张素风,张美娟,张斌,刘叶,宋宝玉,吴养育
ZHANG Su-feng,ZHANG Mei-juan,ZHANG Bin,LIU Ye,SONG Bao-yu,WU Yang-yu

• 1:陕西科技大学轻工科学与工程学院陕西省造纸技术及特种纸品开发重点实验室

摘要(Abstract)：

通过纤维形态分析仪、扫描电镜、X射线衍射仪和热重分析仪对聚对苯二甲酸乙二醇酯(PET)沉析纤维的尺寸大小、表面形貌、结晶性能和热学特性四个方面进行检测分析。结果表明:PET沉析纤维相比市售PET浆粕纤维长度较短,细小纤维含量占70.4%;PET沉析纤维表面分丝帚化现象明显,其外形呈飘带状,形态柔顺,比表面积高达8.009 9 m~2/g;相比浆粕纤维,PET沉析纤维的结晶度和热稳定性相对较高,结晶度为37.88%,初始分解温度365℃,最大分解速率对应的温度为438℃,表明PET沉析纤维具有优异的热学特性,可广泛用于湿法成纸及复合材料增强等领域。
The size, surface morphology, degree of crystallinity and thermal properties of lab-made polyeth-ylene terephthalate(PET) fibrillated fibers were studied by using fiber quality analyzer, scanning elec-tron microscope, X-ray diffractometer and thermogravimetric analysis(TGA). Results indicated that thelength of PET fibrillated fibers was short compared to commercial PET pulp, the fines content accounted for70.4%. It had better fibrous fibrillating, ribbon-like in shape, supple shape and the specific surface area ofup to 8.009 9 m~2/g. PET fibrillated fibers had better thermal performance and crystallinity than that of thecommercial PET pulp, the crystallinity is 37.88 %. The initial decomposition temperature of fibrillated fi-bers was 365 ℃, the maximum rate of decomposition was at 438 ℃, thus demonstrated its excellent thermalproperties, it could be widely used in wet forming paper, composite materials and other fields.

关键词(KeyWords)： 聚对苯二甲酸乙二醇酯;沉析纤维;形貌;热性能
polyethylene terephthalate;fibrillated fiber;morphology;thermal performance

Abstract:

Keywords:

基金项目(Foundation): 陕西省2015科技统筹创新工程计划(2015KTCQ01-44)

作者(Author): 张素风,张美娟,张斌,刘叶,宋宝玉,吴养育
ZHANG Su-feng,ZHANG Mei-juan,ZHANG Bin,LIU Ye,SONG Bao-yu,WU Yang-yu

DOI: 10.16090/j.cnki.hcxw.2017.04.008

参考文献(References)：

• [1]郭倩倩,沈为,曹春祥.仿棉聚酯纤维针织物的起毛起球性能[J].东华大学学报自然科学版,2013,39(5):604-607.
• [2]武荣瑞.聚酯纤维技术发展及前景探讨[J].合成技术及应用,2004,19(3):1-4.
• [3]李青山,李悦,马志国,等.异形聚酯纤维的结构性能研究[J].合成纤维,2009,38(8):15-18.
• [4]代国亮,红,施楣梧.涤纶表面亲水改性研究进展及其发展方向[J].纺织学报,2015,36(8):156-164.
• [5]代国亮.聚酯纤维及织物的电子束辐照改性[D].上海:东华大学,2015.
• [6]马晓光,刘越,崔河,等.改性聚酯异形中空微孔纤维性能研究[J].高分子学报,2005,1(3):442-447.
• [7]徐晓辰.吸湿排汗聚酯纤维的开发及应用[J].合成纤维,2002,31(6):9-12.
• [8]ESPERANZA P,RICHARD M J,WINTHROP M P.Process for producing fibrids by precipitation and violent agitation:US,2988782 A[P].1961.
• [9]WATERS P F,MURARO L J.Process for producing fibrids by violent agitation:US,3431242[P].1969.
• [10]江明,张美云,陆赵情,等.对位芳纶沉析纤维性能研究[J].功能材料,2014(8):8075-8078.
• [11]YAO L,KIM K,KIM J.Fabrication of meta-aramid fibrid by precipitation[J].Fibers&Polymers,2012,13(3):277-281.
• [12]ZHANG S,ZHANG M,LI K.Adhesion force between aramid fibre and aramid fibrid by AFM[J].Polymer Bulletin,2011,66(3):351-362.
• [13]刘永乐.沉析法制备腈纶浆粕的研究[D].上海:东华大学,2005.
• [14]韩曙鹏,徐樑华,曹维宇,等.成纤过程中PAN纤维聚集态结构的形成[J].新型炭材料,2006,21(1):54-58.
• [15]WANG J,CHEN P,LI H,et al.Surface characteristic of poly(p-phenylene terephthalamide)fibers with oxygen plasma treatment[J].Surface&Interface Analysis,2008,40(9):1299-1303.
• [16]王曙中.芳纶浆粕和芳纶纸的发展概况[J].高科技纤维与应用,2009,34(4):15.
• [17]孙智华,唐爱民.对位芳纶浆粕结构及性能的表征[J].中国造纸,2008,27(10):22.
• [18]GYEONG-Yun Kim,MARTIN A.Hubbe engineering of a wet-end additives program relative to process parameters and to the physical and optical properties of filled paper[J].Industrial&Engineering Chemistry Research,2010,49(12):5644.
• [19]江明,张美云,陆赵情,等.对位芳纶沉析纤维及其纸基材料性能的研究[J].中国造纸,2014,33(03):22-26.
• [20]WANG Qifen,WANG Chengguo,WANG Yanxiang,et al.Effect of structure on tensile strength of PAN fiber[J].Journal of Functional Materials,2006,37(11):1787-1789.
• [21]冯凯.PET结晶及其增强复合材料的研究[D].武汉:湖北工业大学,2011.