聚丙烯腈碳纤维原丝聚合及凝固成形的研究进展Research Progress of PAN Precursor Polymerization and Wet-spinning Coagulation
彭公秋,杨永岗,温月芳,刘朗
PENG Gong-qiu1,2, YANG Yong-gang1, WEN Yue-fang1
摘要(Abstract):
综述了聚丙烯腈原丝聚合和湿法纺丝时凝固成形的国内外研究进展,简要介绍了聚合的方式、共聚和共混改性的研究进展,介绍了凝固成形中双扩散理论模型的建立与发展,重点讨论了凝固浴的组成及浓度、温度、拉伸比等因素对扩散及初生纤维结构与性能的影响。
The research progress of PAN precursor fiber in wet-spinning was reviewed from two aspects-polymerization and coagulation. The polymerization method, co-polymerization, polymer blends and modification were introduced briefly. The foundation and development of double-diffusion model in coagulation were presented. The effects of coagulation conditions such as coagulation bath composition, bath temperature and stretch radio on structure and properties of nascent fiber were discussed in detail.
关键词(KeyWords):
聚合;凝固成形;双扩散理论模型;初生纤维
polymerization, coagulation progress, double-diffusion theory model, nascent fiber
基金项目(Foundation):
作者(Author):
彭公秋,杨永岗,温月芳,刘朗
PENG Gong-qiu1,2, YANG Yong-gang1, WEN Yue-fang1
参考文献(References):
- [1]贺福,赵建国,王润娥等.碳纤维开发与碳纤维原丝质量[J].新型炭材料,1998,13(1):64-74.
- [2]王成国,朱波,蔡华苏.制约我国碳纤维工业发展的原因分析[J].化工技术经济,2005,23(4):12-15.
- [3]Gries T,Rixe C,et al.Polyacrylic fibers[J].Chem Fibers Int,2002,52(4):232.
- [4]贺福.碳纤维及其应用技术[M].北京:化学工业出版社,2004:4.
- [5]王延相,王成国,朱波等.聚丙烯腈基纤维的结构设计及其演变性研究[J].高科技纤维与应用,2005,30(1):10-15.
- [6]古谷禧典.丙烯腈系纤维的制法:日本,JP87-265810[P].1987.
- [7]古谷禧典.丙烯腈共聚物熔融纺丝法:日本,JP87-268812[P].1987.
- [8]水口丰和.丙烯腈系聚合物的熔融纺丝方法:日本,JP89-266213[P].1989.
- [9]张寿春.碳纤维用丙烯腈-衣康酸铵共聚树脂的制备及其性能研究[D].中国科学院研究生院博士论文,2004:14.
- [10]Jin-Shy Tsai,et al.The effect of the side chain of acrylate comonomers on the orientation,pore-size distribution,and properties of polyacrylonitrile precursor and resulting carbon fiber[J].J Appl Polym Sci,1991,42:3039-3044.
- [11]Jin-Shy Tsai,Chung-Hua Lin.The effect of molecular weight on the cross section and properties of polyacrylonitrile precursor and resulting carbon fiber[J].J Appl Polym Sci,1991,42:3045-3050.
- [12]P Bajaj,et al.Solution polymerization of acrylonitrile with vinyl acids in dimethyformamide[J].J Appl Polym Sci,1996,59:1539-1550.
- [13]A K Gupta,et al.Effect of the nature and mole fraction of acidic comonomer on the stabilization of polyacrylinitrile[J].J Appl Polym Sci,1996,59:1819-1826.
- [14]A I Stoyanov.Influence of the content of polymer with different molecular weights in spinning solutions on properties of acrylic fibers[J].J Appl Polym Sci,1982,27:235-238.
- [15]王延相,王成国等.聚丙烯腈湿法纺丝中纤维结构的形成研究[J].材料导报,2005,19(7):111-114.
- [16]陈娟,王成国.PAN湿法纺丝中凝固成纤过程的研究进展[J].材料导报,2006,20(9):26-28,42.
- [17]Yan-xiang Wang,et al.Effects of different coagulation conditions on polyacrylonitrile fibers wet spun in a system of dimethylsulphoxide and water[J].J Appl Polym Sci,2006,104:3723-3729.
- [18]D R Paul,et al.Diffusion during the coagulation step of wet-spinning[J].J Appl Polym Sci,1968,12(3):383-402.
- [19]Rende A,et al.A new approach to coagulation phenomena in wet-spinning[J].J Appl Polym Sci,1972,16(3):585-594.
- [20]Chen Hou,et al.Kinetics of diffusion in polyacrylonitrile fiber forma-tion[J].J Appl Polym Sci,2004,96:1529-1533.
- [21]Chen Hou,et al.Diffusion coefficient of DMF in acrylic fiber forma-tion[J].J Appl Polym Sci,2006,101:3616-3619.
- [22]Liang Ying,Chen Hou,et al.Diffusion coefficient of DMSO in poly-acrylonitrile fiber formation[J].J Appl Polym Sci,2006,100:4447-4451.
- [23]汪仁钧,吴承训,潘鼎.PAN湿法纺丝凝固成形中的凝胶化与传质[J].合成技术及应用,2005,20(2):5-7,38.
- [24]张冠,赵炯心等.DMSO湿法PAN纤维截面形状形成条件的研究[J].合成技术及应用,2005,20(4):10-14.
- [25]季保国,王成国等.湿纺凝固条件对PAN初生纤维形态结构的影响[J].合成纤维工业,2006,29(1):1-4.
- [26]J P Knudsen.The influence of coagulation lariables on the structure and physical properties of an acrylic fiber[J].Textile Res J,1963,33:13-20.
- [27]林凤崎,徐樑华等.凝固条件对PAN初生纤维微孔结构形态的影响[J].合成纤维工业,2006,29(1):16-19.
- [28]Xing-guang Dong,Cheng-guo Wang,et al.Effect of DMSO/H2O co-agulation bath on the structure and property of polyacrylonitrile fibers during wet-spinning[J].J Appl Polym Sci,2007,105:1221-1227.
- [29]Wang Qiang,et al.The effect of coagulation and stretch on the struc-ure and properties of PAN precursor by wet spinning[J].合成纤维,005,34(5):24-28.
- 30]吕永根,杨常玲等.用称重法研究聚丙烯腈树脂的凝固过程[J].新炭材料,2004,19(1):16-20.
- 31]H L Doppert,et al.The influence of stretch radio on the rate of diffu-ion in a wet-spinning process[J].J Appl Polym Sci,1973,17:893-903.
- 32]季保华,王成国等.湿法纺丝凝固负拉伸的研究[J].化工技术,006,14(1):1-4.
- 33]邬国铭等.高分子材料加工工艺学[M].中国纺织出版社,2000:134-35.
- 34]潘鼎.聚丙烯腈(PAN)基碳纤维国内技术新进展[J].技术创新,005,12:20-24.
- 35]张旺玺.提高聚丙烯腈原丝及碳纤维质量的研究[J].上海纺织科,2004,32(6);11-13.