硅烷偶联剂改性芳纶工艺研究Study on Modification of Aramid Fiber with Silane Coupling Agent
王彦杰,孟家光,张永锋
WANG Yan-jie,MENG Jia-guang,ZHANG Yong-feng
摘要(Abstract):
采用KH550硅烷偶联剂处理芳纶,将处理温度、时间、硅烷偶联剂的质量分数作为3个因素进行分析,通过单因素分析法确定每个因素对处理前后芳纶与树脂的界面剪切强度的影响,结合扫描电镜观察处理前后纤维的表面结构变化,得到最佳处理的工艺为:处理时间9 h、温度45℃、硅烷偶联剂的质量分数为25%。
Aramid fiber was modified with silane coupling agent KH550. The treatment temperature, time, concentration of the silane coupling agent were analyzed as three factors. Each of these factors was determined by the single factor analysis before and after treatment, combined with the influence of the interfacial shear strength of aramid fiber and resin, fiber surface structure changes observed before and after treatment with scanning electron microscope, the optimal treatment processes were: time 9 h, temperature 45 ℃, concentration of silane coupling agent 25%.
关键词(KeyWords):
芳纶;硅烷偶联剂;界面剪切强度
aramid fiber;silane coupling agent;interfacial shear strength
基金项目(Foundation): 国家支撑计划项目(2012BAF13B03);; 陕西省重点学科专项资金支助项目(2008169);; 陕西省产业用纺织品协同创新中心科研资助项目(2015ZX-06)
作者(Author):
王彦杰,孟家光,张永锋
WANG Yan-jie,MENG Jia-guang,ZHANG Yong-feng
DOI: 10.16090/j.cnki.hcxw.2017.01.013
参考文献(References):
- [1]周宏.对位芳纶应用技术发展水平比较研究[J].新材料产业,2013(5):59-69.
- [2]浦丽莉,黄恒钧,林鹏.芳香族聚酰胺纤维改性技术研究进展[J].化学与黏合,2013(3):58-61.
- [3]王彧婕.介质阻挡放电等离子体改性芳纶纤维的界面性质的研究[D].四川大学,2007.
- [4]王海霞,谢光银,陈前维.芳纶的表面处理方法[J].产业用纺织品,2012(2):32-34.
- [5]李斌,杜华太,张洪民,等.芳纶与橡胶界面粘合技术的研究进展[J].橡胶工业,2012(12):757-761.
- [6]金辉,王一雍.芳纶纤维表面改性技术及相关机理的研究进展[J].化工新型材料,2009(3):24-26,58.
- [7]CHEN P,WANG J,WANG B C,et a1.Improvement of interfacial adhesion for plasma-treated aramid fibers reinforced poly(phthalazinone ether sulfone ketone)composite and fiber surface aging effects[J].Surface and Interface Analysis,2009,41(1):38-43.
- [8]张卫昌,李冲,殷守华,等.芳纶常用表面改性方法及其在橡胶制品中的应用(二)[J].橡胶科技市场,2007(20):9-11,16.
- [9]张艳华.γ-射线辐照改性对芳纶纤维及其复合材料性能的影响[D].哈尔滨:哈尔滨工业大学,2008.
- [10]何淼.γ-射线辐照对国产芳纶纤维及其复合材料界面性能的影响[D].哈尔滨:哈尔滨工业大学,2011.