海藻酸纤维对铜离子的吸附性能The Adsorption Properties of Alginate Fibers for Copper Ions
莫岚,陈洁,宋静,李翠翠,秦益民
MO Lan, CHEN Jie, SONG Jing, LI Cui-cui, QIN Yi-min (The Biochemical Materials Research and Development Center
摘要(Abstract):
为了研究不同种类的海藻酸纤维对铜离子的吸附性能,用盐酸及硫酸钠水溶液处理海藻酸钙纤维,分别得到海藻酸及海藻酸钙钠纤维。把三种纤维分别与含铜离子的水溶液接触后,在不同的时间段测试溶液中铜离子的浓度。结果显示:海藻酸、海藻酸钙及海藻酸钙钠纤维对铜离子均有较好的吸附性能,其平衡吸附容量分别为68.6mg/g、81.7mg/g和71.0mg/g,海藻酸钙纤维的吸附容量在三种纤维中最高;由于海藻酸钙钠纤维遇水后可以很快地吸水膨胀,其吸附速度较其它两种纤维快。
In order to study the adsorption of copper ions by various types of alginate fibers, this paper used aqueous HCl and Na2SO4 solutions to treat calcium alginate fibers to make alginic acid fiber and calcium sodium alginate fiber respectively. The three types of fibers were placed in aqueous solutions containing copper ions and the ion concentrations were measured at different periods of time. Results showed that the equilibrium adsorption capacities for copper ions were 68.6 mg/g, 81.7 mg/g and 71.0 mg/g respectively for alginic acid, calcium alginate and calcium sodium alginate fibers, with calcium alginate fiber having the highest adsorption capacity. Because it could swell rapidly in water, the adsorption speed was highest for the calcium sodium alginate fiber.
关键词(KeyWords):
海藻酸;重金属离子;废水处理;离子交换
alginate, heavy metal ion, waste water treatment, ion exchange
基金项目(Foundation): 浙江省科技计划项目(2008C21005)
作者(Author):
莫岚,陈洁,宋静,李翠翠,秦益民
MO Lan, CHEN Jie, SONG Jing, LI Cui-cui, QIN Yi-min (The Biochemical Materials Research and Development Center
参考文献(References):
- [1]秦益民.海藻酸[M].北京:中国轻工业出版社,2008.
- [2]王秀娟,张坤生,任云霞等.海藻酸钠凝胶特性的研究[J].食品工业科技,2008,29(2):259-262.
- [3]Speakman J B,Chamberlain N H.The production of rayon from alginic acid[J].J Soc Dyers Colourists,1944,60:264-272.
- [4]秦益民.海藻酸纤维在医用敷料中的应用[J].合成纤维,2004,33(3):11-16.
- [5]Smidsrod O,Haug A.Dependence upon the gel-sol state of the ion-exchange properties of alginates[J].Acta Chem Scand,1972,26:2063-2074.
- [6]孟祥如,胡国飞.重金属废水处理[M].北京:化学工业出版社,2000.
- [7]Qin Y,Hu H,Luo A.The conversion of calcium alginate fibers into alginic acid fibers and sodium alginate fibers[J].Journal of Applied Polymer Science,2006,101(6):4216-4221.
- [8]Qin Y.The ion exchange properties of alginate fibers[J].Textile Research Journal,2005,75(2):165-168.