超高性能PBO纤维的最新研究进展The Latest Research Developments of the Super High Performance PBO Fiber
江建明,李光,金俊弘,林菘,王鸣义,钱军,林生兵
JIANG Jian-ming1,LI Guang1,JIN Jun-hong1,LIN Song2,WANG Ming-yi2,QIAN Jun2,LIN Sheng-bing2 (1. College of Material Science and Engineering
摘要(Abstract):
聚对苯撑苯并二噁唑(PBO)纤维被称为21世纪的超级纤维,在强度、模量、耐高温、阻燃等方面具有超高的综合性能,PBO纤维的开发和应用具有重要的战略意义。综述了超高性能PBO纤维的国内外最新研究进展,详细介绍了PBO纤维的制备方法、性能及其应用情况,并提出了PBO纤维的发展建议。
Poly-p-phenylene benzobisthiazole (PBO) fiber was called the super fiber of 21st century. It had excellent comprehensive performance in strength,modulus,heat-resistant and flame retardance properties. Development and application of PBO fiber played a strategic role. The paper introduced the latest advance in research both at home and aboard,it's preparation,properties and application in detail. The suggestions about developing PBO fiber had been put forward.
关键词(KeyWords):
聚对苯撑苯并二噁唑;制备;性能;应用
poly-p-phenylene benzobisthiazole,preparation,property,application
基金项目(Foundation):
作者(Author):
江建明,李光,金俊弘,林菘,王鸣义,钱军,林生兵
JIANG Jian-ming1,LI Guang1,JIN Jun-hong1,LIN Song2,WANG Ming-yi2,QIAN Jun2,LIN Sheng-bing2 (1. College of Material Science and Engineering
参考文献(References):
- [1]Wolfe J F,Arnold F E.Rigid-rod polymers:1,Synthesis and thermal properties of para-aromatic polymers with2,6-benzobisthiazole unites in the main chain[J].Macromolecules,1981,14(4):909-915.
- [2]Choe E Won,Kim Sang Nim.Synthesis,spinning and mechanical properties of poly(p-phenylene benzobisoxazole)[J].Macromolecule,1981,14(4):920-924.
- [3]金宁人,黄银华,王学杰.超级纤维PBO的性能应用及研究进展[J].浙江工业大学学报,2003,31(1):82-87.
- [4]李晔,汪晓峰,沃志坤.21世纪的超级纤维-PBO纤维[J].合成纤维,2002,31(1):18-21.
- [5]雷晖,冯东东,袁明祥.液晶高分子PBO单体和聚合物的合成[J].功能高分子学报,2003,16(1):120-125.
- [6]胡建民,黄银华,金宁人.4,6-二氨基间苯二酚研究进展及合成工艺探索[J].合成技术及应用,2003,18(1):19-23.
- [7]金俊弘,李光,江建明.聚苯撑苯并二噁唑(PBO)的合成[J].东华大学学报(自然科学版),2002,28(6):122-125.
- [8]张春燕,史子兴,冷维等.采用4,6-二氨基间苯二酚-对苯二甲酸盐合成聚苯撑苯并二噁唑[J].上海交通大学学报,2003,37(5):646-649.
- [9]李金焕,许辉,黄玉东.液晶态高分子质量PBO的合成工艺及性能研究[J].合成树脂及塑料,2003,20(6):16-20.
- [10]王斌,金志浩,丘哲明等.PBO纤维缠绕复合材料的初步应用研究[J].航空材料学报,2003,23(4):35-39.
- [11]黄美荣,李新贵,朱立华.高性能芳族聚苯唑的液晶纺丝与纤维结构[J].合成纤维工业,2000,23(5):35-38.
- [12]王百亚,任鹏刚,杨建奎.PBO纤维复合材料探索研究[J].固体火箭技术,2001,24(4):66-68,71.
- [13]贾丽霞,赵洪斌,吴宏博.PBO纤维及其复合材料的研究[J].纤维复合材料,2003,(3):15-16,20.
- [14]李光,江建明,金俊弘等.聚对苯撑苯并二噁唑的制备方法及其使用的搅拌器:中国,ZL02160543.2[P].2006-07-19.
