芳纶表面改性技术进展(三)——表面改性分析表征方法Progress in Surface Modification of Aramid Fiber(Ⅲ)——Analysis and Characterization of Surface Modification
刘克杰,杨文良,彭涛,王凤德
LIU Ke-jie,YANG Wen-liang,PENG Tao,WANG Feng-de(High Performance Fiber Section
摘要(Abstract):
对芳纶表面改性的分析表征方法进行了概述。主要介绍了傅里叶变换红外光谱(FTIR)、拉曼光谱(Raman)、X-射线光电子能谱(XPS)、扫描电子显微镜(SEM)、原子力显微镜(AFM)5种定性分析方法,以及测量比表面积、接触角、浸润速率、界面剪切强度(IFSS)、层间剪切强度(ILSS)、浸胶丝强度等6种定量分析方法。同时介绍了复合材料宏观试验方法、微复合材料试验方法、复合材料原位试验方法3种分析技术。最后指出,综合运用各种分析技术是目前解决问题的现实方法。
The analysis method of surface modification of aramid fiber are outlined.The FTIR,Raman,XPS,SEM,AFM of five quanlitative analysis techniques,and BET method,contact angle,infiltration rate,fiber pull-out method,interlaminar shear strength,fiber-dip strength of six quantitative analysis techniques are introduced,meanwhile,macro-experiment methods of composite material,micro-composite material experiment methods,in-situ experiment of composite materials are reviewed,too.Finally it is pointed out that comprehensive use of the various analysis techniques is the realistic way to solve problem.
关键词(KeyWords):
芳纶;表面改性;分析表征
aramid fiber,surface modification,analysis and characterization
基金项目(Foundation):
作者(Author):
刘克杰,杨文良,彭涛,王凤德
LIU Ke-jie,YANG Wen-liang,PENG Tao,WANG Feng-de(High Performance Fiber Section
DOI: 10.16090/j.cnki.hcxw.2011.08.007
参考文献(References):
- [1]刘克杰,杨文良,彭涛,等.芳纶表面改性技术进展(一)——物理改性方法[J].合成纤维,2011,40(6):25-30.
- [2]刘克杰,杨文良,彭涛,等.芳纶表面改性技术进展(二)——化学改性方法[J].合成纤维,2011,40(7):26-31.
- [3]王飞,黄英,张银玲.高性能纤维表面改性研究进展[J].中国胶粘剂,2010,19(3):49-54.
- [4]Tao Ai,Rumin Wang,Wenying Zhou.Effect of grafting alkoxysilaneon the surface properties of Kevlar fiber[J].Polymer Composites,2007:412-416.
- [5]Jeng Shyong Lin.Effect of surface modification by bromination andmetalation on Kevlar fibre-epoxy adhesion[J].European Polymer Journal,2002,38:79-86.
- [6]Angela M Mavrich,Hatsuo Ishida,Jach L.Koenig.Infrared mapping ofsurface-modified Kevlar fiber-reinforced epoxy systems[J].AppliedSpectroscopy,1995,49(2):149-155.
- [7]艾涛,王汝敏,袁海根,等.用作缝线的凯芙拉-29纤维表面改性研究[J].固体火箭技术,2004,27(4):312-315.
- [8]S L Tidrick,J L Koenig.Photoacoustic FT-IR analysis of surface-modified Kevlar49 fibers[J].Journal of Adhesion,1989,29(1-4):43-51.
- [9]A J Cervenka,R J Young,K Kueseng.Micromechanical phenomenaduring hygrothermal ageing of model composites investigated by Ramanspectroscopy.PartⅠ:Twaron fibres with different surface treatments[J].Composites:Part A,2005,36(7):1 011-1 019.
- [10]Yu Ren,Chunxia Wang,Yiping Qiu.Influence of aramid fibermoisture regain during atmospheric plasms treatment on aging of treatmenteffects on surface wettability and bonding strength to epoxy[J].AppliedSurface Science,2007,253(23):9 283-9 289.
- [11]Min Xi,Yuliang Li,Shuyong Shang,et al.Surface modification ofaramid fiber by air DBD plasma at atmospheric pressure with continuouson-line processing[J].Surface&Coatings Technology,2008:6 029-6 033.
