张清华,金惠芬,黄素萍,耿延候,景遐斌
Zhang Qinghua, Jin Huifeng Huang Suping (College of Polymeric Materials, China Textile University) Geng Yanhou Jing Xiabin (Changchun Institute, of Applied chemistry, Academia Sinica)

• 1:中国纺织大学材料学院
• 2:中国纺织大学材料学院
• 3:中国纺织大学材料学院
• 4:中科院长春应化所

摘要(Abstract)：

本文用红外光谱分别测试聚苯胺的本征态结构和掺杂态结构,分析聚苯胺掺杂前后分子结构的不同与导电性的关系。本工作以樟脑磺酸作掺杂剂,用溶液法把几种不同的聚合物与掺杂态聚苯胺共混,测其阀值为2.3wt％,并用扫描电镜照片对结果给以解释。
JR spectroscopy is used to determine the characteristic and intercalated structures of polyaniline respectively for the relationship of molecular structure and conductive property, before and after intercalation. In this work, camphor sulfonic acid is used as intercalating agent . Several different polymers are blended with intercalated polyaniline by solution method . The determined threshold value is 2. 3 wt%. Results are explained with SEM photographs.

关键词(KeyWords)：

Abstract:

Keywords:

基金项目(Foundation): 国家自然科学基金会资助项目

作者(Author): 张清华,金惠芬,黄素萍,耿延候,景遐斌
Zhang Qinghua, Jin Huifeng Huang Suping (College of Polymeric Materials, China Textile University) Geng Yanhou Jing Xiabin (Changchun Institute, of Applied chemistry, Academia Sinica)

DOI: 10.16090/j.cnki.hcxw.1997.01.004

参考文献(References)：

• [1] 王佛松等.高分子学报.5(1987) 384
• [2] 王佛松等.武汉大学学报(自然科学版).6(1993) 62
• [3] J. Epstein. et al. USP 5135695