张方,黄伟,杨浚源,程春祖,纪艳红
ZHANG Fang,HUANG Wei,YANG Jun-yuan,CHENG Chun-zu,JI Yan-hong

• 1:天津工业大学材料科学与工程学院
• 2:中国纺织科学研究院有限公司生物源纤维制造技术国家重点实验室

摘要(Abstract)：

有色废旧纺织品的回收利用都需要对其进行剥色处理，剥色技术是影响其有效利用的关键，去除织物上的染料，避免因染料的存在而影响纺织品后续的处理。废旧纺织品的种类繁多，不同的纺织品所用纤维也不同，故剥色方法也不相同，单一织物的剥色相对较容易，混纺织物的剥色比较困难。对现有的剥色方法进行简单的阐述，发现采用氧化法和还原法为主的化学剥色方法会产生大量废水；采用物理剥色方法可以实现部分剥色剂等的回收利用，但其剥色效率低；生物、臭氧、光催化剥色方法不仅可以实现较高的剥色效率，而且剥色过程比较绿色环保，符合当下绿色环保的发展理念。
The recycling of colored waste textiles needs to be stripped, and the color stripping technology is the key to its effective utilization, removing the dyes on the fabrics, so as to avoid the existence of dyes affecting the subsequent processing of the textiles. There are many kinds of waste textiles, and different textiles use different fibers, so the color stripping methods are also different. It is relatively easy to strip a single fabric, and it is more difficult to strip a blended fabric. The existing color stripping methods are briefly described, it is found that the chemical color stripping method mainly using oxidation method and reduction method will produce a large amount of waste water; using physical color stripping method can realize the recycling of part of the color stripping agent, but its color stripping efficiency is low; biological methods,ozone, light catalytic color stripping method can not only achieve higher color stripping efficiency, but also the color stripping process is greener and environmentally friendly, which is in line with the current development concept of green environmental protection.

关键词(KeyWords)： 废旧纺织品;染料;剥色;环保
waste textiles;dye;color stripping;environmental protection

Abstract:

Keywords:

基金项目(Foundation):

作者(Author): 张方,黄伟,杨浚源,程春祖,纪艳红
ZHANG Fang,HUANG Wei,YANG Jun-yuan,CHENG Chun-zu,JI Yan-hong

