张亮儒,杨燕宁,卢晨,张正博,尉寄望
ZHANG Liang-ru,YANG Yan-ning,LU Chen,ZHANG Zheng-bo,WEI Ji-wang

• 1:陕西省纺织科学研究院有限公司

摘要(Abstract)：

碳纤维复合材料质轻、比模量与比强度高，广泛应用于航空航天等领域。然而在极端环境下使用碳纤维复合材料会造成其报废与损伤，使得废弃物对资源与环境产生负担，无法满足国家提倡的节能减排的发展要求。从物理、化学、热回收等方法探讨碳纤维复合材料废弃物中碳纤维的回收再利用情况，为发展绿色可持续碳纤维提供更宽的思路。
Carbon fiber composites with light weight, high specific modulus and strength are widely used in aerospace and other fields. However, the use of carbon fiber composites in extreme environment will cause scrap and damage, which makes waste burden on resources and environment, and can not meet the development requirements of energy conservation and emission reduction advocated by the country. The recycling of carbon fiber from carbon fiber composite material waste was discussed by physical, chemical and thermal recovery methods, so as to provide a broader idea for the development of green and sustainable carbon fiber.

关键词(KeyWords)： 碳纤维复合材料;回收;再利用
carbon fiber composites;recycling;reuse

Abstract:

Keywords:

基金项目(Foundation):

作者(Author): 张亮儒,杨燕宁,卢晨,张正博,尉寄望
ZHANG Liang-ru,YANG Yan-ning,LU Chen,ZHANG Zheng-bo,WEI Ji-wang

DOI: 10.16090/j.cnki.hcxw.2023.05.018

参考文献(References)：

• [1]杨斌.碳纤维复合材料回收再利用现状及前景分析[EB/OL].[2019-12-06]. https://v.qq.com/x/page/l3020fchh94.html.
• [2] HEIL J. Study and analysis of carbon fiber recycling[M]. LAP LAMBERT Academic Publishing, 2011.
• [3]赵稼祥.国际碳纤维再生与重用会议[J].高科技纤维与应用,2010, 35(2):1-5.
• [4]三家PAN基碳纤维厂家设立开发碳纤维再生技术组合[N].塑料,2013-05-15(1).
• [5]刘建叶,宋金梅,彭玉刚,等.热固性碳纤维复合材料废弃物回收及再利用现状[J].化工新型材料，2014, 42(8):216-218.
• [6]杜晓渊,程小全,王志勇,等.碳纤维复合材料回收与再利用技术进展[J].高分子材料科学与工程, 2020, 36(8):182-190.
• [7] PALMER J, GHITA O R, SAVAGE L, et al. Successful closed-loop recycling of thermoset composites[J]. Composites Part A Applied Science&Manufacturing, 2009, 40(4):490-498.
• [8] PICKERING S J. Recycling technologies for thermoset composite materials—current status[J]. Composites Part A, 2005, 37(8):1206-1215.
• [9] YILDIRIR E, ONWUDILI J A, WILLIAMS P T. Recovery of carbon fibres and production of high quality fuel gas from the chemical recycling of carbon fibre reinforced plastic wastes[J]. The Journal of Supercritical Fluids, 2014, 92(8):107-114.
• [10] HENRY L, SCHNELLER A, DOERFLER J, et al. Semi-continuous flow recycling method for carbon fibre reinforced thermoset polymers by near-and supercritical solvolysis[J]. Polymer Degradation and Stability,2016, 133:264-274.
• [11] MELENDI-ESPINA S, MORRIS C, TURNER T, et al. Recycling of carbon fibre composites[C]//Proceedings of Carbon 2016. Penn State University, State College, United States, 2016.
• [12]邓建英.微波热解碳纤维/环氧树脂复合材料回收碳纤维的研究[D].昆明:昆明理工大学, 2019.
• [13] HOSSEINI A, GHAFOORI E, MOTAVALLI M, et al. Mode I fatigue crack arrest in tensile steel members using prestressed CFRP plates[J].Composite Structures, 2017, 178:119-134.
• [14]张灵静,陈桦,蒋建军,等.碳纤维增强热固性复合材料回收再利用技术研究进展[J].工程塑料应用, 2019, 47(7):134-140, 150.
• [15] PINERO-HERNANZ R, GARCíA-SERNA J, DODDS C, et al.Chemical recycling of carbon fibre composites using alcohols under subcritical and supercritical conditions[J]. Journal of Supercritical Fluids,2008, 46(1):83-92.
• [16] XU P L, LI J, DING J P. Chemical recycling of carbon fibre/epoxy composites in a mixed solution of peroxide hydrogen and N,N-dimethylformamide[J]. Composites Science and Technology, 2013, 82(18):54-59.
• [17] LIU T, ZHANG M, GUO X L, et al. Mild chemical recycling of aerospace fiber/epoxy composite wastes and utilization of the decomposed resin[J]. Polymer Degradation and Stability, 2017, 139:20-27.
• [18]张亚东.碳纤维复合材料的回收与再利用技术研究[J].广东化工, 2022, 49(10):26-27, 52.
• [19]任彦.碳纤维复合材料的回收与利用[J].新材料产业, 2014(8):19-22.
• [20] PIMENTA S, PINHOS T. Recycling carbon fibre reinforced polymers for structural applications:technology review and market outlook[J].Waste Management, 2010, 31(2):378-392.
• [21] LESTER E, KINGMAN S, WONG K H, et al. Microwave heating as a means for carbon fibre recovery from polymer composites:a technical feasibility study[J]. Materials Research Bulletin, 2004, 39(10):1549-1556.
• [22] BINNER E, MEDIERO-MUNOYERRO M, HUDDLE T, et al. Factors affecting the microwave coking of coals and the implications on microwave cavity design[J]. Fuel Processing Technology, 2014, 125(9):8-17.
• [23]胡侨乐,端玉芳,刘志,等.碳纤维增强聚合物基复合材料回收再利用现状[J].复合材料学报, 2022, 39(1):64-76.
• [24]胡炜杰,钟明建,杨营,等.碳纤维复合材料的回收与再利用技术[J].材料导报, 2021, 35(S2):627-633.
• [25] KIM K W, LEE H M, AN J H, et al. Recycling and characterization of carbon fibers from carbon fiber reinforced epoxy matrix composites by a novel super-heated-steam method[J]. Journal of Environmental Management, 2017, 203(Pt3):872-879.
• [26] JIANG G, PICKERING S J, WALKER G S, et al. Surface characterisation of carbon fibre recycled using fluidised bed[J]. Applied Surface Science, 2008, 254(9):2588-2593.
• [27] YIP H L H, PICKERING S J, RUDD C D. Characterisation of carbon fibres recycled from scrap composites using fluidised bed process[J]. Plastics, Rubber and Composites, 2002, 31(6):278-282.