李东娟;李坤兰;马英冲;宫国梁;王少君;曲丰作;
LI Dong-juan1, LI Kun-lan1, MA Ying-chong1, GONG Guo-liang2, QU Feng-zuo1 (1. Dalian Institute of Light Industry, Dalian Liaoning 116034; 2. State Key Laboratory of Fine Chemistry, Dalian University of Technology, Dalian Liaoning 116012)

• 1:大连轻工业学院
• 2:大连轻工业学院
• 3:大连轻工业学院
• 4:大连理工大学精细化工国家重点实验室

摘要(Abstract)：

离子液体以其熔点低、蒸气压小、酸性可调及良好的溶解性能、黏度、密度等优异的理化特性成为纤维素的新型溶剂。离子液体与传统的纤维素溶剂相比,具有低挥发性、可回收利用、热性质稳定的优点,避免了有机溶剂所造成的污染。介绍了纤维素在离子液体溶剂体系中的溶解、再生和衍生的研究进展。
Ionic liquid is new developed solvent system for dissolving cellulose. Ionic liquid has intrinsically useful properties, such as thermal stability, lower melting point, negligible vapour pressure, acidity changeable and highly solvating, low viscosity and density. Ionic liquid is nonvolatile, nonflammable and recycled solvent. This nonvolatile nature suggests that ionic liquid might potentially be the "green solvents", alternatives to the conventional volatile organic solvents. Recent developments of the ionic liquid to cellulose dissolved, regenerated and homogeneous reaction are reviewed in this paper.

关键词(KeyWords)： 离子液体;纤维素;再生;均相衍生
Ionic liquids, cellulose, regenerated, homogeneous reaction

Abstract:

Keywords:

基金项目(Foundation): 国家重大基础研究计划项目(No.2003CB615805)

作者(Authors): 李东娟;李坤兰;马英冲;宫国梁;王少君;曲丰作;
LI Dong-juan1, LI Kun-lan1, MA Ying-chong1, GONG Guo-liang2, QU Feng-zuo1 (1. Dalian Institute of Light Industry, Dalian Liaoning 116034; 2. State Key Laboratory of Fine Chemistry, Dalian University of Technology, Dalian Liaoning 116012)

