静电纺制备PVDF基锂离子电池隔膜的研究进展Research Progress on Electrospinning PVDF-Based Lithium Ion Battery Separators
王晨,贺辛亥,郭志昂,宋一帆
WANG Chen,HE Xin-hai,GUO Zhi-ang,SONG Yi-fan
摘要(Abstract):
以聚偏氟乙烯(PVDF)为基体,通过静电纺丝法制备的电池用纳米纤维隔膜存在力学性能较低、热稳定性较差等缺点,解决这一问题的主要方法是对纤维膜进行改性。简述了共混、涂覆、热处理等改性研究现状,分析了不同改性方法对纤维隔膜整体性能的影响,总结并讨论了各种改性方法的优缺点,为静电纺PVDF基锂离子电池隔膜的研究和应用提供技术和理论支持。
The electrospun polyvinylidene fluoride(PVDF) based nanofiber membranes for lithium ion battery still have many shortcomings of poor mechanical properties and thermal stability. The main method to solve these problems is to modify the structure of nanofiber membrane. In this paper, the current research status in terms of blending, coating, heat treatment of PVDF nanofiber were described briefly. The effects of different modification methods on the overall performance of PVDF nanofiber membranes were analyzed.Moreover, the advantages and disadvantages of these methods were summarized and discussed. The technical and theoretical support for the research and application of electrospinning PVDF-based lithium ion battery separators were presented.
关键词(KeyWords):
聚偏氟乙烯;静电纺丝;电池隔膜;力学性能
polyvinylidene fluoride;electrospinning;battery separator;machanical property
基金项目(Foundation): 中国纺织工业联合会科技指导性项目(No.2018014)
作者(Author):
王晨,贺辛亥,郭志昂,宋一帆
WANG Chen,HE Xin-hai,GUO Zhi-ang,SONG Yi-fan
DOI: 10.16090/j.cnki.hcxw.2020.01.008
参考文献(References):
- [1]HUANG Z M,ZHANG Y Z,KOTAKI M,et al.A review on polymer nanofibers by electrospinning and their applications in nanocomposites[J].Composites Science and Technology,2003,63(15):2223-2253.
- [2]CHOI S W,JO S M,LEE W S,et al.An electrospun poly(vinylidene fluoride)nanofibrous membrane and its battery applications[J].Advanced Materials,2003,15(23):2027-2032.
- [3]盛晓颖.锂离子电池用聚偏氟乙烯的改性及性能研究[D].太原:中北大学,2011.
- [4]黄友桥,管道安.锂离子电池隔膜材料的研究进展[J].船电技术,2011,31(1):26-29.
- [5]胡继文,许凯,沈家瑞.锂离子电池隔膜的研究与开发[J].高分子材料科学与工程,2003(1):215-219.
- [6]WANG L Y,DENG N P,JU J G,et al.A novel core-shell structured poly-m-phenyleneisophthalamide@polyvinylidene fluoride nanofiber membrane for lithium ion batteries with high-safety and stable electrochemical performance[J].Electrochimica Acta,2019,300:263-273.
- [7]TAYLOR Geoffrey.Disintegration of water drops in an electric field[J].Proceedings of the Royal Society of London.Series A,1964,280(1382):383-397.
- [8]黄友桥,管道安.锂离子电池隔膜材料的研究进展[J].船电技术,2011,31(1):26-29.
- [9]肖文军,伍伯林,谭松庭.电纺聚合物纳米纤维研究进展[J].材料导报,2007(2):102-105.
- [10]胥会,陈建,代文超,等.静电纺丝制备PMMA/PVDF锂离子电池隔膜[J].化工新型材料,2016,44(10):64-66,69.
- [11]ZHANG F,MA X L,CAO C B,et al.Poly(vinylidene fluoride)/SiO2composite membranes prepared by electrospinning and their excellent properties for nonwoven separators for lithium-ion batteries[J].Journal of Power Sources,2014,251:423-431.
- [12]房长江.静电纺聚偏氟乙烯锂离子电池隔膜的无机改性研究[D].杭州:浙江理工大学,2016.
- [13]韩领,陆春,陈平,等.原位生成二氧化钛对静电纺聚偏氟乙烯锂离子电池隔膜力学性能及电化学性能的影响[J].高分子学报,2012(11):1319-1325.
- [14]李琳,陈建,龚勇,等.TiO2改性PVDF锂离子电池隔膜的研究[J].化工新型材料,2018,46(12):133-136.
- [15]胥会.静电纺丝制备勃姆石改性PVDF/PMMA锂电池隔膜的研究[D].自贡:四川理工学院,2016.
- [16]ZHONG Z,CAO Q,JING B,et al.Electrospun PVDF-PVC nanofibrous polymer electrolytes for polymer lithium-ion batteries[J].Materials Science and Engineering:B,2012,177(1):86-91.
- [17]TUSIIMIRE Y,ZHANG C Y,ZHANG C H,et al.Properties of electrospun PVDF/PMMA/CA membrane as lithium based battery separator[J].Cellulose,2014,21(4):2811-2818.
