阻燃涤纶织物的现状及发展Status and Development of Flame Retardant Polyester Fabric
王鲁英;嘎力巴;刘姝;姜佳嫱;张园园;
WANG Lu-ying,GA Li-ba,LIU Shu,JIANG Jia-qiang,ZHANG Yuan-yuan(College of Chemistry and Materials Science,Liaoning Shihua University,Fushun 113001,Liaoning,China)
摘要(Abstract):
概述了国内外涤纶阻燃改性的研究情况,综述了涤纶阻燃处理方法,分析了卤系和磷系阻燃剂及其对涤纶的阻燃改性的优缺点,介绍了涤纶的燃烧机制、阻燃机制、阻燃方法以及阻燃性能的测试方法。涤纶阻燃改性中所用的阻燃剂主要是通过吸热、覆盖和稀释等机制发挥阻燃作用的。分析了涤纶阻燃整理存在的问题,讨论了阻燃涤纶的发展趋势。
The situation of research of flame retardant polyester fiber at home and abroad and their processing methods are summarized.The halogen and phosphorus flame retardant and their advantages and disadvantages of polyester fiber modified by above-mentioned flame retardants are investigated.The test methods of combustion mechanism of polyester fiber,flame retarding mechanism,way and performance of flame retardance are introduced.The function of flame retardant in polyester fiber modification is heat absorbing,covering and diluting.The problem and development trend of flame retardant polyester fiber are analyzed.
关键词(KeyWords):
涤纶;阻燃整理;阻燃剂;阻燃机理
polyester fiber,flame retardant finishing,flame retardant agent,flame retardant mechnism
基金项目(Foundation):
作者(Authors):
王鲁英;嘎力巴;刘姝;姜佳嫱;张园园;
WANG Lu-ying,GA Li-ba,LIU Shu,JIANG Jia-qiang,ZHANG Yuan-yuan(College of Chemistry and Materials Science,Liaoning Shihua University,Fushun 113001,Liaoning,China)
DOI: 10.16090/j.cnki.hcxw.2011.10.020
参考文献(References):
- [1]张榕,朱新生,周舜华,等.涤纶阻燃技术进展[J].合成纤维,2006,35(8):9-12.
- [2]夏延致.涤纶专用阻燃剂的发展及其技术应用[J].纺织信息周刊,2004,46:16.
- [3]江海红,金日光,周亨近.阻燃PET及其纤维的燃烧性能-燃烧机理-群子参数之间关系的研究[J].北京化工大学博士学位论文,2000:1-20.
- [4]赵雪,展义臻,何谨馨.涤纶无卤阻燃研究进展[J].染整技术,2008(12):12-14.
- [5]王兴福,孙丽华.涤纶面料阻燃整理技术的应用[C].第七届全国印染后整理学术研讨会,2005:1-5.
- [6]宗小燕,贺江平,等.纺织品的阻燃综述[J].染整技术,2006,28(10):10-12.
- [7]张利强,劳继红,等.窗帘用涤纶机织物的后整理研究[D].上海:东华大学,2009:18-21.
- [8]余梨花,张胜,等.涤纶织物阻燃后处理的研究[D].北京:北京化工大学,2010:16-19.
- [9]翟中凯,郭永林,李卫华,等.含磷永久性阻燃涤纶的生产和应用[J].广西化纤通讯,2000(1):9-12.
- [10]Levchik V S,Well DE.Review flame redundancy of thermoplasticpolyesters-a review of the recent literature[J].Polym Int,2005,54:11-35.
- [11]曹令,周永凯.纺织品阻燃整理技术的应用与进展[J].中国个体防护装备,2007(3):24-28.
- [12]黄秀丽.阻燃织物的应用和发展[J].中国纤检,2010(3):81-83.
- [13]郑毅,闵洁.涤纶用阻燃剂与分散染料同浴加工研究[D].东华大学硕士学位论文,2008.
- [14]姚培建.阻燃纤维及阻燃纺织品发展趋势[J].中国个体防护装备,2006(2):41-44.
- [15]Cornelius Hamciuc Tachita Vlad-Bubulac,Oana Petreus,GabrielaLisa.Synthesis and characterization of new aromatic polyesters and poly(ester-imide)s containing phosphorous cyclic bulky groups[J].PolymerBulletin,2008 60,657-664.
- [16]Salgaonkar L P,Jayaram R V.Thermal and Flame-retardantproperties of polyester fabric grafted with polyaniliness[J].J Appl Polymsci,2004,93:1 981-1 988.
- [17]GB/T 8746—2001《纺织品燃烧性能:垂直方向试样易点燃性的测定》[s].北京:中国标准出版社,2001.
- [18]GB/T 5455—1997《纺织品燃烧性能实验》:垂直法[s].北京:中国标准出版社,1997.
- [19]GB/T 14645—1993《纺织织物燃烧性能:45°方向损毁面积和接焰次数测定》[s].北京:中国标准出版社,1993.
- [20]GB/T 14644—1993纺织织物燃烧性能:45°方向燃烧速率测定[s].北京:中国标准出版社,1993.
- [21]GB/T 8745—2001《纺织品燃烧性能:织物表面燃烧时间的测定》[s].北京:中国标准出版社,2001.
- [22]乔欣,王跃强,李保梅.纺织品阻燃性能测试[J].染料与染色,2010,47(2):57-59.
- [23]金美菊,石东亮,洪武勇.纺织品燃烧性能测试方法比较[J].针织工业,2010(2):60-61.
- [24]刘晓艳,徐鹏.纺织品阻燃性能的测试[J].中国纤检,2004(5):19-21.
- [25]刘松梅,潘守伟.涤纶的改性方法研究[J].化纤与纺织技术,2008(2):24-27.
- [26]刘会媛.无机阻燃剂的制备及改性应用[J].河北化工,2004(1):18-20.
- [27]张利强,劳继红.窗帘用阻燃机织物的后整理研究[D].东华大学,2009:8-13.
- [28]代培刚,刘志鹏,陈英杰,等.无机阻燃剂发展现状[J].广东化工,2008,35(7):62-64.
- 涤纶
- 阻燃整理
- 阻燃剂
- 阻燃机理
polyester fiber,flame retardant finishing,flame retardant agent,flame retardant mechnism
- 王鲁英
- 嘎力巴
- 刘姝
- 姜佳嫱
- 张园园
WANG Lu-ying- GA Li-ba
- LIU Shu
- JIANG Jia-qiang
- ZHANG Yuan-yuan(College of Chemistry and Materials Science
- Liaoning Shihua University
- Fushun 113001
- Liaoning
- China)
- 王鲁英
- 嘎力巴
- 刘姝
- 姜佳嫱
- 张园园
WANG Lu-ying- GA Li-ba
- LIU Shu
- JIANG Jia-qiang
- ZHANG Yuan-yuan(College of Chemistry and Materials Science
- Liaoning Shihua University
- Fushun 113001
- Liaoning
- China)