杨学萍
YANG Xue-ping

• 1:中国石油化工股份有限公司上海石油化工研究院

摘要(Abstract)：

详细介绍了连续碳纤维增强聚醚醚酮(CCF/PEEK)复合材料主要制备技术的研究进展,包括CCF/PEEK预浸料制备、纤维表面处理以及CCF/PEEK成型技术,明确各工艺的技术研发重点;并介绍了CCF/PEEK复合材料在航空航天、医疗器械以及能源、汽车等工业领域的应用研究进展。最后展望了CCF/PEEK复合材料的未来研究方向及发展趋势。
The research progress of main preparation technologies of continuous carbon fiber reinforced polyetheretherketone(CCF/PEEK) composites was introduced in detail, including the preparation of CCF/PEEK prepreg, fiber surface treatment and CCF/PEEK molding technology, and the technical research and development focus of each process were clarified. The application research progress of CCF/PEEK composites in aerospace, medical devices, energy, automobile and other industries was also introduced. Finally, the future research direction and development trend of CCF/PEEK composites were prospected.

关键词(KeyWords)： 连续碳纤维;聚醚醚酮;复合材料;制备;应用
continuous carbon fiber;polyetheretherketone composite;preparation;application

Abstract:

Keywords:

基金项目(Foundation):

作者(Author): 杨学萍
YANG Xue-ping

DOI: 10.16090/j.cnki.hcxw.2021.05.011

参考文献(References)：

• [1] YAO S S, JIN F L, KYONG Y R, et al. Recent advances in carbon-fiber-reinforced thermoplastic composites:A review[J]. Composites Part B,2018(142):241-250.
• [2] DAI T, KOHARA M, NODA K, et al. Evaluation of detailed transverse crack propagation toward thickness direction for CF/PEEK quasi-isotropic laminates under fatigue loading:Solid mechanics and materials engineering[J]. Mechanical Engineering Journal, 2020, 7(5):20-00128.
• [3]肇研,王凯,陈俊林,等.一种超薄连续纤维增强热塑性树脂预浸料及其制备方法:105904611B[P]. 2019-05-24.
• [4]李学宽,肇研,王凯,等.热熔法制备连续纤维增强热塑性预浸料的浸渍模型和研究进展[J].航空制造技术, 2018, 61(14):74-78.
• [5]一种制备连续碳纤维增强PEEK热塑性预浸带的设备及方法：109849219A[P]. 2019-06-07.
• [6] TRAN M Q, HO K K C, KALINKA G, et al. Carbon fibre reinforced poly(vinylidene fluoride):Impact of matrix modification on fibre/polymer adhesion[J]. Composites Science and Technology, 2008, 68(7):1766-1776.
• [7]周华民,蒋维,黄志高,等.一种连续碳纤维增强聚醚醚酮复合材料的制备方法及产品:108047470A[P]. 2018-05-18.
• [8] ZHANG Y, TAO W, ZHANG Y, et al. Continuous carbon fiber/crosslinkable poly(ether ether ketone)laminated composites with outstanding mechanical properties, robust solvent resistance and excellent thermal stability[J]. Composites Science and Technology, 2018, 165:148-153.
• [9]张云鹤,姜振华,陶巍,等.含有苯乙炔侧基的聚醚醚酮聚合物碳纤维复合材料及其制备方法:104277414A[P]. 2015-05-04.
• [10]陈浩然,李勇,还大军,等. T700/PEEK热塑性自动铺放预浸纱制备质量控制及性能研究[J].航空学报, 2018, 39(6):228-237.
• [11]王彪,胡郁霏,诸金,等.一种连续功能化碳纤维增强热塑性树脂基预浸带的制备工艺:103978696A[P]. 2014-08-13.
• [12]陈书华,韩建平,王喜占,等.连续碳纤维增强聚醚醚酮预浸带成型工艺及性能[J].宇航材料工艺, 2016, 46(4):48-51.
• [13]李欣.碳纤维/聚醚醚酮编织复合材料的制备及性能研究[D].哈尔滨:哈尔滨工业大学, 2017.6
• [14] LUO H L, XIONG G Y, REN K Y, et al. Air DBD plasma treatment on three-dimensional braided carbon fiber-reinforced PEEK composites for enhancement of in vitro bioactivity[J]. Surface&Coatings Technology,2014, 242:1-7.
• [15]李嘉禄,魏丽梅,杨红娜,等.碳纤维三维编织复合材料的结构对拉伸和弯曲性能的影响[J].材料工程, 2004(12):3-7.
• [16] UMUT Y, LEI P, FEI X, et al. Effect of functional groups on interfacial adhesion properties of PEEK/carbon fiber composites[J]. Applied Mechanics and Materials, 2014, 3342:66-72.