- [12]GB/T 19500-2004 X-射线光电子能谱分析方法通则[S].
- [13]习敏,李育亮,李代红,等.DBD等离子体改性芳纶表面的动态工艺研究[J].合成纤维工业,2008,31(2):41-43.
- [14]陈耀文,林月娟,张海丹,等.扫描电子显微镜与原子力显微镜技术之比较[J].中国体视学与图像分析,2006,11(1):53-58.
- [15]隋娟玲,孙珊.扫描电子显微镜和原子力显微镜-表面观察的互补技术[J].矿冶,2004,13(3):95-97.
- [16]V Ravichandran,S K Obendorf.Wettability and adhesion studies ofgrafted poly(p-phenylene terephthalamide)fiber surfaces[J].JournalAdhesion Science Technology,1992,6(12):1 303-1 323.
- [17]GB/T 19587-2004气体吸附BET法测定固态物质比表面积[S].
- [18]王辉,王书秋.树脂基体对玻璃纤维浸润性的测定[J].纤维复合材料,1988(3):7-10.
- [19]Y C Tsai,C T Chou,L S Penn.Contact angle data and adhesiveperformance for smooth surfaces with attached molecular chains[J].Journal Adhesion Science Technology,1992,6(9):945-953.
- [20]赵维加,齐宏进.单丝纤维与液滴接触角的两种算法[J].纺织基础科学学报,1991(1):40-44.
- [21]D H Kaelble.Physical chemistry of adhesion[M].New York:Wiley-interscience.1971.
- [22]孙慕瑾,胡宝蓉,罗爱琴.动态毛吸法测定纤维及粉末料的接触角研究[J].复合材料学报,1989,6(3):5-11.
- [23]王霞,金士九,李已明.动态毛吸法测定纤维浸润性[J].中国胶粘剂,1994,3(3):1-5.
- [24]笪有仙,胡宝蓉,顾元,等.芳纶纤维表面改性及对复合材料性能的影响[C].玻璃钢学会第十一届全国玻璃钢/复合材料学术年会论文集,1995:24-28.
- [25]王杨,李鹏,于运花,等.芳纶纤维的磷酸表面处理及其树脂基复合材料界面性能[J].复合材料学报,2007,24(3):7-12.
- [26]雷渭媛,刘国俊.芳纶复合材料的界面粘结[J].复合材料学报,1991,8(4):27-35.
- [27]A Andres Leal,Joseph M.Deitzel,et al.Interfacial behavior of highperformance organic fibers[J].Polymer,2009,50(5):1 228-1 235.
- [28]Bernard Miller,Umesh Gaur,Douglas E Hirt.Measurement and me-chanical aspects of the microbond pull-out technique for obtaining fiber/resin interfacial shear strength[J].Composites Science and Technology,1991,42(1-3):207-219.
- [29]C Y Yue,K Padmanabhan.Interfacial studies on surface modifiedKevlar fibre/epoxy matrix composites[J].Composites Part B:Engineering,1999,30(2):205-217.
- [30]GB/T 1458-2008纤维缠绕增强塑料环形试样力学性能试验方法[S].
- [31]王斌,丘哲明,杨建奎.F-12芳纶纤维表面处理对复合材料剪切性能的影响[J].固体火箭技术,1995,18(1):64-68.
- [32]张淑慧,张炜,曾金芳.F-12纤维表面处理对复合材料壳体纤维强度转化率的影响[J].高科技纤维与应用,2004,29(3):12-18.
- [33]曾金芳,丘哲明,乔生儒.纤维表面处理对F-12复合材料剪切性能的影响[J].玻璃钢/复合材料,2000(5):20-21.
- [34]JC/T 773-1996单向纤维增强塑料层间剪切强度试验[S].
- [35]GB/T 4550-2005试验用单向纤维增强塑料平板的制备[S].
- [36]GJB 348-1987芳纶复丝拉伸性能测试方法浸胶法[S].
- [37]孙友德,刘庆备.俄罗斯杂环芳纶-环氧胶丝抗拉强度[J].高科技纤维与应用,2006,31(1):22-26.
- [38]黄玉东,魏月贞.复合材料界面研究现状(中)[J].纤维复合材料.1994(1):1-7.