小麦蛋白/聚乙烯醇复合纳米纤维的制备及其表征Preparation and Characterization of Wheat Protein/PVA Blend Composite Nanofiber
潘丽军,张黎黎,姜绍通,王华林
PAN Li-jun1,ZHANG Li-li1,JIANG Shao-tong1,WANG Hua-lin2(1.School of Biotechnology and Food Engineering
摘要(Abstract):
以小麦蛋白、聚乙烯醇(PVA)为原料,采用静电纺丝法制备小麦蛋白/PVA共混复合纳米纤维,重点研究纺丝液质量分数、电压、接收距离对纤维形态的影响,利用扫描电镜、傅里叶变换红外光谱、X-射线衍射光谱对纤维的形态与结构进行表征。结果表明:在纺丝液质量分数10%、小麦蛋白与PVA质量比8∶2、电压12 kV、接收距离10 cm的条件下,可以制备平均直径为280 nm左右的均一、表面光滑的纳米纤维。小麦蛋白与PVA复合后,分子间以氢键结合。
Wheat protein/PVA composite nanofiber was prepared via electrospining technique.The effects of total concentration of the solution,voltages,tip to collector distance and structure of the nanofibers were investigated by scanning electron microscopy(SEM),fourier transform infratred(FT-IR) and X-ray diffraction(XRD).The results indicated that the uniform and smooth wheat protein/PVA composite nanofiber with average diameter of 280 nm could be prepared with following optimal process parameters: total concentration of the solution 10 %,weight ratio of wheat protein to PVA 8∶2,applied voltage 12 kV,and the tip-to-collector distance 10 cm.There were hydrogen bonds between wheat protein and PVA in the composite nanofibers.
关键词(KeyWords):
静电纺丝;聚乙烯醇;纳米纤维;表征
electrospining,PVA,nanofiber,characterization
基金项目(Foundation): 国家自然科学基金项目(31171788)
作者(Author):
潘丽军,张黎黎,姜绍通,王华林
PAN Li-jun1,ZHANG Li-li1,JIANG Shao-tong1,WANG Hua-lin2(1.School of Biotechnology and Food Engineering
DOI: 10.16090/j.cnki.hcxw.2012.04.016
参考文献(References):
- [1]顾卓,冯惠,王建军,等.丝素-聚乙烯醇共混溶液静电纺丝及其含银纳米纤维形态研究[J].合成技术及应用,2008,23(1):11-13.
- [2]秦步祥,徐步荣,成中平.大豆蛋白/聚乙烯醇纤维的性能与开发[J].中国纤检,2006,(9):33-34.
- [3]李梦琴,张剑,任红涛,等.小麦面筋蛋白可食性复合膜的改性研究[J].食品科学,2006,27(12):175-178.
- [4]王金水,赵谋明,杨晓泉.酶解产物对小麦面筋蛋白酶水解过程抑制作用的研究[J].河南工业大学学报(自然科学版),2005,26(4):5-8.
- [5]司学芝,李建伟.麦醇溶蛋白和麦谷蛋白提取条件的研究,郑州工程学院学报[J].2004,25(3):33-35,39.
- [6]Kenawy E,Layman J M,Watkinsa J R,et al.Electrospinning of poly(ethylene,covinyl alcohol)fibers[J].Biomaterials.2003,24(6):907-913.
- [7]李珍,王军.静电纺丝可纺性影响因素的研究成果[J].合成纤维,2008,37(9):6-10.
- [8]Zong X H.Kim K S.Fang D F.Structure and process relationship ofelectrospun bioabsorbable nanofiber membranes[J].Polymer,2002,43:4 403-4 412.
- [9]Deitzel J M,Kleinmeyer J,Harris D,et al.The effect of processingvariables on the morphology of electrospun nanofibers and texiles[J].Polymer,2001,42:261-272.
- [10]Krishnappa R V N,Desai K,Sung C M.Morphological study ofelectrospun polycarbonates as a function of the solvent and processingvoltage[J].Material.Science,2003,38:2 357-2 365.
- [11]常丽娜,张幼珠,张晓东.静电纺丝工艺参数对丝素/壳聚糖纳米纤维的形貌及直径的影响[J].合成纤维,2006,35(2):14-17.
- [12]高亚宁.从X-射线衍射谱图分析研究聚乙烯醇纤维的微观结构[J].合成纤维,2011,40(4):27-29.
- [13]白露,张力平,展娜,等.微纳纤维素晶体改性聚乙烯醇膜材料的研究[J].现代化工,2009,29(2):163-166.
- [14]王守文,陈孝康.聚乙烯醇辐射损伤的红外光谱研究[J].化学研究与应用,1999,11(4):374-377.