杨梅,孙润军
YANG Mei,SUN Run-jun

• 1:西安工程大学纺织与材料学院

摘要(Abstract)：

纳米纤维在污水过滤领域是最有发展前途的过滤材料。阐述了静电纺纳米纤维过滤材料对液体的过滤机制,总结了有关静电纺纳米纤维过滤材料对重金属离子和有机污染物及细菌的应用研究现状,简单讨论了纳米复合过滤材料当前存在的问题和挑战,并展望了静电纺纳米纤维过滤材料在污水处理领域的应用。
Nanofibers can be the most promising filtering materials in the field of sewage filtration. The liquid filtering mechanism of electrospinning nanofibrous filtering materials is describes. The research status of filtration on heavy metal ions, organic pollutants and bacteria by using electrospinning nanofibrous composites is summarized. The problems and challenges of nanocomposite filtering materials are briefly discussed, and the applications of electrospinning nanofiber filtering material in sewage treatment are prospected.

关键词(KeyWords)： 静电纺丝;过滤材料;过滤机制;污水处理
electrospinning;filtering material;filtration mechanism;wastewater treatment

Abstract:

Keywords:

基金项目(Foundation):

作者(Author): 杨梅,孙润军
YANG Mei,SUN Run-jun

DOI: 10.16090/j.cnki.hcxw.2017.09.017

参考文献(References)：

• [1]邹科,龙云泽,吴佑实.静电纺丝制备纳米纤维的进展及应用[J].合成纤维工业,2007,30(3):54-57.
• [2]WANG Xuefen,HSIAO Benjamin S.Electrospun nanofiber membranes[J].Current Opinion in Chemical Engineering,2016,12:62-81.
• [3]KAUR S,SUNDARRAJAN S,RANA D,et al.Review:the characterization of electrospun nanofibrous liquid filtration membranes[J].Journal of Material Sience,2014,49:6143-6159.
• [4]HOMAEIGOHAR S,ELBAHRI M.Nanocomposite electrospun nanofiber membranes for environmental remediation[J].Materials,2014,7:1017-1045.
• [5]AHMED F E,LALIA B S,HASHAIKEH R.A review on electrospinning for membrane fabrication:Challenges and applications[J].Desalination,2015,356(15):15-30.
• [6]丁彬,俞健勇.静电纺丝与纳米纤维[M].北京:中国纺织出版社,2011:1-390.
• [7]康勇,罗茜.液体过滤与过滤介质[M].北京:化学工业出版社,2008:12-89.
• [8]覃小红,王善元.静电纺纳米纤维的过滤机理及性能[J].东华大学学报(自然科学版),2007,33(1):52-56.
• [9]CHAúQUE F C E,LANGELIHLE N D,ADELODUNA A A,et al.Modification of electrospun polyacrylonitrile nanofibers with EDTA for the removal of Cd and Cr ions from water effluents[J].Applied Surface Science,2016,369:19-28.
• [10]WANG Gang,ZHANG Hao,WANG Jianren,et al.In situ synthesis of chemically active ZIF coordinated with electrospun fibrous film for heavy metal removal with a high flux[J].Separation and Purification Technology,2017,177(6):257-262.
• [11]NTHUMBI R M,ADELODUN A A,NGILA J C.Electrospun and functionalized PVDF/PAN composite for the removal of trace metals in contaminated water[J].Physics and Chemistry of the Earth,2016,8:7.
• [12]CHITPONG Nithinart,HUSSON Scott M.Polyacid functionalized cellulose nanofiber membranes for removal of heavy metals from impaired waters[J].Journal of Membrane Science,2017,523(3):418-429.
• [13]WANJALE Santosh,BIRAJDAR Mallinath,JOG Jyoti,et al.Surface tailored PS/Ti O2composite nanofiber membrane for copper removal from water[J].Journal of Colloid and Interface Science,2016,469(9):31-37.
• [14]LI Lei,LI Yanxiang,YANG Chuanfang.Chemical filtration of Cr(VI)with lectrospun chitosan nanofiber membranes[J].Carbohydrate Polymers,2016,140(8):299-307.
• [15]SUN Bolun,LI Xiang,ZHAO Rui,et al.Hierarchical aminated PAN/γ-Al OOH electrospun composite nanofibers and their heavy metal ion adsorption performance[J].Journal of the Taiwan Institute of Chemical Engineers,2016,62(3):219-227.
• [16]XIN Shangjing,ZENG Zhaoyang,ZHOU Xue,et al.Recyclable Saccharomyces cerevisiae loaded nanofibrous mats with sandwich structure constructing via bio-electrospraying for heavy metal removal[J].Journal of Hazardous Materials,2017,324(4):365-372.
• [17]BEHESHTI Hoda,IRANI Mohammad,HOSSEINI Layla,et al.Removal of Cr(VI)from aqueous solutions using chitosan/MWCNT/Fe3O4composite nanofibers-batch and column studies[J].Chemical Engineering Journal,2016,284(2):557-564.
• [18]ASKARI Mohsen,REZAEI Babak,AHMAD Mousavi Shoushtari,et al.Performanceimprovements in structural characteristics of chitosanbased nanofibrous composite membrane for using in liquid filtration[J].Journal of the Taiwan Institute of Chemical Engineers,2015,56(11):77-83.
