王浩旭,王晓晶,罗晓亮,胡振峰
WANG Hao-xu,WANG Xiao-jing,LUO Xiao-liang,HU Zhen-feng

• 1:军事科学院国防科技创新研究院

摘要(Abstract)：

超高分子质量聚乙烯(UHMWPE)纤维具有强度高、模量高、密度低、耐腐蚀等优点，适用于多种武器装备，在两栖登陆装备中应用更为广泛，但由于UHMWPE纤维与树脂基体结合性较差，严重影响了UHMWPE纤维增强复合材料的应用与发展。总结了近几年UHMWPE纤维改性技术研究进展，从物理改性技术、化学改性技术和物理化学改性技术等方面进行归纳分析，并对UHMWPE纤维改性技术发展趋势进行了展望。
Ultra high molecular weight polyethylene(UHMWPE) fiber has the advantages of high strength,high modulus, low density and corrosion resistance. It is suitable for a variety of weapons equipment, and is more widely used in amphibious landing equipment. However, due to the adhesion between UHMWPE fiber and resin matrix is poor, which seriously affects the application and development of UHMWPE fiber reinforced composites. The research progress of modification technology of UHMWPE fiber in recent years is summarized and analyzed from the aspects of physical modification technology, chemical modification technology and physical-chemical modification technology, and the development trend of modification technology is prospected.

关键词(KeyWords)： UHMWPE纤维;表面改性;纤维增强复合材料;黏结强度
UHMWPE fiber;surface modification;fiber reinforced composites;bond strength

Abstract:

Keywords:

基金项目(Foundation): 国家重点研发计划项目(2018YFC1902403)

作者(Author): 王浩旭,王晓晶,罗晓亮,胡振峰
WANG Hao-xu,WANG Xiao-jing,LUO Xiao-liang,HU Zhen-feng