- [15]李光,杨胜林,金俊弘等.搅拌器:中国,02294359.5[P].2003-12-17.
- [16]江建明,金俊弘,杨胜林等.含有羟基基团的聚苯并二噁唑聚合物及其制备方法:中国,ZL200410025469.7[P].2006-03-15.
- [17]杨胜林,金俊弘,李光等.一类含有离子基团的聚苯并二噁唑聚合物及其制备方法:中国,ZL200410054108.5[P].2006-03-15.
- [18]李光,杨胜林,江建明等.聚对苯撑苯并二噁唑纤维的制备方法:中国,200410099003.1[P].2005-07-27.
- [19]林生兵.超高性能PBO纤维[J].金山油化纤,2005,24(1):46-47.
- [20]Zenon Lysenko,Midland Mich.High purity process for the preparation of4,6-diamino-1,3-benzenediol:US,4766244[P].1988.
- [21]泽农.利森刻.高纯度4,6-二氨基-1,3-二羟基苯的制备方法:中国,87107214[P].1988.
- [22]Kazuhiko Akimoto,Kenich Tokunaga.Processes for producing4,6-bis(substituted)phenylazoresorcinols:US,5962740[P].1990.
- [23]德永健一,白鸟元人.4,6-二氨基间苯二酚或其盐的制造方法:中国,129118[P].2001.
- [24]Bassam S,Nader,Midland Mich.Synthsis of4,6-dinitroresorcinol:US,5371291[P].1994.
- [25]熊本行宏,楠本昌彦.4,6-二氨基间苯二酚的制备方法:中国,1276369[P].2000.
- [26]H比勒,H菲格,HU布兰克.制备4,6-二氨基间苯二酚的方法:中国,1074410[P].2001.
- [27]Horst Behre,Helmut Fiege.Process for preparing4,6-dinitroresorcinol dihydrochloride:US,6093852[P].2000.
- [28]Wolfe J F,Sybert P D.Liquid crystalline polymer compositions,process,and products:US,4703103[P].1987.
- [29]Lysenko Z.High purity process for the preparation of4,6-diamino-1,3-benzenediol:EP,266222[P].1988.
- [30]Ying H S,Jerry P H,Bruce B,et al.Study of the mechanism for poly(p-phenylene)benzoxazole polymerization-A remarkable reaction pathway to make rigid-rod polymers[J].Macromolecules,1998,31:5229-5239.
- [31]Tsai T T,Arniod F E,Hwang W F.Synthesis and properties of high strength high modulus ABA block polymer[J].Polymer Science A:polymer Chemical,1989,27:2839-2848.
- [32]Gregory T,Hurting C W,Ledbetter H D,et al.Staged polymerization of polybenzazole polymers:US,5194568[P].1993.
- [33]Sybert J R,Sybert P D,Wolfe J F.Liquid crystalline polymer compositions,process,and products:US,4772678[P].1988.
- [34]Yoshio Imai,Kazuo Itoya,Masa-aki kakimoto.Synthesis of aromatic polybenzoxazoles by silylation method and their thermal and mechanical properties[J].Macromolecule Chemistry&Physics,2000,201(17):2251-2256.
- [35]Jenkins C S,Jacib K I,Kumar S.Modeling the effect of crosslinking in Methyl-pendant poly(p-phenylene benzobisthiazole).J Polym Sci,Part B,Polym Phys,1998,36:3057.
- 江建明
- 李光
- 金俊弘
- 林菘
- 王鸣义
- 钱军
- 林生兵
JIANG Jian-ming1 - LI Guang1
- JIN Jun-hong1
- LIN Song2
- WANG Ming-yi2
- QIAN Jun2
- LIN Sheng-bing2 (1. College of Material Science and Engineering
- 江建明
- 李光
- 金俊弘
- 林菘
- 王鸣义
- 钱军
- 林生兵
JIANG Jian-ming1 - LI Guang1
- JIN Jun-hong1
- LIN Song2
- WANG Ming-yi2
- QIAN Jun2
- LIN Sheng-bing2 (1. College of Material Science and Engineering