• [19]HAIDER S,BINAGAG F F,HAIDER A.Electrospun oxime-graftedpolyacrylonitrile nanofiber membrane and its application to the adsorption of dyes[J].Journal of Polymer Research,2014,21(3):1-13.
• [20]ZHAO Rui,WANG Yong,LI Xiang,et al.Water-insoluble sericin/-cyclodextrin/PVA composite electrospun nanofibers as effective adsorbents towards methylene blue[J].Colloids and Surfaces B:Biointerfaces,2015,136(12):375-382.
• [21]PENG Chen,ZHANG Jiulong,XIONG Zuogang,et al.Fabrication of porous hollow-Al2O3nanofibers by facile electrospinning and its application for water remediation[J].Microporous and Mesoporous Materials,2015,215(19):133-142.
• [22]MOHAMED Alaa,EL-SAYED Ramy,OSMAN T A,et al.Composite nanofibers forhighly efficient photocatalytic degradation of organic dyes from contaminated water[J].Environmental Research,2016,145(2):18-25.
• [23]MALWAL Deepika,GOPINATH P.Efficient adsorption and antibacterial properties of electrospun Cu O-Zn O composite nanofibers for water remediation[J].Journal of Hazardous Materials,2017,321(1):611-621.
• [24]GHASEMI Ensieh,ZIYADI Hakimeh,AFSHAR Ashkan Moein,et al.Iron oxide nanofibers:A new magnetic catalyst for azo dyes degradation in aqueous solution[J].Chemical Engineering Journal,2015,264(6):146-151.
• [25]CHAúQUEA E F C,NGILA J C,ADELODUNA A A,et al.Electrospun polyacrylonitrile nanofibers functionalized with EDTA for adsorption of ionic dyes[J].Physics and Chemistry of the Earth,2016,10:8.
• [26]ALMASIAN Arash,NAJAFI Farhood,MIRJALILI Mohammad,et al.Zwitter ionic modification of cobalt-ferrite nanofiber for the removal of anionic and cationic dyes[J].Journal of the Taiwan Institute of Chemical Engineers,2016,67(10):306-317.
• [27]GUO Jie,ZHANG Qing,CAI Zhijiang,et al.Preparation and dye filtration property of electrospun polyhydroxybutyrate-calcium alginate/carbon nanotubes composite nanofibrous filtration membrane[J].Separation and Purification Technology,2016,161(5):69-79.
• [28]AMIN M T Al AZBA A A,MANZOOR U.et al.A review of removal of pollutants from water/wastewater using different types of nanomaterials[J].Advances in Materials Science and Engineering,2014(1):1-24.
• [29]QU Xianlei,J J ALAREI Pedro,LI Qilin.Applications of nanotechnology in water and wastewater treatment[J].International Journal of Innovative and Emerging Research in Engineering,2(1):21-26.
• [30]MA Hongyang,S HSIAO Benjamin,CHU Benjamin.Functionalized electrospun nanofibrous microfiltration membranes for removal of bacteria and viruses[J].Journal of Membrane Science,2014,452(4):446-452.
• [31]JAVIER SANTIAGO-MORALES,GEORGIANA AMARIEI,PEDRO LETóN.Antimicrobial activity of poly(vinyl alcohol)-poly(acrylic acid)electrospun nanofibers[J].Colloids and Surfaces B:Biointerfaces,2016,146(10):144-151.
• [32]YUAN Guohao,PRABAKARAN Mayakrishnan,SUN Qilong,et al.Cyclodextrin functionalized cellulose nanofiber composites for the faster adsorption of toluene from aqueous solution[J].Journal of the Taiwan Institute of Chemical Engineers,2017,70(1):352-358.
• [33]KAYACI Fatma,AYTAC Zeynep,UYAR Tamer,et al.Surface modification of electrospun polyester nanofibers withcyclodextrin polymer for the removal of phenanthrene fromaqueous solution[J].Journal of Hazardous Materials,2013,261(11):286-294.
• [34]ASLAN Taha,ARSLAN Serkan,EYVAZ Murat,et al.A novel nanofiber microfiltration membrane:Fabrication and characterization of tubular electrospun nanofiber(Tu EN)membrane[J].Journal of Membrane Scienc,2016,520(24):616-629.
• [35]ALI REHAB M,HAMADA HESHAM A,HUSSEINB MOHAMED M,et al.Potential of using green adsorbent of heavy metal removal from aqueous solutions:Adsorption kinetics,isotherm,thermodynamic mechanism and economic analysis[J].Ecological Engineering,2016,91(6):317-332.