杨晗,张蕊萍,牛梅,盛向前
YANG Han,ZHANG Rui-ping,NIU Mei,SHENG Xiang-qian(College of Textile Engineering and Arts

• 1:太原理工大学轻纺工程与美术学院

摘要(Abstract)：

利用双螺杆挤出机制备了聚苯硫醚(PPS)/多壁碳纳米管(MWCNTs)复合材料,然后通过差示扫描量热法(DSC)研究了纯PPS以及PPS/MWCNTs复合材料的等温结晶过程,并运用Avrami模型对纯PPS以及PPS/MWCNTs复合材料的等温结晶动力学进行分析。研究结果表明,MWCNTs的加入明显缩短了PPS的半结晶期,提高了结晶速率;Avrami模型能够较好地描述PPS及PPS/MWCNTs复合材料的等温结晶动力学。
The PPS/MWCNTs composite was prepared by twin-screw extruder.The isothermal crystallization progress of pure PPS and PPS/MWCNTs composite were characterized by differential scanning calorimeter(DSC),moreover,isothermal crystallization kinetics of composites were analyzed through the Avrami model.The experiment indicated that the half-crystallization time of PPS got obviously shorten and its crystallization rate raised with the addition of MWCNTs,Avrami model could well described isothermal crystallization kinetics of PPS/MWCNTs composite.

关键词(KeyWords)： 聚苯硫醚;多壁碳纳米管;纳米复合材料;等温结晶
PPS,MWCNTs,nanocomposite,isothermal crystallization

Abstract:

Keywords:

基金项目(Foundation): 山西省科技攻关项目(项目编号20080322026)

作者(Author): 杨晗,张蕊萍,牛梅,盛向前
YANG Han,ZHANG Rui-ping,NIU Mei,SHENG Xiang-qian(College of Textile Engineering and Arts

DOI: 10.16090/j.cnki.hcxw.2011.01.018

参考文献(References)：

• [1]邱桂花,夏和生,王琪等.聚合物/碳纳米管复合材料研究进展[J].高分子材料科学与工程,2002,18(6):20-23.
• [2]陈晓媛,芦艾,刘际伟等.玻纤增强聚苯硫醚复合材料制备工艺与性能的研究[J].塑料工业,2004,32(11):19-23.
• [3]Jang J,Lee N J.Characterization of functionally gradient epoxy/carbonfiber composite prepared under centrifugal force[J].Journal of MaterialsScience,1997,32(8):2 013-2 020.
• [4]闵敏等.聚苯硫醚/玻璃微珠复合材料体系的相容性及非等温结晶动力学研究[J].工程塑料应用,20103,8(1):59-64.
• [5]Yu Laigui,Yang Shengrong.Investigation of the transfer filmcharacteristic and tribochemical changes of Kevlar fiber reinforcedpolyphylene sulfide composites in sliding against a tool steel counterface[J].Thin Solid Film s,2002,413(1/2):98-103.
• [6]Auer C,Kalinka G,et al.Crystallization kinetics of pure and fiber-reinforced poly(phenylene sulfide)[J].Journal of Applied Polymer Science,1994,51(3):407-413.
• [7]Avrami M.Kinetics of phase change I[J].Journal of Chemical Physics,1939,(7):1 103-1 112.
• [8]何曼君,陈维孝,董西侠.高分子物理[M]上海:复旦大学出版社,1990:72.