were 50 W,15 Pa, 120 s to improve the adhesion of UHMWPE short fibers treated by air low temperature plasma. Un-der the conditions, adhesion was greatly improved with stripping work being 4.14 times to the untreated fi-bers, and the strength loss rate of single fiber was only 3.29%. After treated by the optimum testing condi-tion, the surface roughness of the fibers increased, and the surface wettability improved obviously; the sur-face contents of O and N increased, the content of C decreased, and a functional group(C=O) was found witha content of 22.2%. All these factors were propitious to the adhesion improvement of UHMWPE short fibers.

关键词(KeyWords)： 等离子体改性;UHMWPE短纤维;黏着性;表面性能
plasma modification;UHMWPE short fiber;adhesion;surface property

Abstract:

Keywords:

基金项目(Foundation): 陕西省教育厅自然科学专项(15JK1293)

作者(Author): 田孟琪,杨建忠,高宾
TIAN Meng-qi,YANG Jian-zhong,GAO Bin

DOI: 10.16090/j.cnki.hcxw.2017.05.009

参考文献(References)：

• [1]罗益锋.3大高性能纤维及其应用新动向与对策建议[J].高科技纤维与应用,2012,37(6):1-7.
• [2]任煜,张银.超高相对分子质量聚乙烯纤维表面改性研究进展[J].合成纤维工业,2016,39(4):53-58.
• [3]TEODORN Steluta,KUSANO Yukihiro,ROZLOSNIK Noemi,et al.Continuous plasma treatment of ultra-high-molecular-weight polyethylene(UHMWPE)fibres for adhesion improvement[J].Plasma Processes and Polymers,2009(6):375-381.
• [4]YAAN Necla,OZDOGAN Esen,SEVENTEKIN Necdet,et al.Surface modification methods for improvement of adhesion to textile fibers[J].Tekstil ve Konfeksiyon,2008,18(2):89-93.
• [5]顾如茜,于俊荣,陈蕾,等.低温等离子体对超高分子聚乙烯纤维表面改性研究[J].高分子通报,2011(8):96-102.
• [6]王红红,孙润军.空气等离子体处理芳纶Ⅲ的性能研究[J].合成纤维工业,2016,39(6):30-33.
• [7]任煜,张银,王晓娜,等.空气介质阻挡放电对超高分子量聚乙烯纤维表面性能及粘结力的影响研究[J].高分子学报,2016(10):1439-1446.
• [8]田孟琪,杨建忠.等离子体处理超高相对分子质量聚乙烯纤维[J].合成纤维,2013,42(4):16-19.
• [9]田孟琪,杨建忠.空气冷等离子体处理对UHMWPE纤维性能与结构的影响[J].高科技纤维与应用,2013,38(4):34-37.
• [10]杨建忠,田孟琪.低温等离子体处理对高强聚乙烯纤维表面影响的研究[J].高科技纤维与应用,2014,39(4):32-35,39.
• [11]于伟东.涤纶等离子体表面改性及粘结性研究[J].中国纺织大学学报,1994,20(1):65-71.
• [12]杨建忠,李健,刘梦丽,等.低温等离子体改性PBO纤维黏着性初步研究[J].高科技纤维与应用,2014,39(3):46-48,62.
• [13]SUN Youyi,LIANG Qing,CHI Huijun,et al.The application of gas plasma technologies in surface modification of aramid fiber[J].Fibers and Polymers,2014,15(1):1-7.
• [14]岳震南,黄英,王岩,等.低温等离子体对PBO纤维表面改性的研究[J].玻璃钢/复合材料,2011(1):16-19.
• [15]KIM Jun Young,LEE Yongbeom,LIM Dae Young.Plasma-modified polyethylene membrane as a separator for lithium-ion polymer battery[J].Electrochimica Acta,2009(54):3714-3719.
• [16]何洋,粱国正,吕生华,等.超高分子量聚乙烯纤维表面的铬酸处理及表征[J].材料科学与工艺,2005,13(5):82-85,90.
• [17]MORALES J,OLAYO M G,CRUZ G J,et al.Plasma modification of cellulose fibers for composite materials[J].Journal of Applied Polymer Science,2006,101(6):3821-3828.