PET降解研究STUDY ON DEGRADATION OF PET
王晓春,张健飞
WANG Xiao-chun, ZHANG Jian-fei (Tianjin Polytechnic University 300160)
摘要(Abstract):
聚对苯二甲酸乙二酯为目前应用最广泛的合成有机物之一。但由于其废弃物数量巨大且对大气和微生物的抵抗性很强 ,对环境造成了严重的压力。综述了PET的各种降解方法 ,着重介绍了可使PET进入生态循环 ,从根本上解决其对环境影响的生物降解方法。
Poly(ethylene terephthalate)has grown rapidly to become one of the most widely used man-made organism in the world.However,post-consumer PET products have a problem to environmental influences.This paper is a review of degradation methods of post-consumer PET.The chemical degradation and biodegradation are the main ways this field.
关键词(KeyWords):
PET;水解;醇解;氨解;热裂解;微生物降解;酶降解
PET; hydrolysis; alcoholysis; aminolysis; thermal degradation; biodegradation
基金项目(Foundation):
作者(Author):
王晓春,张健飞
WANG Xiao-chun, ZHANG Jian-fei (Tianjin Polytechnic University 300160)
DOI: 10.16090/j.cnki.hcxw.2002.06.002
参考文献(References):
- [1] 纺织化纤科技信息.2002,(5).
- [2] AllenNS ,EdgeM ,etal.PolymDegradStab,1994,43(2):229.
- [3] PusztaszeriSF .USP 4355175,1982.
- [4] SharmaND ,VaidyaAA ,etal.IndPatent163385,1985.
- [5] YoshiokaT ,SatoT ,OkuwakiA .JApplPolymSci,1994,52:1353.
- [6] AlterH .EncyclopediaofPolymerScienceandEngineering;WileyInterscience:NewYork,1986,5:103.
- [7] PitatJ ,HolcikV ,etal.GBPatent822834.1959.
- [8] CampanelliJR ,CooperDG ,etal.JApplPolymSci,1994b,53:985.
- [9] CampanelliJR ,CooperDG ,etal.ANTEC 1992,50:270.
- [10] MichalskiA .WlChem.1990,63:387(inPolish).
- [11] 张师民.聚酯的生产和应用.北京:中国石化出版社,1997:288.
- [12] KamalMR ,LaiFookRA ,YalcinyuvaT .ANTEC 1994,2896.
- [13] TadafumiA ,OsamuS ,etal.KagakuKogakuRonbushu.1997,23:505.
- [14] DebruinBR ,NaujokasAA ,GambleWJ .USP 5432203,1995.
- [15] 曹维良,张敬畅,李勇.北京化工大学学报,1999,26(4).
- [16] 王汉夫,孙辉等.吉林大学自然科学学报,2000,(4):39.
- [17] ChenJ ,etal.JApplPolymSci,1991,42:1501.
- [18] CollinsMJ ,ZeronianSH ,MarshallML .JMacromolSciChem,1991,A28:775.
- [19] BlackmonKP ,etal.EP 365842,1988.
- [20] IndPatent154774.1985.
- [21] 黄发荣,陈涛,沈学宁.高分子材料的循环利用.化学工业出版社,2000:273.
- [22] CBirdladeanu,CVasile,IASchneider.MakromolChem,1976,177:121.
- [23] TokiwaY ,SuzukiT .Nature,1977,270:76.
- [24] ReedAM ,GildingDK .Polymer,1981,22:499.
- [25] NagataM ,KitotsukuriT ,etal.EurPolymJ ,10:1701.
- [26] JunHS ,BOKim,etal.JEnviroPolymDegrad.1994a,2(1):9.
- [27] DE 19935156Al.2000.
- [28] HuangSJ,ByrneCA .JApplPolymSci,1980,25:1951.
- [29] 小田耕平.加工技术(日),1999,(5):14.
- [30] MeeYoungYoon,JimKellis,AJPoulose.presentedatAATCCSymposium,2001.