• [17] FU H J, MA C Q, KUANG N H, et al. Interfacial properties modification of carbon fiber/polyarylacetylene composites[J]. Chinese Journal of Aeronautics. 2007, 20(2):124-128.
• [18] FUKUNAGA A, UEDA S, NAGUMO M. Anodic surface oxidation mechanisms of PAN-based and pitch-based carbon fibres[J]. Journal of Materials Science, 1999, 34(12):2851-2854.
• [19] LEI PAN, UMUT YAPICI. A comparative study on mechanical properties of carbon fiber/PEEK composites[J]. Advanced Composite Materials, 2016, 25(4):359-374.
• [20]张晓玲,焦莎,王川,等.一种连续碳纤维表面改性的方法:1040183408A[P]. 2014-09-03.
• [21]姜再兴,苑雪玉.一种碳纤维增强热塑性复合材料的制备方法:110423367A[P]. 2019-11-08.
• [22]张照,曹硕,朱姝,等.纺织结构碳纤维增强聚醚醚酮基复合材料的制备及界面改性[J].高分子材料科学与工程, 2017, 33(10):141-148.
• [23] LI J. Interfacial studies on the ozone and air-oxidation-modified carbon fiber reinforced PEEK composites[J]. Surface and Interface Analysis,2009, 41:310-315.
• [24] JYONGSIK J, HYUNCHEOL K. Improvement of carbon fiber/PEEK hybrid fabric composites using plasma treatment[J]. Polymer Composites,1997, 18(1):125-132.
• [25] SUDHIR T, MOHIT S, STEPHANE P, et al. Influence of cold remote nitrogen oxygen plasma treatment on carbon fabric and its composites with specialty polymers[J]. Journal of Materials Science, 2011, 46(4):964-974.
• [26]鲁佳腾,颜春,徐海兵,等.热塑性碳纤维上浆剂的研究进展[J].玻璃钢/复合材料, 2017(6):94-99.
• [27] HASSAN E A M, ELAGIB T H H, MEMON H, et al. Surface modification of carbon fibers by grafting PEEK-NH2for improving interfacial adhesion with polyetheretherketone[J]. Materials, 2019, 12(5):778.
• [28] HASSAN E A M, GEA D T, YANG L L, et al. Highly boosting the interlaminar shear strength of CF/PEEK composites via introduction of PEKK onto activated CF[J]. Composites Part A:Applied Science and Manufacturing, 2018, 112:155-160.
• [29] GIRAUD I, FRANCESCHI-MESSANT S, PEREZ E. Preparation of aqueous dispersion of thermoplastic sizing agent for carbon fiber by emulsion/solvent evaporation[J]. Applied Surface Science, 2013, 266:94-99.
• [30]岳喜贵,李梦竹,徐攀,等.连续纤维增强聚芳醚酮单向预浸带及其制备方法:109280188A[P]. 2019-01-29.
• [31] WANG X K, HUANG Z G, LAI M L, et al. Highly enhancing the interfacial strength of CF/PEEK composites by introducing PAIK onto diazonium functionalized carbon fibers[J]. Applied Surface Science, 2020, 510:145400.
• [32] LIU H S, ZHAO Y, LI N, et al. Enhanced interfacial strength of carbon fiber/PEEK composites using a facile approach via PEI&ZIF-67 synergistic modification[J]. Journal of Materials Research and Technology,2019,8(6):6289-6300.
• [33] LUO H L, XIONG, YANG G Z, et al. Preparation of three-dimensional braided carbon fiber-reinforced PEEK composites for potential loadbearing bone fixations. Part I. Mechanical properties and cytocompatibility[J]. Journal of the Mechanical Behavior of Biomedical Materials, 2014, 29:103-113.
• [34]史如静,吴举,周剑锋,等.模压成型工艺参数对CF/PEEK复合材料I型层间断裂韧性的影响[J].高科技纤维与应用, 2020, 45(1):26-32.
