唐永良
TANG Yong-Liang (Shanghai Research Institute of Petrochemical Technology

• 1:中国石油化工股份有限公司上海石油化工研究院 上海201208

摘要(Abstract)：

对环氧乙烷催化法合成乙二醇研究的最新进展作了综述。阐述了用于环氧乙烷催化水合反应中的多羧酸衍生物催化体系、离子交换树脂催化体系、大环螯合物催化体系、季鏻盐催化体系、多相水滑石型催化体系及其他催化体系近年来的研究进展;同时阐述了用于碳酸亚乙酯法合成乙二醇反应中的催化体系的新进展。
Recent advances in preparation of ethylene glycol via ethylene oxide catalytic reaction are reviewed in this paper. New developments of polycarboxylic acid derivative catalysts, ion exchange resin catalysts,macrocyclic chelating compound catalysts, quaternary phosphonium salt catalysts, heterogeneous hydrotalcite-type catalysts and other catalysts which to be used in ethylene oxide catalytic hydration, and the catalysts of synthesis method of ethylene glycol via preparation and reaction of ethylene carbonate are expounded.

关键词(KeyWords)： 环氧乙烷;催化法;合成;乙二醇
ethylene oxide, catalytic method, synthesis, ethylene glycol

Abstract:

Keywords:

基金项目(Foundation):

作者(Author): 唐永良
TANG Yong-Liang (Shanghai Research Institute of Petrochemical Technology

参考文献(References)：

• [1]Li Y Ch,Y an Sh R,et al.E ffects of support m odification on N b2O5/alpha-A l2O3catalyst for ethylene oxide hydration[J].Journal of M olecular C atalysis A,2005,226(2):285￣290.
• [2]沈菊华.国内外乙二醇生产发展概况[J].化工科技市场,2003,26(6):12￣15.
• [3]K ruchten V,A ndre E M G.Carboxylates in catalytic hydrolysis ofalky-lene oxides[P].U S6316571,2001.
• [4]Lem anski,Francis M,et al.Catalyst stabilizing additive in the hydroly-sis ofalkylene oxides[P].U S6156942,2000.
• [5]Shvets V F,K ozlovskiy R A,etal.The cause and quantitative descrip-tion of catalyst deactivation in the ethylene oxide hydration process[J].C hem ical Engineering Journal,2005,107(1-3):199￣204.
• [6]K ruchten V,M arie E.C atalytic hydrolysis of alkylene oxides[P].U S6137014,2000.
• [7]K ruchten V,A ndre E M G.Q uaternary phosphonium salt catalysts in C atalytic hydrolysis ofalkylene oxides[P].U S6124508,2000.
• [8]华强,刘定华等.催化水合法合成乙二醇[J].石油化工,2003,32(4):317￣320.
• [9]华强,刘定华等.催化水合法合成乙二醇工艺条件的分析与优化[J].化学反应工程与工艺,2003,19(1):63￣68,88.
• [10]戴忻,刘定华等.环氧乙烷的吸收与催化水合法制乙二醇[J].石油化工,2004,33(4):316￣319.
• [11]张勇斌,刘定华,马正飞等.N Y型均相催化剂对乙二醇产品U V值的影响[J].石油化工,2004,33(5):460￣463.跃
• [12]Li Y C h,Y an Sh R,et al.Selective catalytic hydration of ethylene oxide over niobium oxide supported on alpha-alum ina[J].A pplied Catal-ysis A,2004,272(1-2):305￣310.
• [13]李应成,何文军等.碳酸亚乙酯法合成乙二醇研究进展[J].工业催化,2002,10(4):40￣44.
• [14]田恒水,朱云峰,潘鹤林.乙二醇生产新工艺[J].上海化工,2001,(15):15￣17.
• [15]Strickler G R,Landon V G,et al.M ethod for m aking glycolin an adi-abatic reactor system[P].U S6160187,2000.
• [16]K aw abe K.Process for sim ultaneous production of ethylene glycol and carbonate ester[P].U S20010020102,2001.
• [17]B hanage B M,Fujita S I,et al.Concurrent synthesis of dim ethyl car-bonate and ethylene glycol via transesterification Carbonate and m ethanol using sm ectite catalysts containing M g and/or N i[J].C atalysis Letters,2002,83(3):137￣141.
• [18]杜建军,梁云峰等.环氧乙烷/乙二醇生产装置用能分析与调优[J].现代化工,2003,23(11):43￣47.
• [19]Shvets V F,M akarov M G,et al.M ethod of synthesis of alkylene gly-cols[P].R U2149864,2000.
• [20]K ruchten V,A ndre E M G,et al.C atalytic process for producing an alkylene glycol with reactor-outputcycle[P].U S6580008,2003.