聚丙烯改性及其抗老化性能的研究进展Research Progress of Polypropylene Modification and Its Anti-Aging Properties
杨洋,赵强,朱琦,钟雯
YANG Yang,ZHAO Qiang,ZHU Qi,ZHONG Wen
摘要(Abstract):
聚丙烯是一种开发应用非常广泛的通用塑料,但受紫外线、氧气和热的作用易发生老化致使性能下降,限制了其应用范围和发展前景。针对这一问题,综述了聚丙烯改性的方法,同时也介绍了聚丙烯老化机制和国内外抗老化聚丙烯的研究现状,并指出研究改性抗老化聚丙烯材料将具有深远的理论意义和实际应用价值。
Polypropylene is a general-purpose plastic with a very wide range of development and application. Howerer, it is prone to aging due to the effects of ultraviolet rays, oxygen and heat, resulting in performance degradation which limites its application scope and development prospects. In view of this problem,the modification methods of polypropylene are summarized, the aging mechanism of polypropylene and the research status at home and abroad are also introduced, and it is pointed out that the research of modification of aging resistant polypropylene material will have far-reaching theoretical significance and practical application value.
关键词(KeyWords):
聚丙烯;改性;老化
polypropylene;modification;aging
基金项目(Foundation): 教育部“春晖”计划合作科研项目;; 西华大学“西华杯”创新创业项目;; 四川省科技厅重点资助研发项目资助
作者(Author):
杨洋,赵强,朱琦,钟雯
YANG Yang,ZHAO Qiang,ZHU Qi,ZHONG Wen
DOI: 10.16090/j.cnki.hcxw.2021.02.003
参考文献(References):
- [1]孔令光,陈赵文,霍伟智.耐老化聚丙烯的研究进展[J].广东化工,2020, 47(16):81-82.
- [2]武卫莉,李响.改性聚丙烯纤维研究进展[J].工程塑料应用, 2020,48(1):128-131.
- [3]杨帅.基于聚丙烯复合材料的制备及其性能研究[D].长春:长春工业大学, 2018.
- [4]罗志,李化毅,张辽云.超细聚丙烯固相接枝马来酸酐用作相容剂的研究[J].石油化工, 2017, 46(6):731-738.
- [5]李庆华,张峻岭,邓颖薇,等.聚丙烯改性技术及应用[J].当代化工研究, 2019(4):180-181.
- [6]王飞,王浩江,雷祖碧,等.滑石粉填充PP复合材料的耐候改性研究[J].合成材料老化与应用, 2018, 47(4):13-15.
- [7]彭志宏,唐昌伟,张旭文.丙烯基弹性体对聚丙烯增韧改性的研究[J].合成材料老化与应用, 2015,44(5):11-14.
- [8] RICCO T, PAVAN A, DANUSSO F. Crazing within glassy occlusions in rubber particles of toughened glassy polymers:a micromechanical investigation[J]. 1979, 20(3):367-370.
- [9]张友强,梁勇芳.聚丙烯成核剂的研究与发展[J].工程塑料应用,2010, 38(2):85-88.
- [10]张国辉,王雷,王丽.不同晶型成核剂在聚丙烯改性中的应用[J].塑料制造, 2009(3):49-52.
- [11] SCOTT G. Mechanisms of polymer degradation and stabilization[J].Elsevier Applied Science, 1990, 50(12):2039-2045.
- [12]周郭煌. UV吸收剂对聚合物光稳定作用的稀土配位化学改性研究[D].广州:广东工业大学, 2005.
- [13]赵芳萍.滑石粉及抗氧化剂对PP材料老化性能的影响研究[J].广州:广州化学, 2015, 40(2):12-16.
- [14]马立群,孙兆洋,何子健,等.纳米TiO2表面接枝PAN及其对PP抗紫外老化性能的影响[J].工程塑料应用, 2014, 42(6):69-73.
- [15]王全华,付中玉,朱金唐.紫外光对聚丙烯纤维结构和拉伸强度的影响[J].北京服装学院学报, 2006(1):12-19.
- [16]徐立新,蒋东升,费正东,等. PMA表面接枝包覆纳米TiO2及其在PP中抗紫外老化的研究[J].塑料工业, 2007(1):45-48.
- [17] TURTON T, WHITE R. Effect of stabilizer and pigment on photo degradation depthprofiles in polypropylene[J]. Polymer Degtadation and Stability, 2001, 74:559-568.
- [18]孙梦捷,王国雨,王永香,等.无规共聚聚丙烯DSC原位加速老化研究[J].塑料工业, 2019, 47(8):97-100.
- [19] HATANAKA T. Study of thermo-oxidative degradation of molten state polypropylene with a variety of tacticities[J]. Polym Degrad Stabil,1999, 64(2):313-319.
- [20]朱梦玲,李素英,顾鹏斐,等.改性纳米SiO2对聚丙烯抗老化性能影响的研究[J].纺织科技进展, 2019(1):7-9.