宋会青,温月芳,杨永岗,王茂章
SONG Hui-qing 1,2,WEN Yue-fang1,YANG Yong-gang1

• 1:中国科学院山西煤炭化学研究所炭材料重点实验室
• 2:中国科学院山西煤炭化学研究所炭材料重点实验室
• 3:中国科学院山西煤炭化学研究所炭材料重点实验室
• 4:中国科学院山西煤炭化学研究所炭材料重点实验室 山西太原030001 中国科学院研究生院

摘要(Abstract)：

聚丙烯腈(PAN)纤维的稳定化是制备PAN碳纤维的关键步骤之一,综述了PAN纤维在不同介质中的稳定化过程研究以及国内外纤维改性后稳定化的研究,并简要介绍了时间、温度、张力等对稳定化过程的影响。
The stabilization of polyacrylonitrile fiber was a crucial step in the production of PAN-based carbon fibers.The present paper presented a review of the stabilization of PAN fibers in different medium and the effects of modification on the stabilization.It also introduced the influence of time-consuming,temperature and tension on stabilization of PAN fibers.

关键词(KeyWords)： 聚丙烯腈;稳定化;改性;碳纤维
polyacrylonitrile,stabilization,modification,carbon fiber

Abstract:

Keywords:

基金项目(Foundation): 973计划项目(2006CB605304);; 国家自然科学基金项目(50604025)

作者(Author): 宋会青,温月芳,杨永岗,王茂章
SONG Hui-qing 1,2,WEN Yue-fang1,YANG Yong-gang1

参考文献(References)：

• [1]王茂章,贺福.碳纤维的制造、性质及其应用[M].北京:科学出版社,1984.34.
• [2]于美杰,王成国,朱波等.聚丙烯腈基碳纤维原丝热稳定化研究进展[J].材料工程,2006,11:62-65.
• [3]R C Houz.Orlon acrylic fiber:chemistry and properties[J].Textile Res Journal,1950,20:786-801.
• [4]N Grassie,J N Hay,I C McNeill.Coloration in acrylonitrile and methacrylonitrile polymers[J].Journal of Polymer Science,1958,31:205-206.
• [5]J Schurz J.Discoloration effects in acrylonitrile polymers[J].Journal of Polymer Science,1958,28:438-439.
• [6]W Wattand,W Johnson.Mechanism of oxidization of polyacrylonitrile fibers[J].Nature,1975,257:210-212.
• [7]Grassie N,Hay JN.Thermal coloration and insolubilization in polyacry-lonitrile[J].Journal of Polymer Science,1962,56:189-202.
• [8]L H Peebles,J Brandrup.A chemical means of distinguishing between conjugated bonds[J].Die Makromoekulare Chemie,1966,98(1):189-203.
• [9]A E Standage,R D Matkowsky.Thermal oxidation of polyacrylonitrile[J].European Polymer,1971,7:775-783.
• [10]S S Chen,J R Schaefgen,W O Statton.Laterally ordered polymers:polyacrylonitrile and poly(vinyl trifuoroacetate)[J].Polym Sci,1961,55:531-549.
• [11]M M Coleman,G T Sivy,et al.Studies of the degradation of acryloni-trile/acrylamide copolymers as a funtion of composition and temperature[J].Carbon1983,21:255-263.
• [12]于晓强,庄光山,丁洪太.聚丙烯腈碳纤维在预氧化过程中环构化机理[J].山东工业大学学报,1995,25(4):301-305.
• [13]张利珍,吕春祥,吕永根.聚丙烯腈纤维在预氧化过程的结构和热性能转变[J].新型炭材料,2005,20(2):144-150.
• [14]刘杰,李仍员.PAN共聚纤维的热氧化研究[J].高分子材料科学与工程,1993,1(4):18-113.
• [15]JP2004-300600.
• [16]JP平1-104835.
• [17]高学平,朱波,王强.碳纤维流态化预氧化设备的研制[J].工业加热,2005,34(2):42-45.
• [18]JP平2-84505.
• [19]JP平2-14013.
• [20]N Grassie,R McGuchan.Pyrolysis of polyacrylonitrile and related polymers-VI.Acrylonitrile copolymers containing carboxylic acid and amide structures[J].European Polymer,1972,8:257-269.
• [21]Mathur R Gupta D.Infrared spectral studies of preoxidized PAN fibers incorporated with cuprous chloride additive[J].Fiber Science and Technology,1984,20:227-234.
• [22]Shiedlin A,Marom G,Zillkna A.Catalic initiation of polyacrylonitrile stabilization[J].Polymer,1985,26(3):447-451.
• [23]Tsehao Ko,Li chuan Huang.Preparation of high performance carbon fibers from PAN fibers modified with cobaltous chloride[J].J of Materials Science,1992,27:2429-2436.
• [24]Tsehao Ko,Singchuang Liau.Preparation of graphite fibres from a modified PAN precursor[J].J of Materials Science,1992,27:6071-6078.
• [25]Mathur R B,Mitta J,Bahl O P.Bimodification of polyacrylonitrile fibers[J].Journal of Applied Polymer Science,1993,49:469-476.
• [26]Bahl OP Mathur R B,Dhami TL.Modification of polyacrylonitrile fibres to make suitable for conversion into high performace carbon fibres[J].Materials Science and Engineering,1985,73(12):105-112.
• [27]J Mittal,R B Mathurb,et al.Post spinning treatment of PAN fibers using succinic acid to produce high performance carbon fibers.Carbon,1998,36:893-897.
• [28]刘杰,王培华,李玉梅.民用PAN大丝束的热氧稳定化、炭化研究[A].见:第四界全国新型材料学术研讨会议论文集[C].新型炭材料编辑部,1999.145-148.
• [29]张旺玺等.NiSO4改性对聚丙烯腈原丝及其碳纤维结构与性能的影响[J].高分子学报,2001,10(5):28-32.
• [30]王延相,王成国,蔡华苏.PAN原丝改性对碳纤维结构和性能的影响[J].合成纤维工业,2002,25(2):14-16.
• [31]刘焕章,王成国,王延相.聚丙烯腈纤维预氧化工艺条件对其结构和性能的影响.高科技纤维与应用,2006,31(1):31-35.
• [32]Bahl OP,Mathur RB.Effect of load on mechanical properties of carbon fibers from PAN precursor[J].Fiber science and technology,1979,12:31-39.
• [33]Layden GK.Tensile response of polyactylonitrile fibers during air heating[J].Journal of applied polymer science,1971,15:1709-1715.