高低黏PET并列复合纤维的制备与性能Preparation and Properties of High and Low Viscosity PET Side-by-Side Bicomponent Fiber
高庆文,邓倩倩,曹宇恒,吴灿清,张须臻,王秀华
GAO Qing-wen,DENG Qian-qian,CAO Yu-heng,WU Can-qing,ZHANG Xu-zhen,WANG Xiu-hua
摘要(Abstract):
以两种不同特性黏度的聚对苯二甲酸乙二醇酯(PET)为原料,利用复合纺丝技术,一步法制得并列复合全拉伸丝(FDY)。采用声速法、差式扫描量热法等测试手段,分析了纺丝、热定形工艺对并列复合FDY的声速取向因子和结晶度下降,断裂伸长率增大,断裂强度减小,纤维的卷曲性能变好;随着热定形温度的升高,纤维的声速取向因子和结晶度增大,断裂强度提高,纤维的断裂伸长率和卷曲性能下降。
Based on two kinds of polyethylene terephthalate(PET) with different viscosity, PET side-by-side bicomponent fiber was obtained by melt spinning with twin screw extruder. Sound velocity method and different scanning calorimeter test were used to discuss the influence of different drawing process of PET fully drawn yarn(FDY) on its structure and properties. The results show that with the increase of spinning speed, the degree of crystallization and orientation of PET composite fiber decrease, the elongation at breaking and crimp properties of the PET composite fiber obviously increase, breaking strength decreases.However, with the increase of heat setting temperature of PET composite fiber, the degree of crystallization and orientation of fiber increase gradually, the breaking strength is improved. Nevertheless elongation and crimp properties decrease.
关键词(KeyWords):
聚酯并列复合纤维;FDY;纺丝速度;热定形温度
PET side-by-side bicomponent fiber;FDY;spinning speed;heat setting temperature
基金项目(Foundation): 中国纺织工业联合会科技指导性项目(计划编号2017002)
作者(Author):
高庆文,邓倩倩,曹宇恒,吴灿清,张须臻,王秀华
GAO Qing-wen,DENG Qian-qian,CAO Yu-heng,WU Can-qing,ZHANG Xu-zhen,WANG Xiu-hua
DOI: 10.16090/j.cnki.hcxw.20181214.002
参考文献(References):
- [1]王显楼,于国信,朱宝梅.三维卷曲纤维制取的技术[J].合成纤维,1995, 24(1):22-26.
- [2]张明成,孔维嘉.双PET并列复合弹性纤维生产技术[J].聚酯工业, 2017, 30(5):16-19.
- [3]李夏.并列复合聚酯弹性纤维的制备及结构性能研究[D].上海:东华大学, 2014.
- [4]吴宏仁,谭武红,陈时达,等.拉伸工艺对FDY结构、性能的影响[J].合成纤维工业, 1989, 12(6):10-14.
- [5]王秀华,沈金科,沈国光,等.一步法PET/CDP混纤牵伸丝的制备与性能[J].纺织学报, 2013, 34(5):30-34.
- [6]董纪震.合成纤维生产工艺学[M].北京:纺织工业出版社, 1984.
- [7]梁冬.拉伸工艺对涤纶FDY结构性能的影响[J].化纤与纺织技术,2006(4):23-25.
- [8] HWAN Oh Tae. Melt spinning and drawing process of PET side-byside bicomponent fibers[J]. Journal of Applied Polymer Science, 2006,101(3):1362-1367.
- [9]冯永生,蔡涛,欧阳文咸.纺丝工艺对PET/PTT复合纤维性能的影响[J].合成纤维工业, 2016, 39(6):65-67.
- [10]杨超,周永凯,张华,等.拉伸倍数和热定型温度对高强聚酰胺纤维染色性能的影响[J].北京服装学院学报(自然科学版), 2014, 34(1):1-8.
- [11]张良.热定形对聚酯纤维微结构和碱减量整理的影响[J].印染,1988(2):75-81.