国内聚酯多元醇研究进展The Research Progress on Domestic Polyester Polyols
任倩茹,徐垚英,周祥光
REN Qian-ru,XU Yao-ying,ZHOU Xiang-guang
摘要(Abstract):
聚酯多元醇作为合成聚氨酯的重要中间体,由多元酸与多元醇经酯化、脱水、聚合反应而成。简述了聚酯多元醇的分类及生产工艺,综述了其合成过程中的主要影响因素,并详细介绍了国内聚酯多元醇的研究进展,最后指出了未来聚酯多元醇的发展方向。
As an important intermediate of polyurethane, the synthesis process of polyester polyol consists of esterification, dehydration and polymerization. The classification and production process of polyester polyols were briefly described. The main influencing factors in the synthesis of polyester polyols were reviewed and research progress in domestic polyester polyols was also researched in detail. In the end, the future research directions of polyether polyols were also pointed out.
关键词(KeyWords):
聚氨酯;酯化;多元酸;多元醇
polyurethane;esterification;polyacid;polyol
基金项目(Foundation):
作者(Author):
任倩茹,徐垚英,周祥光
REN Qian-ru,XU Yao-ying,ZHOU Xiang-guang
DOI: 10.16090/j.cnki.hcxw.2019.12.001
参考文献(References):
- [1]任智鑫,陶绪泉,董晨洁,等.聚酯多元醇研究进展[J].化学推进剂与高分子材料, 2018, 16(4):51-54.
- [2]陈铃,刘亚辉,周志伟,等.聚氨酯用阻燃聚醚多元醇的研究进展[J].合成纤维, 2019, 48(4):17-20.
- [3] LEE J S, SHIN J H, KIM B K, et al. Modification of aqueous polyurethanes by forming latex interpenetrating polymer networks with polystyrene[J]. Colloid&Polymer Science, 2001, 279(10):959-965.
- [4] ZHOU X, TU Weiping, HU Jianqing. Preparation and characterization of two-component waterborne polyurethane comprised of water-soluble acrylic resin and HDI biuret[J]. Chinese Journal of Chemical Engineering, 2006, 14(1):99-104.
- [5]赵海鹏,张烨.聚酯多元醇的分类及研究进展[J].上海塑料, 2017,24(4):15-21.
- [6]晁国库,郭武学,赵亚娟,等.聚酯多元醇的合成方法研究[J].长春工业大学学报:自然科学版, 2007, 28(1):17-21.
- [7] MüLLER Rolf-Joachim, KLEEBERG I, DECKWER W D. Biodegradation of polyesters containing aromatic constituents[J]. Journal of Biotechnology, 2001, 86(2):87-95.
- [8]李绍雄,刘益军.聚氨酯树脂及其应用[M].化学工业出版社,北京, 2002:75-76.
- [9]曹祺风,朱长春,宋文生,等.聚酯多元醇合成中催化剂的应用研究[J].中国胶粘剂, 2008, 17(5):9-14.
- [10]关雎,关燕琼,彭进平,等.合成聚酯多元醇中催化剂性能的比较研究[J].广州化工, 2008, 36(3):36-38.
- [11]戴永祥,张彪.抗氧剂对聚酯多元醇合成的影响[J].安徽化工,2017,43(6):75-77.
- [12]邓亚丽,张华.己二酸产品杂质对聚酯多元醇质量影响分析[J].辽宁化工, 2018, 47(4):277-279.
- [13]石晓.阻燃聚酯多元醇的合成及应用[J].聚氨酯工业, 2006, 21(1):31-33.
- [14]孔宪志,赫羴姗,刘彤,等.木质素基聚酯多元醇的合成与表征[J].化学与黏合, 2015, 37(3):171-174.
- [15]来雅赟,邸明伟,孔宪志.二元醇对合成木质素基聚酯多元醇性能的影响[J].化学与黏合, 2018, 40(3):149-152.
- [16]蒋洪权,宋湛谦,商士斌,等.蓖麻油酸基聚酯多元醇的合成研究[J].聚氨酯工业, 2010, 25(2):25-28.
- [17]王亚群,王贵友,胡春圃.可再生聚酯多元醇的合成及其在聚氨酯材料中的应用[J].聚氨酯工业, 2013, 28(6):30-33.
- [18]王宏晓,商士斌,宋湛谦,等.松香基多元醇的合成及其应用[J].生物质化学工程, 2007, 41(6):32-36.
- [19]刘鹤,徐徐,高宏,等.马来海松酸聚酯多元醇的制备及性能研究[J].涂料工业, 2013, 43(1):53-55.
- [20]司红燕,商士斌,廖圣良,等.水可分散型松香基聚酯多元醇的制备及耐热性研究[J].林产化学与工业, 2016, 36(1):42-48.