无卤高阻燃共聚酯的合成与应用Synthesis and Application of Non-Halogen High Flame Retardant Copolyester
梁倩倩,刘健飞
LIANG Qian-qian,LIU Jian-fei(Sichuan EM Technology Co.Ltd.
摘要(Abstract)：
以自制的含双官能团的DCF-5为共聚型含磷阻燃剂,在自制助催化剂及防滴落剂的作用下合成无卤高阻燃共聚酯。磷含量、阻燃性能及环保性能测试结果表明:该产品磷含量超过1.7%,极限氧指数高达56%,阻燃等级完全达到V-0级,并通过了SGS公司卤素及RoHS测试。此外,重点阐述了该阻燃聚酯产品在下游各领域实际应用中取得的重大突破和技术优势。
The non-halogen high flame retardant copolyester with self-made DCF-5 as the bifunctional phosphorus flame retardant,self-made catalyst and anti-dropping agent was prepared.The test result showed that the content of phosphorus in the product over 1.7 %,the limiting oxygen index 56 %,the flame retardant level V-0,it passed the RoHS test and the halogen test from SGS Co.The important breakthough and technical advantage of the series products of non-halogen high flame retardant copolyester in the application of downstream fields were discussed.
关键词(KeyWords)：
无卤阻燃;共聚酯;双官能团磷系阻燃剂
non-halogen flame retardant,coplyester,bifunctional phosphorus flame retardant
基金项目(Foundation): 2011年战略性新兴产业发展专顶资金项目
作者(Author):
梁倩倩,刘健飞
LIANG Qian-qian,LIU Jian-fei(Sichuan EM Technology Co.Ltd.
DOI: 10.16090/j.cnki.hcxw.2013.07.018
参考文献(References)：
- [1]王鸣义.“环境友好型”聚酯纤维的产品开发[J].合成纤维,2009,38(3):1-6.
- [2]白木.聚酯瓶在包装领域的应用[J].中国包装,2011(5):39-42.
- [3]滕岩.PET薄膜在干膜生产中的应用[J].聚酯工业,2011(3):53-54.
- [4]杨始堃,陈玉君.PET的发泡及在液晶反射板的应用[J].聚酯工业,2010,23(1):1-4.
- [5]刘锋,王锡柱,张德善.PET改性工程塑料的发展动态[J].弹性体,2005,15(6):59-63.
- [6]Deyi Wang,Xueqi Liu,et al.Preparation and characterisation of anovel fire retardant PET/α-zirconium phosphate nanocomposite[J].Poly-mer Degradation and Stability,2009,94(4):544-549.
- [7]Nizar Didane,Stéphane Giraud,et al.Fire performances comparisonof back coating and melt spinning approaches for PET covering textiles[J].Polymer Degradation and Stability,2012,97(7):1 083-1 089.
- [8]Hongbing Chen,Yi Zhang,et al.Novel inherently flame-retardantpoly-(trimethylene Terephthalate)copolyester with the phosphorus-con-taining linking pendent group[J].Industrial&Engineering Chemistry Re-search,2010,49(15):7 052-7 059.
- [9]Federico Carosio,Galina Laufer,et al.Layer-by-layer assembly ofsilica-based flame retardant thin film on PET fabric[J].Polymer Degrada-tion and Stability,2011,96(5):745-750.
- [10]Jenny Alongi,Alberto Frache,Emilia Gioffredi.Fire-retardant poly(ethylene tere-phthalate)by combination of expandable graphite and lay-ered clays for plastics and textiles[J].Fire and Materials,2011,35(6):383-396.
- [11]侯彩英,周艳明,罗红,等.磷系列新结构环保型阻燃聚酯研究进展[J].材料开发与应用,2011(6):63-67.
- [12]王鲁英,嗄力巴,刘姝,等.阻燃涤纶织物的现状及发展[J].合成纤维,2011,40(10):6-10.
- [13]周向阳,贾德民,严志云.聚酯纤维阻燃技术研究进展[J].合成材料老化与应用,2011,40(1):37-41.