硅氮系阻燃黏胶纤维的结构与性能研究Study on Structure and Properties of Silicon-Nitride Flame Retardante Viscose Fiber
张美荣,冉国庆,姚勇波,刘承修,姜沪,陈烨
ZHANG Mei-rong,RAN Guo-qing,YAO Yong-bo,LIU Cheng-xiu,JIANG Hu,CHEN Ye
摘要(Abstract):
分析了硅氮系阻燃黏胶纤维的结构与性能,探讨其阻燃机制。通过扫描电子显微镜、X射线衍射、力学性能以及极限氧指数等测试,分析了硅氮系阻燃剂含量对纤维阻燃性能、热性能和力学性能等的影响。结果表明:当阻燃剂质量分数为20%时,纤维的干态断裂强度为2.1 cN/dtex,极限氧指数为28%,在满足纺织服用需求的同时,达到国家阻燃标准,兼具安全环保与良好的阻燃性能。
The structure and properties of silicon-nitride flame retardant viscose fiber and its flame retardant mechanism were mainly analyzesd. Scanning electron microscopy, X-ray diffraction, mechanical properties and limiting oxygen index were used to analyze the effects of silicon-nitride flame retardant on fiber flame retardancy, thermal properties and mechanical properties. The results show that when the flame retardant content is 20%, the dry rupture strength is 2.1 cN/dtex, and the limiting oxygen index of the fiber is 28%. It meets the national flame retardant standard while meeting the textile demand, and it is safe,environmentally friendly and has good flame retardant properties.
关键词(KeyWords):
黏胶纤维;硅氮系阻燃剂;极限氧指数
viscose fiber;silicon-nitride flame retardant;limiting oxygen index
基金项目(Foundation): 国家重点研发计划项目课题(2017YFB0309000)
作者(Author):
张美荣,冉国庆,姚勇波,刘承修,姜沪,陈烨
ZHANG Mei-rong,RAN Guo-qing,YAO Yong-bo,LIU Cheng-xiu,JIANG Hu,CHEN Ye
DOI: 10.16090/j.cnki.hcxw.20190531.002
参考文献(References):
- [1]邱有龙.黏胶纤维行业新技术、新产品的发展现状及趋势(Ⅰ)[J].纺织导报,2010(9):84-87.
- [2]HE Y,CHEN Y,ZHENG Q,et al.Preparation and properties of flameretardant viscose fiber modified with poly[bis(methoxyethoxy)phosphazene][J].Fibers and Polymers,2015,16(5):1005-1011.
- [3]KANDOLA B K,HORROCKS A R,PRICE D,et al.Flame-retardant treatments of celluloseand their influence on the mechanism of cellulose pyrolysis[J].Journal of Macromolecular Science,Part C:Polymer Reviews,1996,36(4):721-794.
- [4]周翠荣,董奎勇,杨萍.阻燃黏胶纤维及其研究现状[J].人造纤维,2004,34(4):22-26.
- [5]WANG S,SUI X,LI Y,et al.Durable flame retardant finishing of cotton fabrics with organosilicon functionalized cyclotriphosphazene[J].Polymer Degradation and Stability,2016,128:22-28.
- [6]杨东昌,齐鲁.黏胶纤维阻燃改性方法[J].毛纺科技,2016,44(6):54-57.
- [7]陈胜,郑庆康,叶光斗,等.烷氧基环三磷腈共混改性阻燃黏胶纤维阻燃机理研究[J].工程科学与技术,2006,38(2):109-113.
- [8]全凤玉,纪全,夏延致,等.阻燃黏胶纤维的研究及其进展[J].纺织学报,2004,25(1):121-12
- [9]JIANG S,YU B,ZHOU K,et al.Sol-gelsynthesis and enhanced propertiesof a novel transparent PMMAbased organic-inorganichybrid containing phosphorus,nitrogen and silicon[J].Journal of Sol-Gel Science and Technology,2014,69(2):418-428.
- [10]全凤玉.阻燃黏胶的制备及性能研究[D].青岛:青岛大学,2003.
- [11]刘承修,毕慎平.一种环保型阻燃剂及其制备方法和应用:CN104032401B[P].2014-09-10.
- [12]刘承修,毕慎平.一种环保型耐高温耐久性阻燃纤维及其制备方法:CN 103789858A[P].2014-05-14.
- [13]李娟,邱纯利,李建勇.硅氮系阻燃黏胶纤维的开发[J].人造纤维,2012(3):9-11.
- [14]CHEN X,BURGER C,FANG D,et al.X-ray studies of regenerated cellulose fibers wet spun from cotton linter pulp in NaOH/thiourea aqueous solutions[J].Polymer,2006,47(8):2839-2848.
- [15]张瑞文.共混改性阻燃黏胶纤维的性能研究[J].中原工学院学报,2009,20(6):17-20.
- [16]曾静.阻燃纤维素/SiO2纳米复合纤维的研究[D].青岛:青岛大学,2007.
- [17]JIANG G,HUANG W,LI L,et al.Structure and properties of regenerated cellulose fibers from different technology processes[J].Carbohydrate Polymers,2012,87(3):2012-2018.
- [18]冉国庆.有机硅氮系阻燃再生纤维素纤维的阻燃、远红外及抗菌性能研究[J].人造纤维,2017(4):7-11.
- [19]CHIANG C L,CHANG R C.Synthesis,characterization and properties of novely,2008,68(14):2849-2857.
- [20]李树锋,程博闻,孙坤松,等.接枝阻燃改性粘胶纤维性能测试[J].纺织学报,2006,27(8):61-63.
- [21]HSIEH C Y,SU W C,WU C S,et al.Benzoxazine-containing branched polysiloxanes:Highly efficient reactive-type flame retardants and property enhancement agents for polymers[J].Polymer,2013,54(12):2945-2951.
- [22]KASHIWAGI T,MORGAN A B,ANTONUCCI J M,et al.Thermal and flammability properties of a silica-poly(methylmethacrylate)nanocomposite[J].Journal of Applied Polymer Science,2003,89(8):7.