李杨,王进美,李彩霞
LI Yang,WANG Jin-mei,LI Cai-xia

• 1:西安工程大学

摘要(Abstract)：

研究了掺杂酸种类、氧化剂浓度、反应温度、有机酸浓度对聚苯胺导电性的影响,选用过硫酸铵(APS)作为氧化剂,磺基水杨酸(SSA)和对甲苯磺酸(TSA)两种有机酸作为掺杂酸,经过试验探索得到最佳的工艺:苯胺与APS、掺杂酸的摩尔比为1∶1∶1,聚合温度0℃,APS浓度为1.0 mol/L,SSA和TSA的浓度分别为0.3 mol/L和0.4 mol/L。
The effects of acid type, oxidant concentration, temperature and concentration of organic acid onthe conductive of polyaniline were studied. Ammonium persulfate was used as the oxidant, SSA and TSA or-ganic acid were used as the doping acid. After experimental exploration the best process were got: mole ra-tio of anitine, ammonium persulfate and organic acid was 1:1:1, polymerization temperature was 0 ℃, oxi-dant concentration was 1.0 mol/L, the concentration of the doping acid SSA and TSA were 0.3 mol/L and 0.4 mol/L.

关键词(KeyWords)： 聚苯胺;有机酸;电导率
polyaniline,organic acid,electrical conductivity

Abstract:

Keywords:

基金项目(Foundation):

作者(Author): 李杨,王进美,李彩霞
LI Yang,WANG Jin-mei,LI Cai-xia

DOI: 10.16090/j.cnki.hcxw.2015.05.002

参考文献(References)：

• [1]徐浩,延卫,冯江涛.聚苯胺的合成与聚合机理研究进展[J].化工进展,2008(10):1 561-1 568.
• [2]乔欣,杜建功,夏勇.原位聚合法制备聚苯胺导电纤维的研究进展[J].现代纺织技术,2010(4):65-68.
• [3]张保宏,薛涛,孟家光.静电纺丝法制备抗静电腈纶及其性能[J].合成纤维,2013,42(6):23-25.
• [4]张晓辉,李龙,赵伟.聚苯胺/涤纶居电织物的制备[J].合成纤维,2010,39(8):16-19.
• [5]马利,汤琪.导电高分子材料聚苯胺的研究进展[J].重庆大学学报(自然科学版),2002(2):124-127.
• [6]E K Chatzidaki,E P Favvas,S K Papageorgiou,et al.Theophilou New polyimide-polyaniline hollow fibers:Synthesis,characterization and behavior in gas separation[J].European Polymer Journal,2007,43(12):5 010-5 016.
• [7]黄惠,周继禹,许金泉,等.有机/无机酸复合掺杂导电聚苯胺的合成及性能研究[J].高校化学工程学报,2009(6):984-989.
• [8]苏静,王庚超,邓惠山,等.掺杂质子酸的类型对聚苯胺结构和电导率的影响[J].功能高分子学报,2002(2):122-126.
• [9]马利,冯利军,甘孟瑜,等.复合酸掺杂导电聚苯胺的合成及性能[J].应用化学,2008(2):142-146.
• [10]李志勇.掺杂态聚苯胺的研究[D].天津工业大学,2007.
• [11]颜海燕,寇开昌.温度对化学氧化法合成盐酸掺杂聚苯胺的影响[J].科学技术与工程,2008,15:4 406-4 408,4 421.
• [12]郑剑锋,赵江红,朱珍平.掺杂酸和氧化剂的浓度对聚苯胺纳米线导电性的影响[J].材料导报,2009(6):17-20.