王军庆,李龙,钱祥宇
WANG Jun-qing,LI Long,QIAN Xiang-yu

• 1:西安工程大学纺织科学与工程学院
• 2:西安工程大学功能性纺织材料及制品教育部重点实验室
• 3:东华大学纺织学院

摘要(Abstract)：

柔性超级电容器具有灵活性高、充放电速度快、功率密度大、绿色环保、安全性高、成本低等优越性能,在可穿戴电子设备领域具有重要的应用价值。纯导电聚合物电极材料的循环稳定性和电化学性能有限,而导电聚合物复合其他导电材料形成的复合电极能改善其循环稳定性和电化学性能。根据近年来不同导电聚合物基柔性超级电容器电极材料的研究进展,介绍了以导电聚合物(聚苯胺、聚吡咯和聚噻吩)基复合材料作为柔性超级电容器电极材料的制备及其性能研究。
The flexible supercapacitors have the advantages of high flexibility,fast charge and discharge speed,high power density,green environment protection,high safety and low cost,which have great application value in the field of wearable and portable electronic devices.The cyclic stability and electrochemical properties of the pure conductive polymer electrode materials were limited,while the composite electrode formed by the conductive polymer and other conductive materials improved its cyclic stability and electrochemical properties.Based on the recent progress of electrode materials for flexible supercapacitors based on different conducting polymers,the preparation and properties of electrode materials based on conducting polymers(polyaniline,polypyrrole and polythiophene) were introduced.

关键词(KeyWords)： 柔性超级电容器;电极材料;聚苯胺;聚吡咯;聚噻吩
flexible supercapacitor;electrode material;polyaniline;polypyrrole;polyhiophene

Abstract:

Keywords:

基金项目(Foundation):

