直接缩聚法合成聚乳酸的研究STUDY ON THE DIRECT POLYCONDENSATION OF POLYLACTIC ACID
赵耀明,张军,麦杭珍
ZhaoYaoming Zhang Jun Mai Hangzhen (Institute of Material of Sci & Eng SCUT 510640)
摘要(Abstract):
研究了以乳酸为单体,用直接缩聚法合成聚乳酸的反应过程。利用联苯醚作为溶剂,与体系的水分进行共沸回流,达到充分脱水的目的。探讨了反应历程中包括温度、反应时间、溶剂用量、催化剂用量等参数对聚合产物的分子量的影响。
Polylactic acid is produced directly from lactic acid. Diphenyl ether is used as solvent and azeotropied with water.The affecting factors in the progress on molecular weight,such as temperature,time,amount of solvent and catalyst,etc.are studied.
关键词(KeyWords):
聚乳酸;可生物降解;直接缩聚
基金项目(Foundation): 广东省自然科学基金项目;;国家教育部高校博士点专项科研基金资助项目
作者(Author):
赵耀明,张军,麦杭珍
ZhaoYaoming Zhang Jun Mai Hangzhen (Institute of Material of Sci & Eng SCUT 510640)
DOI: 10.16090/j.cnki.hcxw.2001.03.001
参考文献(References):
- [1]Anthony L.Andrady Macromol Chem Phys.1994,C34(l):25 ~76
- [2]Ch Schugens,V Maguet ,et al Polymer.1996, (37):1027 ~1038
- [3]李洪权.全大萍等.化工新型材料.1999,(8):3~6
- [4]Tetsuju Ymaoka,Yoshitake takahashi,et al . Mournal of Polymer
- Science.1999. (37):l513~1521
- [5]Zhang Z Hou and K E Gonsalves.Journal of Polymer Science:Part
- A:Polymer Chemistry.1996, (34): 2737~2742
- [6]严冰,赵耀明,合成纤维、2000,(3):16~19
- [7] 王身国.化学通报.1997(2):45~48
- [8]David R Witzke,et al.Macromolecules.1997, (30):7075~ 7085
- [9]Masanobu Ajioka ,et al .Bull Chem Soc Jpn.1995.(68):2125
- [10]Centre de Recherche sur les Biopolymeres Artificesls.URA CNRS,
- Faulte de Pharmacie.Macromolecules.1996,(29):3535
- [11]Hans R Kricheldorf ,et al.Macromolecules.1996,(29):1375
- [12]苏涛,唐艳霞,刘晓静.化工时刊.1998,(5):18-21