王学利,张晨,俞建勇,徐卫海,娄雪芹,李乃强
WANG Xue-li,ZHANG-Chen,YU Jian-yong,XU Wei-hai,LOU Xue-qin,LI Nai-qiang

• 1:东华大学研究院
• 2:东华大学纺织学院
• 3:上海凯赛生物技术研发中心有限公司

摘要(Abstract)：

生物基聚己二酸戊二胺(聚酰胺56)是由生物基戊二胺和石油基己二酸聚合而成,通过核磁共振、红外光谱、元素分析表征了生物基聚酰胺56的结构,通过差示扫描量热分析、热重分析研究了生物基聚酰胺56的热性能,采用高速纺丝、拉伸两步法进行纺丝试验,并测试了其物理性能。与现有石油基聚酰胺66、聚酰胺6的性能相比,生物基聚酰胺56可纺性良好,纤维的力学性能较好,亲水性能优于聚酰胺6和聚酰胺66,是一种具有广泛应用前景的生物质纤维材料。
Biologicalbased poly(adipic acid- 1,5- diaminopentane)(bio- PA56) is synthesized by the bio-based pentamethylene diamine and petroleum-based adipic acid. The structure of bio-PA56 was confirmedby1 H NMR, infrared spectroscopy, and elemental analysis. The thermal properties of bio-PA56 were charac-terized by DSC and TG. By the two-step preparation of high speed spinning and tensile process, the physi-cal properties of bio-PA56 were compared with existing petroleum-based PA66 and PA6. Results showedthat bio-56 exhibited good spinning ability and mechanical property, and its hydrophilic performance wassuperior to PA6 and PA66. This bio-based fibrous material has promising application.

关键词(KeyWords)： 生物基聚己二酸戊二胺;结构;高速纺;性能
biologicalbased poly(adipic acid-1,5-diaminopentane),structure,high speed spinning,property

Abstract:

Keywords:

基金项目(Foundation):

作者(Author): 王学利,张晨,俞建勇,徐卫海,娄雪芹,李乃强
WANG Xue-li,ZHANG-Chen,YU Jian-yong,XU Wei-hai,LOU Xue-qin,LI Nai-qiang

DOI: 10.16090/j.cnki.hcxw.2015.09.001

参考文献(References)：

• [1]KOHAN M I.Nylon Plastics Handbook[M].New York:Hanser Publishers,1995:74-85.
• [2]朱吴兰.红外光谱法鉴别不同种类聚酰胺[J].塑料,2009(3):114-117
• [3]赵天增.核磁共振氢谱[M].北京大学出版社(第一版),1987:30.
• [4]牵伸作用对尼龙6纤维晶型结构及力学性能的影响[J].高分子学报,2012(12):1 643-1 647.
• [5]WARD I M,WILDING M A,BRODY H.The mechanical properties and structure of poly(m-methylene terephthalate)fiber[J].Journal of Polymer Seience,1976,14:263-274.
• [6]程英超.基于热分析方法的PTT和PET纤维定性鉴别及其混纺产品定量分析方法研究[D].苏州:苏州大学纺织学院,2014:21-22.
• [7]李建华.PTT及PTT/PET共聚酯的结构[D].北京:北京化工大学材料科学与工程学院,2006:35-39.