静电纺制备超疏水表面纤维膜的研究进展Research Progress of Super-hydrophobic Surfaces via Electrospinning
李小红,丁彬,俞建勇
LI Xiao-hong1,2, DING Bin1
摘要(Abstract):
简介经典的固体表面润湿性理论,阐明了实现超疏水性的两个必要条件:低表面能表面和微-纳米复合结构。综述了当前国内外静电纺丝制备超疏水纤维膜的最新研究进展及其应用前景。
The two necessary conditions of the preparation of super-hydrophobic solid surface including low energy surface and special micro surface roughness were elucidated from the wetting theory of solid surface. The recent progress of fabrication of super-hydrophobic surfaces by electrospinning in different countries was reviewed, and application of super-hydrophobic surfaces was proposed.
关键词(KeyWords):
超疏水;接触角;静电纺丝;微纳米结构
super-hydrophobic, contact angle, electrospinning, micro-and nano-structure
基金项目(Foundation):
作者(Author):
李小红,丁彬,俞建勇
LI Xiao-hong1,2, DING Bin1
参考文献(References):
- [1]Li X M,Reinhoudt D,Crego-Calama M.What do we need for a su-perhydrophobic surface?A review on the recent progress in the prepara-tion of superhydrophobic surfaces[J].Chemical Society Reviews,2007,36(8):1350-1368.
- [2]Ma M,Hill R M.Superhydrophobic surfaces[J].Current Opinion in Colloid&Interface Science,2006,11(4):193-202.
- [3]Barthlott W,Neinhuis C.Purity of the sacred lotus,or escape from contamination in biological surfaces[J].Planta,1997,202(1):1-8.
- [4]Feng L,Li S H,Li Y S,et al.Super-hydrophobic surfaces:From natu-ral to artificial[J].Advanced Materials,2002,14(24):1857-1860.
- [5]江雷.从自然到仿生的超疏水纳米界面材料[J].科技导报,2005,23(2):4-7.
- [6]Ping Lu,Bin Ding.Applications of electrospun fibers[J].Recent Pat Nanotechnol,2008,2(3):169-182.
- [7]常敏,李从举.静电纺纳米纤维的应用[J].合成纤维工业,2007,04(30):50-52.
- [8]Shang H M,Wang Y,et al.Nanostructured superhydrophobic surfaces[J].Journal of Materials Science,2005,40(13):3587-3591.
- [9]Lim J M,Yi G R,Moon J H,et al.Superhydrophobic films of electro-spun fibers with multiple-scale surface morphology[J].Langmuir,2007,23(15):7981-7989.
- [10]Jiang L,Zhao Y,Zhai J.A lotus-leaf-like superhydrophobic surface:A porous microsphere/nanofiber composite film prepared by electrohydro-dynamics[J].Angewandte Chemie-International Edition,2004,43(33):4338-4341.
- [11]Acatay K,Simsek E,et al.Tunable,superhydrophobically stable polymeric surfaces by electrospinning[J].Angewandte Chemie-Interna-tional Edition,2004,43(39):5210-5213.
- [12]Ma M L,Hill R M,et al.Electrospun poly(styrene-block-dimethyl-siloxane)block copolymer fibers exhibiting superhydrophobicity[J].Lang-muir,2005,21(12):5549-5554.
- [13]Gu Z Z,Wei H M,et al.Artificial silver ragwort surface[J].Applied Phyxics Letters,2005,86:1-3.
- [14]Singh A,Steely L,Allcock H R.Poly[bis(2,2,2-trifluoroethoxy)phos-phazene]superhydrophobic nanofibers[J].Langmuir,2005,21(25):11604-11607.
- [15]Miyauchi Y,Ding B,Shiratori S.Fabrication of a silver-ragwort-leaf-like super-hydrophobic micro/nanoporous fibrous mat surface by electrospinning[J].Nanotechnology,2006,17(20):5151-5156.
- [16]Kang M,Jung R,et al.Preparation of superhydrophobic polystyrene membranes by electrospinning[J].Colloids and Surfaces A:Physicochem-ical and Engineering Aspects,2008,(313-314):411-414.
- [17]Han D,Steckl A J.Superhydrophobic and oleophobic fibers by coax-ial electrospinning[J].Langmuir,2009,Article ASAP.
- [18]Ding B,Li C R,et al.Conversion of an electrospun nanofibrous cel-lulose acetate mat from a super-hydrophilic to super-hydrophobic surface[J].Nanotechnology,2006,17(17):4332-4339.
- [19]Ogawa T,Ding B,et al.Super-hydrophobic surfaces of layer-by-layer structured film-coated electrospun nanofibrous membranes[J].Nan-otechnology,2007,18(16):165607-165614.
- [20]Jong-Min L,Gi-Ra Y,et al.Superhydrophobic films of electrospun fibers with multi-scale surface morphology[J].Langmuir2007,23(15):7981-7989.
- [21]Ding B,Ogawa T,et al.Fabrication of a super-hydrophobic nanofi-brous zinc oxide film surface by electrospinning[J].Thin Solid Films,2008,516(9):2495-2501.