聚苯胺/聚丙烯导电纤维的制备Preparing of Polyaniline/Polypropylene Conducting Fibers
张鸿,王立久
ZHANG Hong1,2
摘要(Abstract):
采用现场吸附聚合法制备了聚苯胺/聚丙烯导电纤维,研究了盐酸浓度、氧化剂浓度、苯胺单体含量、反应温度、反应时间等反应条件对纤维上聚苯胺含量的影响,并研究了改变纤维截面形状和粗细、共混纺丝、表面等离子体处理等改性处理对纤维上聚苯胺含量的影响。
Polyaniline/PP conducting fibers were obtained using in-situ adsorption polymerization. The effects of hydrcochloric acid concentration, oxidizer concentration, polyaniline monomer content, reaction temperature, reaction time, etc on polyaniline content of fiber were studied. The influence of changing fiber cross section and diameter, blending spinning and surface treatment with plasma on polyaniline content of fiber was also investigated.
关键词(KeyWords):
苯胺;聚丙烯纤维;现场吸附聚合;反应条件;纤维改性
polyaniline, PP, in-situ adsorption polymerization, reaction condition, fiber modification
基金项目(Foundation): 辽宁省自然科学基金资助项目(20062147);; 辽宁省教育厅资助项目(20040099)。
作者(Author):
张鸿,王立久
ZHANG Hong1,2
参考文献(References):
- [1]景遐斌,王利祥,王献红等.导电聚苯胺的合成、结构、性能和应用[J].高分子学报,2005,(5):655-663.
- [2]Vasileva I S,Morozova O V,et al.Laccase-catalyzed synthesis o optically active polyaniline[J].Synthetic Metals,2007,157(18-20):684-689.
- [3]Kim B,Koncar V,et al.Electrecal and morphological properties of PP and PET condrctive polymer fibers[J].Synthetic Metals,2004,146(2)167-174.
- [4]潘玮,黄素萍,龚静华.聚苯胺涤纶导电纤维的制备及其织物抗静电性能研究[J].合成纤维,2002,31(1):30-31.
- [5]Macdiarmid A G,Epstein A J.The polyaniline,molecular weight oxidation state and derivatives[J].Polymer Preprint,1989,30:147-152.
- [6]MacdiarmidA G.The production of conducting polymer fibers:.US,5177187[P].1993.12,22.
- 苯胺
- 聚丙烯纤维
- 现场吸附聚合
- 反应条件
- 纤维改性
polyaniline, PP, in-situ adsorption polymerization, reaction condition, fiber modification