化纤油剂中烷基磺酸盐的分离与分析Separation and Analysis of Alkane Sulphonate in Finishes for Chemical Fiber
徐杰;唐福伟;叶达峰;赵静文;
XU Jie;TANG Fu-wei;YE Da-feng;ZHAO Jing-wen;Zhejiang Lvkean Chemical Co., Ltd.;Zhejiang Huangma Technology Co., Ltd.;
摘要(Abstract)：
采用阴离子交换色谱法成功地将化纤油剂中的仲烷基磺酸盐分离出来，综合应用离子类型鉴定、红外光谱、液质联用仪以及热裂解气质联用仪确定了它们的结构。试验表明，热裂解-气质联用技术可以很好地确定仲烷基磺酸钠的分子结构，仲烷基磺酸钠在油剂样品中的质量分数约为3.1%。
The secondary alkane sulphonates in finishes for chemical fiber were separated by anion-exchange chromatography. Their structure was determined by ionicity determination, infrared spectrum, liquid chromatography-mass spectrometry and pyrolysis-gas chromatography mass spectrometry. The results show that the molecular structure of sodium secondary alkyl sulfonate can be well determined by pyrolysis/gas chromatography-mass spectrometry. The mass fraction of sodium secondary alkyl sulfonate in finish samples is approximately 3.1%.
关键词(KeyWords)：
化纤油剂;烷基磺酸盐;分离;定性
finish for chemical fiber;alkane sulphonate;separation;qualitative analysis
基金项目(Foundation):
作者(Authors):
徐杰;唐福伟;叶达峰;赵静文;
XU Jie;TANG Fu-wei;YE Da-feng;ZHAO Jing-wen;Zhejiang Lvkean Chemical Co., Ltd.;Zhejiang Huangma Technology Co., Ltd.;
DOI: 10.16090/j.cnki.hcxw.2023.03.004
参考文献(References)：
- [1]蔡继权.我国化纤油剂的生产现状与发展趋势(上)[J].纺织导报,2012(6):116-118.
- [2]丁竹君.国产涤纶FDY纺丝油剂配制工艺的研究[J].合成纤维,2019, 48(11):23-25.
- [3]任华明,李德绵.实用化学纤维油剂[M].北京:纺织工业出版社,1987:232-233.
- [4]刘燕军,姜鹏飞,郑帼,等.新型锦纶工业丝油剂的组成及结构剖析[J].天津工业大学学报, 2015, 34(4):22-26.
- [5]王建平,朱逸生.化纤油剂剖析方法[J].合成纤维, 1999, 28(5):44-49.
- [6]刘方方,曹亚琼,王超.化纤油剂的剖析方法[J].印染助剂，2008(5):40-44.
- [7]郭建国. EO/PO无规聚醚的合成表征及应用研究[D].上海:东华大学, 2011.
- [8]郑学芳,廉琪,朱红,等.新型三次采油用环烷基磺酸盐的制备与评价[J].高校化学工程学报, 2013, 27(6):1094-1099.
- [9]帕拉马尼克B N,甘古利A K,格罗斯M L.电喷雾质谱应用技术[M].蒋宏键,俞克佳,译.北京:化学工业出版社, 2005:29-30.
- [10]钟雷,丁悠丹.表面活性剂及其助剂分析[M].杭州:浙江科学技术出版社, 1986:370-372.