参考文献(References)：

• [1]Barthel S,Heinze T.Acylation and carbanilation of cellulose in ionic liquids[J].Green Chem,2006,8:301-306.
• [2]Mohanty A K,Misra M,Drzal L T.Sustainable bio-composites from renewable resources:opportunities and challenges in the green materi-alsworld[J].Journal of Polymers and the Environment,2002,10(1-2):19-26.
• [3]高洁,汤烈贵.纤维素科学[M].北京:科学出版社,1999.24-27.
• [4]胡雪生,余江.离子液体的绿色合成及环境性质[J].化学通讯,2005,(12):906-910
• [5]Swatloski R P,Spear S K,Holbrey J D,et al.Dissolution of cellose with ionic liquids[J].J Am Chem Soc,2002,124:4974-4975.
• [6]任强,武进,张军等.1-烯丙基,3-甲基咪唑室温离子液体的合成及其对纤维素溶解性能的初步研究[J].高分子学报,2003,(3):448-451.
• [7]罗惠谋,李毅群,周长忍等.功能化离子液体对纤维素的溶解性能研究[J].高分子材料科学与工程,2005,21(2):233-235.
• [8]刘仁庆.纤维素化学基础[M].北京:科学出版社,1985.190-192.
• [9]魏虹玢,渠少林,魏良等.溶剂法生产纤维素纤维[J].机械管理开发,2001,5(2):27-28.
• [10]万雅波,李凤霞.溶剂法纤维素纤维的工艺、性能及其发展[J].纺织学报,1998,19(4):61-64.
• [11]吴江.α-纤维素膜的制备、性能及应用研究[D]:[博士论文].大连:中国科学院大连化学物理研究所,2002.
• [12]吴翠玲,李新平,秦胜利.纤维素溶剂研究现状及应用前景[J].中国造纸学报,2004,19(2):171-175.
• [13]任强.纤维素在离子液体中的溶解性能研究[D]:[硕士论文].北京:北京航空航天大学,2003.
• [14]杨淑惠.植物纤维化学[M].北京:中国轻工业出版社,2001.188.
• [15]程博闻.纤维素在LiCl极性溶剂体系中溶解性能的研究[J].天津纺织工学院学报,2000,19(2):1-3.
• [16]Heinze T,Liebert T.Unconventional methods in cellulose functional-ization[J].Prog Polym Sci,2001,26(9):1689-1762.
• [17]解芳,邵自强.天然纤维素纤维的溶解机理及纺丝技术发展[J].华北工学院报,2002,23(2):199-203.
• [18]刘瑞刚,沈弋弋,邵惠丽等.纤维素/NMMO·H2O溶液的熔融和固化行为[J].中国纺织大学学报,2000,12(6):114-130.
• [19]肖长发.NMMO/DMSO溶剂体系对纤维素溶解作用的研究[J].纤维素科学与技术,1994,2(3-4):66-71.
• [20]吴翠玲,李新平,秦胜利等.新型有机纤维素溶剂NMMO的研究[J].兰州理工大学报,2005,31(2):73-76.
• [21]Branco L B,Rosa J N,Ramos J J M,et al.Preparation and charac-terization of new room temperature ionic liquids[J].Chem Eur J,2002,8(16):3671-3677.
• [22]李汝雄,王建.绿色溶剂-离子液体的制备与应用[J].化工进展,2001,21(1):43-48.
• [23]顾彦龙,彭家建,乔琨等,室温离子液体及其在催化和有机合成中的应用[J].化学进展,2003,15(3):222-241.
• [24]Blanchard L A,Hancu D,Beckman E J,et al.Green processing us-ing ionic liquid and CO2[J].Nature,1999,399:28-29.
• [25]Welton T.Room-temperature ionic liquid-solvents for synthesis and catalysis[J].Chem Rev,1999,99:2071-2083.
• [26]Wilkes J S.A short history of ionic liquid-from molten salts to neo-teric solvents[J].Green Chemistry,2002,4:73-80.
• [27]Heinze T,Schwikal K,Barthel S.Ionic liquids as reaction medium in cellulose fxunctionalization[J].Macromol Biosci,2005,5:520-525.
• [28]Zhu Y J,Wang W W,Qi R J,et al.Microware assisted synthesis of single-crystalline tellurium nanorods and nanowires in ionic liquid[J].Angew Chem Int Ed,2004,43:1410-1414.
• [29]李雪辉,张磊,王乐夫等.N-羧基吡啶功能化离子液体的表征[J].物理化学学报,2006,22(4):430-435.
• [30]Heinze T,Dicke R,Koschella A,et al.Effective preparation of cel-lulose derivatives in a new simple cellulose solvent[J].Macromol Chem Phys,2000,201:627-631.
• [31]赵家森,王渊龙,程博闻.绿色纤维素纤维——Lyocell纤维[J].纺织学报,2004,25(5):124-127.
• [32]Marson G A,El Seoud O A.A novel,efficient procedure for acylation of cellulose under homogeneous solution conditions[J].Journal of Applied Polymer Science,1999,24:1355-1360.
• [33]许冬生.纤维素衍生物[M].北京:化学工业出版社,2001.7-12.
• [34]任天瑞,沈斌,李永红等.纤维素的均相化学反应[J].化学进展,2004,16(6):948-953.
• [35]Wu J,Zhang J,Zhang H,et al.Homogeneous acetylation of cellulose in a new ionic liquid[J].Biomacromolecules,2004,(5):266-268.
• [36]武进,张昊,张军等.纤维素在离子液体中的均相乙酰化及其选择性[J].高等学校化学学报,2006,27(3):592-594.