一种新型高强度大伸长涤纶工业丝的制备Preparation for a New Industrial Polyester Yarn with High Strength and Large Elongation
王新东,孙永明,庄源,马鹏程,葛骏敏,姚玉元
WANG Xin-dong,SUN Yong-ming,ZHUANG Yuan,MA Peng-cheng,GE Jun-min,YAO Yu-yuan
摘要(Abstract):
以普通聚酯切片为原料,利用固相聚合装置对其干燥增黏,制得低含水率、高黏度聚酯切片,再经熔融纺丝制备出一种新型高强度、大伸长涤纶工业丝。采用X射线衍射仪、差示扫描量热仪对其进行了表征,并利用纤维强伸仪测试了纤维的力学性能。结果表明:固相聚合后的切片结晶度高达60%以上,含水率可达0.000 5%以下,特性黏度为1.105 d L/g。以此增黏切片为原料,可生产出纤度为472 dtex,断裂强度≥7.15 c N/dtex,断裂伸长率为23.7%的纤维。由于该产品具有强度高、伸长率大和毛丝数量少的特点,已在水处理的超滤膜支撑材料领域得到了应用。
Using the normal polyester chips as materials, the high viscosity polyester chips are prepared bySSP device, then the chips are melt-spun to prepare a new industrial polyester yarn with high strength andlarge elongation. The performance of chips are analyzed by X-ray diffraction, differential scanning calorime-try. The yarn's properties are analyzed by fiber strength measurement. The results show that the crystallineof chips increases to more than 60% after the solid phase polymerization, moisture content decreases to lessthan 0.000 5%, intrinsic viscosity is 1.105 d L/g. Using high viscosity polyester chips as material, the fine-ness of the product is 472 dtex, intensity is ≥7.0 c N/dtex, breaking elongation ratio is 23.7%. Because theproducts have high strength, large elongation and less fuzz, they have been used as ultrafiltration membranesupport materials in water treatment area.
关键词(KeyWords):
涤纶工业丝;高强度;大伸长
industrial polyester yarn;high strength;large elongation
基金项目(Foundation): 浙江省重大科技专项(2013C01013)
作者(Author):
王新东,孙永明,庄源,马鹏程,葛骏敏,姚玉元
WANG Xin-dong,SUN Yong-ming,ZHUANG Yuan,MA Peng-cheng,GE Jun-min,YAO Yu-yuan
DOI: 10.16090/j.cnki.hcxw.2016.01.004
参考文献(References):
- [1]范胤祯.工业水处理中膜分离技术的应用研究[J].化工管理,2014(4):84.
- [2]雷晓东,熊蓉春,魏刚,等.膜分离法污水处理技术[J].工业水处理,2003,1(1):38-42.
- [3]孙立坤.PVA/PVAm改性涤纶滤布复合膜制备及其抗污染性能研究[D].大连:大连理工大学,2012:3-4.
- [4]周东凯.新型纤维挂膜填料污水处理研究[D].北京:北京化工大学,2013:20-23.
- [5]赵阳.涤纶长丝基布结构对PVC涂层膜结构材料性能影响的研究[D].天津:天津工业大学,2009:4-6.
- [6]高国洪,江秀明,庾培源,等.一步法生产涤-涤复合丝条干不匀率的优化[J].合成纤维,2014,43(11):14-16.
- [7]朱湘萍,于维才,孙彦洁,等.高强型涤纶工业用全拉伸丝的工艺及设备[J].合成纤维,2013,42(1):38-42.
- [8]张军.高分了量PET合成与SSP工艺优化研究[D].杭州:浙江大学,2011:106-109.
- [9]崔利,庄耀中,姚敏刚,等.267 dtex/288 f竹炭涤纶预取向丝的生产[J].合成纤维,2015,44(6):19-21.