螺纹式喷头制备PAN纳米纤维及其空气过滤性能Preparation of PAN Nanofibers by Threaded Nozzle and Its Air Filtration Performance
孙晓斌,范展华,赵义侠,孙宜东,张小研,马莹莹
SUN Xiao-bin,FAN Zhan-hua,ZHAO Yi-xia,SUN Yi-dong,ZHANG Xiao-yan,MA Ying-ying
摘要(Abstract):
以聚丙烯腈(PAN)为纺丝液,采用自主设计研发的螺纹式喷头静电纺丝装置制备了幅宽为600 mm的纳米纤维膜。通过扫描电镜和孔径测定仪考察了纤维形貌以及直径分布,并测试了纳米纤维膜对0.26μm氯化钠粒子的过滤性能。结果表明:纤维的平均直径为138 nm,平均孔径为1.98μm,纤维膜平均厚度为0.025 mm;PAN纳米纤维膜过滤效率为99.899%,滤阻为280.9 Pa。
Using polyacrylonitrile(PAN) as spinning solution, the nanofiber membrane with a width of 600 mm were prepared by using a threaded nozzle electrospinning equipment which was independently designed and developed. Field emission scanning electron microscopy and pore size meter were employed to study the morphology and pore diameter of nanofiber membranes, and the filtration performance of nanofiber membranes to 0.26 μm NaCl particles was tested. The results showed that the average fiber diameter was 138 nm, the average pore diameters was 1.98 μm, and the average thickness was 0.025 mm. The filtration efficiency of the PAN nanofiber membrane was 99.899% and the pressure resistance was 280.9 Pa.
关键词(KeyWords):
静电纺;螺纹式喷头;聚丙烯腈;纳米纤维
electrospinning;threaded nozzle;polyacrylonitrile;nanofiber
基金项目(Foundation): 天津市自然科学基金项目(18JCQNJC02900)
作者(Author):
孙晓斌,范展华,赵义侠,孙宜东,张小研,马莹莹
SUN Xiao-bin,FAN Zhan-hua,ZHAO Yi-xia,SUN Yi-dong,ZHANG Xiao-yan,MA Ying-ying
DOI: 10.16090/j.cnki.hcxw.2020.03.008
参考文献(References):
- [1]师奇松,于建香,顾克壮,等.静电纺丝技术及其应用[J].化学世界,2005,46(5):313-316.
- [2]李山山,何素文,胡祖明,等.静电纺丝的研究进展[J].合成纤维工业,2009,32(4):44-47.
- [3]丁彬,俞建勇.静电纺丝与纳米纤维[M].北京:中国纺织出版社,2011:3-5.
- [4]覃小红,王善元.静电纺丝纳米纤维的工艺原理、现状及应用前景[J].高科技纤维与应用,2004,29(2):28-32.
- [5]冯丽.静电纺纤维结构研究进展[J].产业用纺织品,2011,29(7):1-6.
- [6]胡敏,仲兆祥,邢卫红.纳米纤维膜在空气净化中的应用研究进展[J].化工进展,2018(4):1305-1313.
- [7]赵月,何婷,李茹冰,等.静电纺丝技术在创伤敷料方面的研究进展[J].生物医学工程研究,2017,36(1):90-94.
- [8]KIM S,PARK S G,KANG S W,et al.Nanofiber-based hydrocolloid from colloid electrospinning toward next generation wound dressing[J].Macromolecular Materials&Engineering,2016,301(7):818-826.
- [9]HAN Z,CHENG Z,CHEN Y,et al.Fabrication of highly pressure-sensitive,hydrophobic,and flexible 3D carbon nanofiber networks by electrospinning for human physiological signal monitoring[J].Nanoscale,2019,11(13):5942-5950.
- [10]马露,杨雪珂,高倩钰,等.静电纺相变纤维的制备及性能表征[J].国际纺织导报,2019(4):4-6.
- [11]JIRSAK O,SYSEL P,SANETRNIK F,et al.Polyamic acid nanofibers produced by needleless electrospinning[J].Journal of Nanomaterials,2010,2010(1):1-6.
- [12]KEITH M F,GREGORY C R.Free surface electrospinning from a wire electrode[J].Chemical Engineering Journal,2012,183:492-503.
- [13]何吉欢,孔海燕,周丽霞.气泡静电纺丝装置:201210177134.1[P].2012-05-31.
- [14]程博闻,康卫民,李全祥,等.一种静电纺纳米纤维非织造布生产装置:200810153891.9[P].2008-12-10.
- [15]SHARMA U,PHAM Q,MARINI J,et al.Electrospinning process for manufacture of multi-layered structures:US 9194058[P].2015-11-24.
- [16]高桥光弘,竹泽幹夫,冨永善章,等.纳米纤维和高分子网状物的制造方法和装置:200780043349.1[P].2007-11-20.
- [17]李好义.熔体微分静电纺丝原理、方法与设备[D].北京:北京化工大学,2014.
- [18]WANG N,WANG X F,DING B,et al.Tunable fabrication of threedimensional polyamide-66 nano-fiber/nets for high efficiency fine particulate filtration[J].Journal of Materials Chemistry,2012,22(4):1445-1452.