高分子基相变储能材料的研究进展Research of Polymer-Based Phase Transition Materials for Thermal Energy Storage
郭静,李楠
GUO Jing, LI Nan (Dalian Polytechnic University
摘要(Abstract):
根据相变介质与基体的结合方式,将高分子基相变材料分为3大类:即以高聚物为基体的复合相变材料、交联型结晶高聚物相变材料和接枝型结晶高聚物相变材料。详细介绍了各种相变材料的相变机理和研究成果,对高分子基相变储能材料的应用和未来研究方向做了评述。
Based on the combined-manner between phase transition medium and matrix, polymer-based phase change materials (PCMs) had been classified into three categories: the composites with polymers as the matrices, the crystalline polymer with crosslinked structure and the crystalline polymers with grafting structures. The phase change mechanism and research achievements of polymer-based PCMs had been summarized in detail. The applications and research content of polymer-based PCMs in further had been reviewed.
关键词(KeyWords):
相变材料;高分子基;进展;综述
phase chang material, polymer-based, progress, review
基金项目(Foundation):
作者(Author):
郭静,李楠
GUO Jing, LI Nan (Dalian Polytechnic University
参考文献(References):
- [1]Younsook Shin,Dong-Il Yoo,Kyunghee Son.Development of thermoregulating textile materials with microencapsulated phase change materials(PCM).II.Preparation and application of PCM microcapsules[J].Journal of Applied Polymer Science,2005,96(6):2005-2010.
- [2]Younsook Shin,Dong-Il Yoo,Kyunghee Son.Development of thermoregulating textile materials with microencapsulated phase change materials(PCM).IV.Performance properties and hand of fabrics treated with PCM microcapsules[J].Journal of Applied Polymer Science,2005,97(3):910-915.
- [3]Y!zonur,M Mazman,et al.Microencapsulation of coco fatty acid mixture for thermal energy storage with phase change material[J].International Journal of Energy Research,2006,30(10):741-749.
- [4]Krzysztof Pielichowski,Kinga Flejtuch.Recent developments in polymeric phase change materials for energy storage:poly(ethylene oxide)/stearic acid blends[J].Polymers for Advanced Technologies,2005,16(2-3):127-132.
- [5]陈立新,焦剑,蓝立文.功能塑料[M].北京:化学工业出版社,2004:361-362.
- [6]Uwe Beginn.Applicability of frozen gels from ultra high molecular weight polyethylene and paraffin waxes as shape persistent solid/liquid phase change materials[J].Macromolecular Materials and Engineering,2003,288(3):245-251.
- [7]Ye Hong,Ge Xueshi.Preparation of polyethylene-paraffin compound as a form-stable solid-liquid phase change material[J].Solar Energy Materials and Solar Cells,2000,64(1):37-44.
- [8]Ahmet Sari.Form-stable paraffin/high density polyethylene composites as solid-liquid phase change material for thermal energy storage:preparation and thermal properties[J].Energy Conversion and Management,2004,45:(13-14):2033-2042.
- [9]柳乐仙,洪成海,崔秀国等.不同分子量聚乙二醇的相变热性质研究[J].长春理工大学学报,2005,28(1):98-100.
- [10]Cemil Alkan,Ahmet Sari,Orhan Uzun.Poly(ethylene glycol)/acrylic polymer blends for latent heat thermal energy storage[J].American Institute of Chemical Engineers,2006,52(9):3310-3314.
- [11]王忠,陈立贵,付蕾等.共混法制备高分子固-固相变材料及其表征[J].材料导报,2007,21(3):276-278.
- [12]郭元强,童真,陈鸣才等.聚乙二醇/二醋酸纤维素共混物的相变行为[J].高分子材料科学与工程,2003,19(5):149-153.
- [13]Changzhong Chen,Linge Wang and Yong Huang.Electrospinning of thermo-regulating ultrafine fibers based on polyethylene glycol/cellulose acetate composite[J].Polymer,2007,48(18):5202-5207.
- [14]Yong Jiang,Enyong Ding and Guokang Li.Study on transition characteristics of PEG/CDA solid-solid phase change materials[J].Polymer,2002,43(1):117-122.
- [15]Wei-Dong Li,En-Yong Ding.Preparation and characterization of cross-linking PEG/MDI/PE copolymer as solid-solid phase change heat storage material[J].Solar Energy Materials and Solar Cells,2007,91(9):764-768.
- [16]侯敏,俞昊,成时亮,戴天贺等.聚乙二醇单甲醚/二醋酸纤维素相变纤维的制备及其热性能的研究[J].东华大学学报(自然科学版),2006,32(6):124-127.
- [17]张梅,那莹,姜振华.接枝共聚法制备聚乙二醇(PEG)/聚乙烯醇(PVA)高分子固-固相变材料性能研究[J].高等学校化学学报,2005,26(1):170-174.
- [18]张梅,李全明,邱发贵等.聚乙二醇(PEG)/聚乙烯醇(PVA)固-固相变材料受限非等温结晶动力学研究[J].功能材料,2007,38(10):1709-1712.
- [19]张莹莹,张公正,刘灿强等.聚乙二醇/聚丙烯酰胺相变材料的制备及性质研究,化工新型材料,2006,34:(1):45-47.
- [20]原小平,丁恩勇.纳米纤维素/聚乙二醇固-固相变材料的制备及其储能性能的研究[J].林产化学与工业,2007,27(2):67-69.
- [21]Jing-Cang Su,Peng-Sheng Liu.A novel solid-solid phase change heat storage material with polyurethane block copolymer structure[J].Energy Conversion and Management,2006,47(18-19):3185-3191.
- [22]粟劲苍,刘朋生.聚乙二醇型聚氨酯软硬段对其相变储热性能的影响[J].高分子学报,2007(2):97-102.
- [23]曹琪,刘朋生.交联型聚氨酯固-固相变材料的相变性能及形态[J].应用化学,2007,24,(6):652-655.