陈观福寿,朱小云,黄斌香
CHENGUAN Fu-shou~1,ZHU Xiao-yun~2,HUANG Bin-xiang~1 (1.Shanghai Lingqiao Environmental Protection Equipment Works.Co.Ltd.

• 1:上海市凌桥环保设备厂有限公司
• 2:上海市纺织科学研究院

摘要(Abstract)：

以不同聚四氟乙烯分散树脂为原料,通过混料、熟化、预成型、压延、双向拉伸及膜裂切割等工艺,制备了高性能聚四氟乙烯(PTFE)纤维。试验结果表明:树脂原料的优劣、热处理温度及拉伸工艺是影响PTFE纤维力学性能的主要因素,PTFE纤维的拉伸倍数应该控制在32～49之间,最佳的拉伸温度在240～320℃之间。
High-performance polytetrafluoroethylene(PTFE) fiber was fabricated from different PTFE fine powder by a series of mechanical operations such as material mixing,curing,pre-forming,rolling,biaxial stretching,spliting and cutting.The results showed that the resin material,heat treatment process and drawing process were the major process affecting the performance of PTFE fibers.The stretching ratio should be controlled between 32~49 times and the best stretching temperature was 240~320℃during the course of PTPF production.

关键词(KeyWords)： 聚四氟乙烯;膜裂法;切割;纤维
polytetrafluoroethylene;spliting;cutting;fiber

Abstract:

Keywords:

基金项目(Foundation): 国家重点新产品计划(编号2009GRC00041、2010GRC00016、2011TJC00023);; 上海市重点新产品计划(编号08XP0503900、09XP0510000);; 中国纺织工业协会指导性科技项目(编号2010145)

作者(Author): 陈观福寿,朱小云,黄斌香
CHENGUAN Fu-shou~1,ZHU Xiao-yun~2,HUANG Bin-xiang~1 (1.Shanghai Lingqiao Environmental Protection Equipment Works.Co.Ltd.

DOI: 10.16090/j.cnki.hcxw.2012.08.019

参考文献(References)：

• [1]龚光甫,胡建国.尹邦良等.膨体聚四氟乙烯缝线替换心脏瓣膜腱索[J].中华胸心血管外科杂志,1999,15(6):333-334.
• [2]W L Gore & Associates Introduces GORE INFINIT Mesh-A Revolutionary Combination of Material and Structure[EB/OL].(2008-10-01) [2011-12-02].http://www.gore.com/en_xx/news/infinitmesh.html.
• [3]何正兴.国产聚四氟乙烯纤维的特性与应用[J].合成纤维,2007,36 (4):16-18.
• [4]张瑞甫,张建等.膜材料在建筑结构中的发展与应用[J].陕西建筑, 2007(3):1-3.
• [6]Abdul R H,Chua C S,Toyoda H.Weather ability of coated fabrics as roofing material in tropical environment[J].Building and Enviroment, 2004,39(1):87-92.
• [7]李如琰.聚四氟乙烯纤维织物在关节轴承上的应用[J].功能材料, 2004,35(z1):2 221-2 223.
• [8]Alexander S.Polytetrafluoroethylene fiber-based composite antifriction coating[J].Industrial and Engineering Chemistry Research,1993,32(5): 763-746.
• [9]Robert L.Mc Gee,John R.Collier.Solid state extrusion of polytetrafluoroethylene fibers[J].Polymer Engineering Science,1986,26(3): 239-243.
• [10]Ishiwari Kazuo,Sakakura Atsushi.Porous polytetrafluoroethylene ??hollow yarn and preparation thereof:EP,0351584(A1)[P].1990-01-24.
• [11]Katayama Shigeki.A yam article comprising a tetrafluoroethylene polymer and a process for producing the same:EP,0352749(A1)[P]. 1990-01-31.
• [12]Martin Marsehe,Walter Schiek.PTFE纤维:通过专利生产技术获取的特性[J].国际纺织导报,2006,34(12):4-5.
• [13]郭玉海,陈建勇,张华鹏,等.用于废气分解的膨体聚四氟乙烯纤维的制备方法:中国专利,200610154943.5[P].2007-06-13.
• [14]黄斌香,黄磊,苏韵芳,等.一种聚四氟乙烯长纤维的制造方法: CN200610026648[P].2007-11-21.
• [15]陈丽萍,王耀武,孙润军,等.聚四氟乙烯纤维的制备与性能表征[J].合成纤维,2010,39(10):24-26,34.
• [16]郭占军,陈建勇,郭玉海,等.热处理对PTFE牵伸性能的影响[J].纺织学报,2010,31(6):21-24.
• [17]Moriyarma Yasuhiro,Suzukil Shoji,Yoshimura Atsuo,et al.Porous polytetrafluoroethylene material:US 4760102[P].1988-07-26.
• [18]Alexander Messinger,Rob Fleming,Csilla Wollner.Architectural fabric structures:Exploration,Modeling,and Implementation[C].National Textile Center Annual Report,2001(11):1-9.
• [19]任忠海,王庆华,武中德等.聚四氟乙烯纤维织物耐磨材料的摩擦学特性研究[J].摩擦学学报.2002,22(3):193-196
• [20]从文.浅述PTFE塑料的收缩率及蠕变性[J].有机氟工业,2002 (2):33-36.