BaSO_4对BaSO_4/PVA共混纤维结构与性能影响的研究Influence of BaSO_4 Content on the Structure and Properties of BaSO_4/poly (vinyl alcohol) Blend Fibers
高进,何唯平,张杰,王志鑫,王依民
GAO Jin1, HE Wei-ping2, ZHANG Jie2, WANG Zhi-xin2, WANG Yi-min3 (1. College of Material Science and Engineering
摘要(Abstract)：
通过冻胶纺丝的方法制得了屏蔽剂BaSO4含量达70%的屏蔽X-射线纤维,讨论了BaSO4含量对共混纤维的力学性能、结晶性能的影响。研究表明,随屏蔽剂BaSO4含量的增加,共混纤维的各项力学性能指标均变差,纤维的结晶度、结晶温度均随之发生变化。
BaSO4/poly (vinyl alcohol)(PVA) blend fibers were prepared by gel spinning process, and the maximum BaSO4 content was up to 70 %. The influences of BaSO4 content on the mechanical properties, thermal property and crystallization behavior were investigated. The mechanical properties of the fibers were decreased with the increase of the BaSO4 content. The crystal property was also varied with different BaSO4/PVA ratios.
关键词(KeyWords)：
BaSO4;PVA;共混纤维
BaSO4, PVA, blend fiber
基金项目(Foundation): 上海市重点学科建设项目(编号B603)
作者(Author):
高进,何唯平,张杰,王志鑫,王依民
GAO Jin1, HE Wei-ping2, ZHANG Jie2, WANG Zhi-xin2, WANG Yi-min3 (1. College of Material Science and Engineering
参考文献(References)：
- [1]齐鲁,段谨源,王学晨等.防X射线纤维的力学性能及屏蔽效果[J].纺织学报,1995,16[2]:87-90.
- [2]Rainer Friedrich,Daniel Riester,Peter Gottig.Structure of a novel thrombin inhibitor with an unchanged D-amino acid as P1residue[J].European Journal of Medicinal Chemistry,2008,43[6]:1330-1335.
- [3]K J Singh,N Singh,R S Kaundal.Gamma-ray shielding and structural properties of PbO-SiO2glasses[J].Nuclear Instruments and Methods in Physics Research,2008,266[6]:944-948.
- [4]S S Amritphale,Avneesh Anshul.Development of celsian ceramics from fly ash useful for X-ray,radiation-shielding application[J].Journal of the European Ceramic Society.2007,27[16]:4639-4647.
- [5]Ozlem Yayuz,Mannoj K Ram,Matt Aldissi.Polypyrrole composites for shielding applications[J].Synthetic Metals,2005,151[3]:211-217.
- [6]张跃飞,辛忠.去氢枞酸类成核剂改性聚丙烯的非等温结晶动力学研究[J].功能高分子学报,2003,16[4]:431-434.