DOI: 10.16090/j.cnki.hcxw.2022.12.001

参考文献(References)：

• [1] GOLOVIN K, PHOENIX S L. Effects of extreme transverse deformation on the strength of UHMWPE single filaments for ballistic applications[J]. Journal of Materials Science, 2016, 51(17):8075-8086.
• [2] CHHETRI S, BOUGHERARA H. A comprehensive review on surface modification of UHMWPE fiber and interfacial properties[J]. Composites Part A:Applied Science and Manufacturing, 2021, 140:106146.
• [3] LIU R, WANG X, YU J, et al. Surface modification of UHMWPE/fabric composite membrane via self-polymerized polydopamine followed by mPEG-NH2immobilization[J]. Journal of Applied Polymer Science, 2018,135(26):46428.
• [4]莫根林,刘静,金永喜,等.超高分子量聚乙烯纤维防护机理研究综述[J].兵器装备工程学报, 2021, 42(10):23-28.
• [5] AAWA A, TD B, HENAB C. Fiber tortuosity and its effects on shock transfer characteristics of ultra high molecular weight polyethylene(UHMWPE)fibers embedded in a polyurethane composite structure[J]. Composites Science and Technology, 2020, 192:108112.
• [6] HAN L, CAI H, CHEN X, et al. Study of UHMWPE fiber surface modification and the properties of UHMWPE/epoxy composite[J]. Polymers,2020, 12(3):521.
• [7]李露露,韩立新,王爽芳,等.超高分子量聚乙烯纤维表面改性及其界面性能研究进展[J].功能材料, 2022, 53(4):4088-4096.
• [8]苗润,王伟力,吴世永,等.小型舰艇复合防护结构加筋板抗侵彻能力分析[J].兵器装备工程学报, 2018, 39(10):1-5.
• [9] LI C, SHI Y, ZHANG R, et al. Effect of surface modifications on the properties of UHMWPE fibres and their composites[J]. e-Polymers, 2019,19(1):40-49.
• [10] FENG M, LI W W, LIU X J, et al. Copper-polydopamine composite coating decorating UHMWPE fibers for enhancing the strength and toughness of rigid polyurethane composites[J]. Polymer Testing, 2021, 93:106883.
• [11]尚晴,赵晗,赵宁,等.超高分子量聚乙烯纤维表面改性的研究进展[J].高分子通报, 2020(4):22-29.
• [12]王浩旭,杜建华,李辉,等.超高分子质量聚乙烯纤维黏结强度增强方法研究[J].合成纤维, 2019, 48(6):27-30.
• [13] OGAWA T, MUKAI H, OSAWA S. Improvement of the mechanical properties of an ultrahigh molecular weight polyethylene fiber/epoxy composite by corona-discharge treatment[J]. Journal of Applied Polymer Science, 2001, 79(7):1162-1168.
• [14]李瑞培,李微微,孟立,等.超高分子量聚乙烯纤维的液相氧化改性及其环氧树脂基复合材料的力学和摩擦性能[J].材料导报, 2016,30(4):41-46.
• [15] FIROUZI D, RIZVI S N, CHING C Y, et al. Development of oxygenplasma-surface-treated UHMWPE fabric coated with a mixture of sic/polyurethane for protection against puncture and needle threats[J]. Fibers,2019, 7(5):46.
• [16] BELGACEMI R, DERRADJI M, TRACHE D, et al. Toward an efficient stress transfer with a fully connected hybrid network from epoxy, oxidized UHMWPE fibers, and silane surface modified silicon carbide nanoparticles[J]. Polymer Composites, 2021, 42:462-473.
• [17] HOLLOWAY J L, LOWMAN A M, VANLANDINGHAM M R, et al.Chemical grafting for improved interfacial shear strength in UHMWPE/PVA-hydrogel fiber-based composites used as soft fibrous tissue replacements[J]. Composites Science&Technology, 2013, 85:118-125.
• [18] WEN Y, LI R X, CAI F, et al. Influence of ethylene glycol pretreatment on effectiveness of atmospheric pressure plasma treatment of polyethylene fibers[J]. Applied Surface Science, 2009, 256(10):3253-3258.
• [19] DOMINGUEZ-LOPEZI,DOMíNGUEZ-DíAZBM,GARCíA-GARCíA A L, et al. Effect of atmospheric plasma treatment on the wettability of UHMWPE[J]. Materials Letters, 2021, 285.
• [20] BAHRAMIAN N, ATAI M, NAIMI-JAMAL M R. Ultra-high-molecular-weight polyethylene fiber reinforced dental composites:effect of fiber surface treatment on mechanical properties of the composites[J]. Dental Materials, 2015, 31(9):1022-1029.
• [21]李焱,李常胜,黄献聪.电晕处理对UHMWPE纤维的性能影响[J].合成纤维工业, 2010, 33(3):36-38.
• [22] BAHRAMIAN N, ATAI M, NAIMI-JAMAL M R. Ultra-high-molecular-weight polyethylene fiber reinforced dental composites:effect of fiber surface treatment on mechanical properties of the composites[J]. Dental Materials, 2015, 31(9):1022-1029.
• [23] DAYYOUB T, MAKSIMKIN A V, SENATOV F S, et al. Treating UHMWPE surface for enhancing the adhesion properties by cellulose grafting[J]. International Journal of Adhesion and Adhesives, 2020, 98(C):102535.
• [24]魏寒,邢哲,王谋华,等.超高分子量聚乙烯纤维预辐照接枝丙烯酸甲酯[J].辐射研究与辐射工艺学报, 2012, 30(6):328-332.
• [25] WANG L, GAO S, WANG J, et al. Surface modification of UHMWPE fibers by ozone treatment and UV grafting for adhesion improvement[J].The Journal of Adhesion, 2018, 94(1):30-45.
• [26]黄鑫,王恩召,张天骄,等.紫外辐照交联改性UHMWPE纤维的研究[J].合成纤维工业, 2011, 34(2):23-26.
• [27] LI W W, MENG L, WANG L, et al. Surface modification of ultrahigh molecular weight polyethylene fibers by chromic acid.[J]. Surface and Interface Analysis, 2016, 48(12):1316-1319.
• [28]向媛.简单化学表面处理增强超高相对分子质量聚乙烯-环氧树脂粘接性能[J].化学与粘合, 2009, 31(1):66-69.
• [29]贺建强,于俊荣,张秀雨,等.铬酸氧化法改善超高分子量聚乙烯纤维表面粘接性能[J].高分子材料科学与工程, 2014, 30(5):57-61.
• [30] KALTEH H G, REZAEI M, ABBASI F, et al. Radiation-induced graft copolymerization of MMA monomer onto UHMWPE:Adhesion improvement[J]. Journal of Applied Polymer Science, 2010, 108(2):1086-1092.
• [31] BOER J D, BERG H, PENNINGS A J. Crosslinking of ultra-high molecular weight polyethylene in the oriented state with dicumylperoxide[J].Polymer(Guildf), 1984, 25(4):513-519.
• [32]张一,于俊荣,黄献聪,等.偶联剂改性UHMWPE纤维表面性能的研究[J].合成纤维工业, 2009, 32(1):1-3, 7.
• [33]边丽娜,肖长发,金欣. PPy-UHMWPE纤维结构与性能的研究[J].纺织学报, 2011, 32(3):1-4, 24.
• [34] TIAN Y Y, GUO L M. Adhesion performance of UHMWPE fiber treated with polyethylene wax grafted methyl methacrylate alone or in conjunction with silane coupling agent[J]. Journal of Adhesion Science and Technology, 2021, 35(11):1219-1235.
• [35] WANG S C, MA J Y, FENG X, et al. An effective surface modification of UHMWPE fiber for improving the interfacial adhesion of epoxy resin composites[J]. Polymer Composites, 2020, 41(4):1614-1623.
• [36] SA R, WEI Z H, YAN Y, et al. Catechol and epoxy functionalized ultrahigh molecular weight polyethylene(UHMWPE)fibers with improved surface activity and interfacial adhesion[J]. Composites Science&Technology, 2015, 113(5):54-62.
• [37]赵晗,尚晴,杨萌,等. ZnO纳米棒改性超高分子量聚乙烯纤维及其性能研究[J].高分子学报, 2020, 51(6):649-655.
• [38] REN Y, DING Z R, WANG C X, et al. Influence of DBD plasma pretreatment on the deposition of chitosan onto UHMWPE fiber surfaces for improvement of adhesion and dyeing properties[J]. Applied Surface Science, 2017, 396:1571-1579.
• [39] ZHU M, REN H, LU Q, et al. An in situ surface modification method of ultra-high molecular weight polyethylene fiber on the basis of dry gelspinning technique[J]. Polymer Testing, 2020:106951.
• [40]代栋梁,施楣梧.超临界CO2预处理对UHMWPE纤维电子束辐照效果的影响[J].合成纤维, 2016, 45(6):31-37.