作者(Author): 王军庆,李龙,钱祥宇
WANG Jun-qing,LI Long,QIAN Xiang-yu

DOI: 10.16090/j.cnki.hcxw.2020.08.017

参考文献(References)：

• [1]宋利黎,韩颖慧,李玉娟,等.柔性超级电容器电极材料研究进展[J].电源技术,2019,43(2):354-356.
• [2]叶星柯,周乾隆,万中全,等.柔性超级电容器电极材料与器件研究进展[J].化学通报,2017,80(1):10-33,76.
• [3]杨静,刘艳君.织物基柔性超级电容器电极材料的研究进展[J].棉纺织技术,2017,45(10):79-84.
• [4]于婷,周亚丽,关晓琳,等.柔性超级电容器电极材料制备方法研究进展[J].功能材料,2019,50(8):8051-8064.
• [5]张笑寒.柔性固态超级电容器材料及部件的发展[J].集成电路应用,2020,37(2):26-29.
• [6]ALLAGUI A,ELWAKIL A S,FREEBORN T J.Supercapacitor reciprocity and response to linear current and voltage ramps[J].Electrochimica Acta,2017,258:1081-1085.
• [7]刘永坤,姚菊明,卢秋玲,等.碳纤维基柔性超级电容器电极材料的应用进展[J].储能科学与技术,2019,8(1):47-57.
• [8]陈静,郭红霞,毛卫国,等.石墨烯基超级电容器的发展现状与战略研究[J].中国工程科学,2018,20(6):75-81.
• [9]郭慰彬,陈嘉炼,刘金玲,等.超级电容器用碳基电极材料研究进展[J].电子元件与材料,2019,38(1):1-8.
• [10]RAJ C J,RAJESH M,MANIKANDAN R,et al.Two-dimensional planar supercapacitor based on Zinc oxide/manganese oxide core/shell nanoarchitecture[J].Electrochimica Acta,2017,247:949-957.
• [11]TAJIK S,DUBAL D P,GOMEZ-ROMERO P,et al.Nanostructured mixed transition metal oxides for high performance asymmetric supercapacitors:Facile synthetic strategy[J].International Journal of Hydrogen Energy,2017,42(17):12384-12395.
• [12]ABDAH M A A M,ZUBAIR N A,AZMAN N H N,et al.Fabrication of PEDOT coated PVA-GO nanofiber for supercapacitor[J].Materials Chemistry and Physics,2017,192:161-169.
• [13]SINGH P,PAL K.Multiphase nanostructured PANI anchored@CVD grown MWCNT on r GO coated nickel foam for binder free supercapacitor electrode[J].Electrochimica Acta,2017,242:47-55.
• [14]冯辉霞,王滨,谭琳,等.导电聚合物基超级电容器电极材料研究进展[J].化工进展,2014,33(3):689-695.
• [15]张海涛,向翠丽,邹勇进,等.纳米导电聚合物超级电容器研究进展[J].传感器与微系统,2016,35(8):1-3,7.
• [16]冯鑫.导电聚合物超级电容器电极材料研究进展[J].化工技术与开发,2016,45(5):47-49,64.
• [17]MENG Q,CAI K,CHEN Y,et al.Research progress on conducting polymer based supercapacitor electrode materials[J].Nano Energy,2017,36:268-285.
• [18]HOU L,ZHI X,ZHANG W,et al.Boosting the electrochemical properties of polyaniline by one-step co-doped electrodeposition for high performance flexible supercapacitor applications[J].Journal of Electroanalytical Chemistry,2020,863:114064.
• [19]HU C L,ZHANG X Y,LIU B,et al.Orderly and highly dense polyaniline nanorod arrays fenced on carbon nanofibers for all-solid-state flexible electrochemical energy storage[J].Electrochimica Acta,2020,338:12.
• [20]YU J H,XIE F F,WU Z C,et al.Flexible metallic fabric supercapacitor based on graphene/polyaniline composites[J].Electrochimica Acta,2018,259:968-974.
• [21]WEI G,GONG S S,TANG J,et al.Preparation by pulsed current electrochemical polymerisation and properties of ordered comb-shaped polyaniline/carbon fibres composites for flexible supercapacitor electrodes[J].Transactions of the Institute of Metal Finishing,2020,98(2):98-104.
• [22]OU D W,LIU J Q,YAN J,et al.Construction of three-dimensional graphene like carbon on carbon fibers and loading of polyaniline for high performance asymmetric supercapacitor[J].Electrochimica Acta,2020,335(C):135679.
• [23]SHAO L,WANG Q,MA Z L,et al.A high-capacitance flexible solidstate supercapacitor based on polyaniline and Metal-Organic Framework(Ui O-66)composites[J].Journal of Power Sources,2018,379:350-361.
• [24]IQBAL N,WANG X F,BABAR A A,et al.Polyaniline enriched flexible carbon nanofibers with core-shell structure for high-performance wearable supercapacitors[J].Advanced Materials Interfaces,2017,4(24):8.
• [25]WU Z F,HE K W,WU Y Z,et al.A high performance flexible recyclable supercapacitor with polyaniline by casting in unconventional proportion[J].Journal of Power Sources,2019,442:9.
• [26]GU Y F,ZHANG Y,SHI Y H,et al.3D all printing of polypyrrole nanotubes for high mass loading flexible supercapacitor[J].Chemistryselect,2019,4(36):10902-10906.
• [27]MAO J W,LIU C C,CHENG C,et al.A porous and interconnected polypyrrole film with high conductivity and ion accessibility as electrode for flexible all-solid-state supercapacitors[J].Chemelectrochem,2019,6(21):5479-5485.
• [28]SUN Y Y,JIA D D,ZHANG A T,et al.Synthesis of polypyrrole coated melamine foam by in-situ interfacial polymerization method for highly compressible and flexible supercapacitor[J].Journal of Colloid and Interface Science,2019,557:617-627.
• [29]FU Q J,WANG Y Y,LIANG S B,et al.High-performance flexible freestanding polypyrrole-coated CNF film electrodes for all-solid-state supercapacitors[J].Journal of Solid State Electrochemistry,2020,24(3):533-544.
• [30]ZHANG Y H,SHANG Z,SHEN M X,et al.Cellulose nanofibers/reduced graphene uxide/polypyrrole aerogel electrodes for high-capacitance flexible all-solid-state supercapacitors[J].Acs Sustainable Chemistry&Engineering,2019,7(13):11175-11185.
• [31]CHEN L,CHEN L N,AI Q,et al.Flexible all-solid-state supercapacitors based on freestanding,binder-free carbon nanofibers@polypyrrole@graphene film[J].Chemical Engineering Journal,2018,334:184-190.
• [32]MA L N,LIU R,NIU H J,et al.Flexible and freestanding electrode based on polypyrrole/graphene/bacterial cellulose paper for supercapacitor[J].Composites Science and Technology,2016,137:87-93.
• [33]PURKAIT T,SINGH G,KAMBOJ N,et al.All-porous heterostructure of reduced graphene oxide-polypyrrole-nanoporous gold for a planar flexible supercapacitor showing outstanding volumetric capacitance and energy density[J].Journal of Materials Chemistry A,2018,6(45):22858-22869.
• [34]YANG S S,SUN L J,AN X H,et al.Construction of flexible electrodes based on ternary polypyrrole@cobalt oxyhydroxide/cellulose fiber composite for supercapacitor[J].Carbohydrate Polymers,2020,229:115455.
• [35]HUANG Y,HU H,HUANG Y,et al.From industrially weavable and knittable highly conductive yarns to large wearable energy storage textiles[J].Acs Nano,2015,9(5):4766-4775.
• [36]WU K Z,ZHAO J J,WU R T,et al.The impact of Fe3+doping on the flexible polythiophene electrodes for supercapacitors[J].Journal of Electroanalytical Chemistry,2018,823:527-530.
• [37]VIJETH H,ASHOKKUMAR S P,YESAPPA L,et al.Flexible and high energy density solid-state asymmetric supercapacitor based on polythiophene nanocomposites and charcoal[J].Rsc Advances,2018,8(55):31414-31426.
• [38]AMBADE R B,AMBADE S B,Salunkhe R R,et al.Flexible-wire shaped all-solid-state supercapacitors based on facile electropolymerization of polythiophene with ultra-high energy density[J].Journal of Materials Chemistry A,2016,4(19):7406-7415.
• [39]CHEN Q,WANG X Q,CHEN F,et al.Extremely strong and tough polythiophene composite for flexible electronics[J].Chemical Engineering Journal,2019,368:933-940.