纺丝工艺对T700级碳纤维及其复合材料性能的影响Effect of Spinning Process on the Properties of T700 Carbon Fibers and Its Reinforced Composites
徐牛牛,杭传伟,张淑斌,彭飞
XU Niu-niu,HANG Chuan-wei,ZHANG Shu-bin,PENG Fei
摘要(Abstract):
采用同种上浆剂对不同纺丝工艺国产T700级碳纤维进行上浆,测试分析了不同纺丝工艺碳纤维的表观性能、接触角、展纱性、毛丝量及硬挺度,并对两种纺丝工艺碳纤维制备的复合材料的力学性能进行了测试分析。结果表明:干喷湿纺碳纤维的表面光滑,截面形状基本为圆形,湿纺碳纤维的表面有沟槽,截面形状大部分为近圆形或椭圆形,少量为腰形;干喷湿纺碳纤维在耐磨性、集束性和硬挺度方面均优于湿纺碳纤维,而湿纺碳纤维的展纱性及浸润性优于干喷湿纺碳纤维;干喷湿纺碳纤维制备的复合材料的层间剪切强度比湿纺碳纤维的高12%,干喷湿纺碳纤维制备的NOL环的拉伸强度及强度转化率也高于湿纺碳纤维的。
Domestic T700 carbon fibers made of different spinning processes were sized using the same sizing agent. The apparent properties, contact angle, splitting rate, fuzz content and stiffness of the carbon fibers of different spinning processes were tested and analyzed. The mechanical properties of the composite materials prepared by the carbon fibers of two spinning processes were also tested and analyzed. The results show that the surface of the carbon fibers of dry jet wet spinning process is smooth and the cross-section shape is basically circular, while the surface of the carbon fibers of wet spinning process has grooves, and the section shape is mostly nearly round or oval, and a little is waist shape. The carbon fibers of dry jet wet spinning process is superior to the carbon fibers of wet spinning process in wear resistance, bunching and stiffness, while the carbon fibers of wet spinning process is superior to the carbon fibers of dry jet wet spinning process in splitting rate and wetting property. The interlaminar shear strength of the composites prepared by the carbon fibers of dry jet wet spinning process is 12% higher than that of the carbon fibers of wet spinning process. The tensile strength and strength conversion rate of the NOL rings prepared by carbon fibers of dry jet wet spinning process are also higher than that of the carbon fibers of wet spinning process.
关键词(KeyWords):
国产T700碳纤维;纺丝工艺;复合材料;性能
domestic T700 carbon fibers;spinning process;composites;performance
基金项目(Foundation):
作者(Author):
徐牛牛,杭传伟,张淑斌,彭飞
XU Niu-niu,HANG Chuan-wei,ZHANG Shu-bin,PENG Fei
DOI: 10.16090/j.cnki.hcxw.2023.05.005
参考文献(References):
- [1] WANG C G, DONG X G, WANG Q F. Effect of coagulation on the structure and property of PAN nascent fibers during dry jet wet spinning[J]. Journal of Polymer Research, 2009, 16(6):719-724.
- [2]贺福.碳纤维及石墨纤维[M].北京:化学工业出版社. 2010.
- [3] LI J J, YU Y X, LI H J, et al. Polyacrylonitrile based on carbon fibers:spinning technology dependent precursor fiber structure and its successive transformation[J]. Journal of Applied Polymer Science, 2021, 138(38):50988.
- [4]卢杰,周姬娜,李炜,等.湿纺与干喷湿纺碳纤维的性能分析[C]//第二十一届全国玻璃钢/复合材料学术年会. 2016:34-38, 70.
- [5]惠雪梅,侯晓,崔红,等.国产T800S级碳纤维表面结构和耐磨性研究[J].固体火箭技术, 2021, 44(4):513-519.
- [6] JING M, TAN T,WANG C, et al. Comparison on the micro-structure of Toray T800H and T800S carbon fiber[J]. Materials Science and Technology, 2015, 23(2):45-52.
- [7]张世杰,王汝敏,廖英强.不同纺丝工艺T800炭纤维及其缠绕压力容器性能差异性研究[J].新型炭材料, 2019, 34(6):578-586.
- [8]程勇,侯晓,张世杰,等.纺丝工艺对炭纤维缠绕复合材料强度转化率的影响[J].固体火箭技术, 2017, 40(2):239-243.
- [9]张世杰,王汝敏,刘宁,等.纺丝工艺对T800碳纤维及其复合材料性能的影响[J].材料工程, 2019, 47(8):118-124.
- [10]张世杰,王汝敏,刘宁,等.两种纺丝工艺T800级炭纤维复合材料容器性能对比[J].固体火箭技术, 2019, 42(2):239-244.
- [11]杭传伟,钱鸿川,徐牛牛,等.上浆剂组分对碳纤维表观性能的影响研究[J].玻璃钢/复合材料, 2019(7):60-64.
- [12]吴佩云,黄靖昱.几种新型纤维束摩擦性能探讨[C]//2008年全国现代纺纱技术研讨会. 2008:228-237.
- [13]崔峙.国产碳纤维表面结构与复合材料性能转化率关系研究[D].北京:北京化工大学, 2020.
- [14]欧阳新峰,王芬,孙玉婷,等.国内外主要碳纤维品种综合性能表征[J].高科技纤维与应用, 2018, 43(5):48-57.
- [15]沈丹.基于摩擦性能与弯曲性能的织物手感客观检测研究[D].天津:天津工业大学, 2008.
- [16] CHEN W M, YU Y H, LI P, et al. Effect of new epoxy matrix for T800 carbon fiber/epoxy filament wound composites[J]. Composites Science and Technology, 2007, 67(11):2261-2270.
- [17]林松,张琳,高志琪,等.国产T700炭纤维复合材料发动机壳体强度设计及成型工艺[J].固体火箭技术, 2018, 41(5):614-620.
- [18]石佩洛,尚呈元,陈亮,等.碳纤维截面特性对碳纤维/环氧树脂复合材料压缩强度的影响[J].复合材料学报, 2021, 38(12):4052-4059.