DOI: 10.16090/j.cnki.hcxw.2023.04.015

参考文献(References)：

• [1] TOMH, UISAN K, OKYS, et al. Recent trends in greenand sustainable chemistry:rethinking textile waste in acircular economy[J]. Current Opinion in Green and Sus-tainable Chemistry, 2019, 20:1-10.
• [2] SHIRVANIMOGHADDAM K, MOTAMED B, RAMAKRISHNA S,et al. Death by waste:fashion and textile circulareconomycase[J]. Science of the Total Environment, 2020, 718:137317.
• [3]李静,李晓清.积极探索我国废旧纺织品的回收和再利用[J].中国纤检, 2016(4):28-30.
• [4]陈艳华,赵萍.我国废旧纺织品的回收再利用现状研究[J].轻工科技, 2019, 35(1):92-93, 117.
• [5]甘胜华,李红彬,李现顺,等.国内外废旧纺织品回收利用现状及展望[J].合成纤维, 2016, 45(9):42-46.
• [6]徐长杰.垃圾分类攻坚战打响,纺织循环经济大有可为[J].纺织服装周刊, 2019(26):12-13.
• [7]张振方,安红玉.废旧纺织品回收再利用的研究现状及发展趋势[J].成都纺织高等专科学校学报, 2017, 34(3):172-175.
• [8]徐寰,唐世君.国外废旧纺织品回收利用发展现状简析[J].纺织导报, 2012(7):31-32.
• [9]石杏玲,高晓新,潘锦萍.废旧纺织品的回收利用[J].轻工科技,2015, 31(2):111-112.
• [10]顾明明,赵凯,贺燕丽.欧洲废旧纺织品回收利用现状及启示[J].再生资源与循环经济, 2016, 9(5):41-44.
• [11]陶亚奇,王小雷.废旧服装升级利用现状的研究[J].服饰导刊,2019, 8(1):50-56.
• [12]陈益平.废弃纺织品剥色方法研究[D].苏州:苏州大学, 2020.
• [13]杨帆.棉织物催化氧化剥色的研究[D].杭州:浙江理工大学, 2013.
• [14]朱斌,胡敏亚.纯棉纱线活性染料剥色工艺[J].印染, 2009, 35(6):19-21.
• [15]李伟勇,邓沁兰,袁冬梅.活性染料染色纯棉纱线的剥色[J].化纤与纺织技术, 2009(2):8-9, 19.
• [16]陈世良,吕慎水,魏莉莉,等.二氧化氯对活性染料的脱色[J].纺织学报, 2007(3):68-71.
• [17]楚艳艳,张晓莉,崔世忠.纯棉织物的氧化法剥色工艺研究[J].上海纺织科技, 2011, 39(7):30-33.
• [18]李青献,周永群.次氯酸钠用于分散染料剥色的作用机理及应用性能初探[J].针织工业, 1993(5):22-25.
• [19]蒲宗耀,黄玉华,刘庆. DMF剥色法测定分散染料在细旦涤纶纤维上的固色率[J].印染, 1996(12):32-33.
• [20]吴宝宅,武志云,汪少朋,等.应用二甲基亚砜对废旧聚酯纺织品的脱色[J].纺织学报, 2014, 35(4):84-87.
• [21]牛振怀.废旧涤纶织物再资源化的研究[D].太原:太原理工大学, 2015.
• [22]李明,王晓晶,彭帅,等.一种有色涤纶织物的脱色方法:108951233A[P]. 2018-12-07.
• [23]胡剑安,李志刚.一种废旧聚酯纺织品的脱色工艺:110387759A[P]. 2019-10-29.
• [24]张朔,陈文兴,刘雄,等.一种实现溶剂循环的含涤废旧纺织品脱色工艺:107587362A[P]. 2018-01-16.
• [25]蔡智锋.涤棉混纺织物剥色方法及其机理的研究[D].太原:太原理工大学, 2013.
• [26]王彬.废旧涤/棉织物脱色及回收工艺研究[D].青岛:青岛大学, 2015.
• [27]丁鹏飞,陈宝健,赵为陶,等.废旧涤/棉织物的剥色和分离回收工艺探讨[J].江苏丝绸, 2017(3):26-32.
• [28]崔浩然.染色涤纶或锦纶织物如何进行减色(减浅)处理?[J].印染,2015, 41(19):59.
• [29]翦育林,伍建国.锦纶杂色废短绒剥色工艺[J].丝绸, 1997(12):27-29.
• [30]王惠珍,龙家杰,唐人成,等.阳离子染料剥色剂DCA-01的应用性能[J].印染助剂, 2001(6):5-10.
• [31]陈美云,张玉萍.羊毛双氧水—尿素漂白工艺探讨[J].毛纺科技,1998(2):39-41.
• [32]陈美云.真丝织物精练、漂白一步法工艺[J].印染,1997(3):12-14.
• [33]程彦,闫腾,李美真,等.赖可匀MF在染色羊绒纱线剥色上的应用[J].染整技术, 2007(4):31-33.
• [34]王树根,田秀枝.配位体在酸性媒介染料染毛制品匀染剂剥色中的应用[J].印染助剂, 2003(2):25-27.
• [35]史惠祥,赵伟荣,汪大翚.偶氮染料的臭氧氧化机理研究[J].浙江大学学报(工学版), 2003(6):106-110.
• [36]任腊梅.有色涤纶及涤棉织物的臭氧脱色研究[D].无锡:江南大学, 2021.
• [37]刘阳,雷荣洁,邵娟.活性染料染色棉织物的臭氧脱色[J].印染助剂, 2020, 37(12):40-43.
• [38] SEMIHA E, BUSE G, HUSEYIN A. Colour stripping of reactivedyed cotton by ozone treatment[J]. Coloration Technology, 2016, 132(6):466-471.
• [39] PEDERSEN. Removal of excess dye from new textiles:US5356437[P]. 1994-10-18.
• [40] CHATHA S A S. Investigation of the potential of microbial stripping of dyed cotton fabric using white rot fungi[J]. Textile Research Journal,2011, 81(17):1762-1771.
• [41] CHATHA S A S, ASGHER M, ALI S, et al. Biological color stripping:a novel technology for removal of dye from cellulose fibers[J]. Carbohydrate Polymers, 2012, 87(2):1476-1481.
• [42] CHATHA S A S, MALLHI A I, HUSSAIN A I, et al. A biological approach for color-stripping of cotton fabric dyed with CI reactive black 5using fungalenzymes from solid state fermentation[J]. Current Biotechnology, 2014, 3(2):166-173.
• [43]刘守新,刘鸿.光催化及光电催化基础与应用[M].北京:化学工业出版社, 2005.
• [44]解昌峰,龙家杰,唐人成.活性染色棉织物的UV/H2O2体系低温剥色[J].印染, 2010, 36(4):11-15.
• [45] LONG J J, LIU B, WANG G F, et al. Photocatalitic stripping of fixed reactive RedX-3B dye from cotton with nano-TiO2/UV system[J]. Journal of cleaner production, 2017, 165:788-800.
• [46] HE F N, LI X, ZHU M K, et al. Color stripping of reactive-dyed cotton fabric in a UV/sodium hydrosulfite system with a dipping manner at low temperature[J]. Cellulose, 2019, 26(6):4125-4142.
• [47]何家铭,刘波,龙家杰.棉织物上活性黄X-R的纳米光催化剥色研究[J].毛纺科技, 2021, 49(4):62-69.
• [48]刘波,解昌峰,孙建平,等. UV/Na2S2O4体系中棉织物上活性染料的浸轧剥色研究[J].纺织导报, 2017(6):78-82.