• [35] DAI G M, ZHAN L H, GUAN C L, et al. The effect of moulding process parameters on interlaminar properties of CF/PEEK composite laminates[J]. High Performance Polymers, 2020, 32(7):835-841.
• [36]郑利杭,刘洋,谭洪生,等.连续碳纤维增强聚醚醚酮板材的研究[J].塑料工业，2020, 48(7):153-157,163.
• [37] YASSIN K, HOJJATI M. Processing of thermoplastic matrix composites through automated fiber placement and tape laying methods:A review[J]. Journal of Thermoplastic Composite Materials, 2018, 31(12):1676-1725.
• [38]单毫,陈宇,李俊杰,等.红外加热缠绕成型工艺参数对CF/PEEK复合材料层间剪切性能的影响[J].复合材料科学与工程，2020(1):39-46.
• [39]成烨,还大军,李勇,等. AS4D/PEEK热塑性复合材料激光固结缠绕工艺参数优化[J].材料导报, 2020, 34(22):22190-22194.
• [40] SCHAKEL M, HOSSEINI S M A, JANSSEN H, et al. Temperature analysis for the laser-assisted tape winding process of multilayered composite pipes[J]. Procedia CIRP, 2019, 85:171-176
• [41] ALMAJID A, FRIEDRICH K, FLOECK J, et al. Surface damage characteristics and specific wear rates of a new continuous carbon fiber(CF)/polyetheretherketone(PEEK)composite under sliding and rolling contact conditions[J]. Applied Composite Materials, 2011, 18(3):211-230.
• [42]孙九霄,陆野,刘刚.碳纤维分段缠绕复合材料厚壁圆筒:108081700BA[P]. 2020.11.17
• [43]宋清华,肖军.文立伟,等.热塑性复合材料自动纤维铺放装备技术[J].复合材料学报, 2016, 33(6):1214-1222.
• [44]高士杰. PEEK热塑性复合材料纤维铺放工艺研究[D].哈尔滨:哈尔滨工业大学, 2018.
• [45] STOKES-GRIFFIN M C, COMPSTON P. The effect of processing temperature and placement rate on the short beam strength of carbon fibre-PEEK manufactured using a laser tape placement process[J]. Composites Part A, 2015, 78:274-283
• [46]包艳玲,阮英波,张承双,等.激光原位铺放CF增强PEEK基复合材料工艺研究[J].合成材料老化与应用, 2020, 49(1):1-3, 21.
• [47] STEPASHKIN AA, CHUKOV D I, SENATOV F S, et al. 3D-printed PEEK-carbon fiber(CF)composites:structure and thermal properties[J],Composites Science and Technology, 2018,164:319-326.
• [48]罗盟,田小永,尚俊凡,等.高性能纤维增强聚醚醚酮复合材料挤出成型增材制造现状与挑战[J].航空制造技术, 2020, 63(15):39-47.
• [49] NEKODAVAN D W, PRATIK K, JAFAR G, et al. Investigating the hot isostatic pressing of an additively manufactured continuous carbon fiber reinforced PEEK composite[J]. Additive Manufacturing, 2021, 37:101634.
• [50] CHANG B M, LI X M, PARANDOUSH P, et al. Additive manufacturing of continuous carbon fiber reinforced poly-ether-ether-ketone with ultrahigh mechanical properties[J]. Polymer Testing, 2020, 88(106563):1-5.
• [51]吴琨.热塑性树脂基复合材料在航空领域的研究进展[J].价值工程, 2020, 39(9):210-211.
• [52]胡记强,王兵,张涵其,等.热塑性复合材料构件的制备及其在航空航天领域的应用[J].宇航总体技术, 2020, 4(4):61-70.
• [53]李三平,杨正.连续碳纤维增强热塑性复合材料的性能优势及应用举例[J].中国新技术新产品, 2019(20):64-65.
• [54]索尔维碳纤维增强聚醚醚酮产品强化植入机械[J].橡塑技术与装备, 2018, 44(2):60-61.
• [55] BROCKETT C L, JOHN G, WILLIAMS S, et al. Wear of ceramic-oncarbon fiber-reinforced poly-ether ether ketone hip replacements[J].Journal of Biomedical Materials Research Part B:Applied and Biomaterials, 2012, 100B(6):1459-1465
• [56] KOH Y G, PARK K M, LEEB J A, et al. Total knee arthroplasty application of polyetheretherketone and carbonfiber-reinforced polyetheretherketone:A review[J]. Materials Science&Engineering C, 2019,100:70-81.
• [57]谭洪生,宋鹏飞,于婷婷. 2018法国JEC国际复材展热塑性预浸料及构件观感[J].工程塑料应用, 2018, 46(10):141-146.
• [58]倪志春.国内外聚醚醚酮开发应用进展[J].国外塑料, 2013, 31(10):32-36.