- [18]MONALI V B,SUBHASH B K.Electrospun poly(vinylidene fluoride)/cellulose acetate/AgTiO2nanofibers polymer electrolyte membrane for lithium ion battery[J].Solid State Ionics,2019,333:38-44.
- [19]刘京强.电纺PVDF/PEI复合纤维薄膜的制备与性能研究[D].哈尔滨:哈尔滨理工大学,2016.
- [20]CHEN H L,JIAO X N.Preparation and characterization of polyvinylidene fluoride/octaphenyl-polyhedral oligomeric silsesquioxane hybrid lithium-ion battery separators by electrospinning[J].Solid State Ionics,2017,310:134-142.
- [21]ZHU Y,YIN M,LIU H S,et al.Modification and characterization of electrospun poly(vinylidene fluoride)/poly(acrylonitrile)blend separator membranes[J].Composites Part B,2017,112:31-37.
- [22]WU D Z,DENG L,SUN Y,et al.A high-safety PVDF/Al2O3composite separator for Li-ion batteries via tip-induced electrospinning and dipcoating[J].Rsc Advances,2017,7(39):24410-24416.
- [23]孟庆朋.聚偏氟乙烯基锂离子电池隔膜的改性及其性能研究[D].黑龙江:哈尔滨理工大学,2019.
- [24]CAO C Y,TAN L,LIU W W,et al.Polydopamine coated electrospun poly(vinyldiene fluoride)nanofibrous membrane as separator for lithiumion batteries[J].Journal of Power Sources,2014,248:224-229.
- [25]辜其隆,陈建,龚勇,等.热处理工艺对静电纺丝制备PVDF/PM-MA复合膜的力学性能的影响[J].功能高分子学报,2019,32(2):225-232.
- [26]漆东岳,刘延波,马营,等.PAN-PVDF复合增强静电纺锂离子电池隔膜[J].电源技术,2014,38(12):2231-2234,2238.
- [27]龚勇,代祖洋,辜其隆,等.热压改性电纺聚偏氟乙烯隔膜研究[J].化工新型材料,2018,46(4):87-89,93.
- [28]LIANG Y,CHENG S,ZHAO J,et al.Heat treatment of electrospun Polyvinylidene fluoride fibrous membrane separators for rechargeable lithium-ion batteries[J].Journal of Power Sources,2013,240:204-211.
- [29]杨广斌.PPEK与PVDF复合膜作为锂离子电池隔膜的研究[D].大连:大连理工大学,2017.
- [30]程司辰.基于静电纺丝法的PVDF基锂离子[D].上海:东华大学,2013.
- [31]LIN Y S,ROSAIAH Pitcheri,ZHU J H,et al.Electrospun PVDF/PSSLi ionomer films as a functional separator for lithium-sulfur batteries[J].Journal of Alloys and Compounds,2019,785:627-633.
- [32]潘教龙.多功能聚合物薄膜的制备及其用作锂离子电池隔膜的研究[D].南昌:南昌大学,2018.
- [33]WANG Shuo,ZHANG D L,SHAO Z Q,et al.Cellulosic materialsenhanced sandwich structure-like separator via electrospinning towards safer lithium-ion battery[J].Carbohydrate Polymers,2019,214:328-336.
- [34]WU D Z,SHI C,HUANG S H,et al.Electrospun nanofibers for sandwiched polyimide/ppoly(vinylidene fluoride)/polyimide separators with the thermal shutdown function[J].Electrochimica Acta,2015,176:727-734.
- [35]姜红娟,张燕青,吴大勇,等.高性能锂离子电池隔膜的结构设计及其制备与表征[J].高分子学报,2015(11):1271-1279.
- [36]吴小娟,余妙晶,舒慧,等.过温保护层合纳米纤维隔膜的制备及其性能[J].纺织学报,2018,39(7):21-26.
- [37]周锦涛.纳米SiO2颗粒添加改性PVDF/PMMA静电纺丝锂离子电池隔膜的制备与性能研究[D].天津:天津工业大学,2017.
- [38]刘太奇,马福瑞,赵云腾.溶液聚偏氟乙烯静电纺纤维基超高分子量聚乙烯锂电池隔膜的制备[J].高分子材料科学与工程,2015,31(10):128-132.
- [39]GONG W Z,WEI S Y,RUAN S L,et al.Electrospun coaxial PPESK/PVDF fibrous membranes with thermal shutdown property used for lithium-ion batteries[J].Materials Letters,2019,244:126-129.
- [40]崔巍巍,孟庆朋,王振宇,等.大倍率高耐热聚醚酰亚胺-聚偏氟乙烯芯壳纳米纤维锂离子电池隔膜[J].复合材料学报,2019,36(1):69-76.
- [41]龚文正,周晶晶,阮诗伦,等.静电纺丝与静电喷雾技术共纺制备PPESK/PVDF复合锂电池隔膜[J].材料工程,2018,46(3):1-6.
- [42]宁景霞.β-PVDF复合纤维隔膜的结构控制与性能研究[D].无锡:江南大学,2018.